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RARE METALS, SEMICONDUCTORS
ArticleName Synthesis of a titanium (IV)-based sorbent and potentialities of its usage for extracting cations of non-ferrous metals
DOI 10.17580/nfm.2017.02.06
ArticleAuthor Gerasimova L. G., Nikolaev A. I., Maslova M. V., Shchukina E. S.
ArticleAuthorData

Establishment of the Russian Academy of Sciences I. V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials of the Kola Science Centre of the Russian Academy of Sciences, Apatity, Russia:

L. G. Gerasimova, Chief Research Assistant, e-mail: gerasimova@chemy.kolasc.net.ru
A. I. Nikolaev, Head of Laboratory
M. V. Maslova, Leading Research Assistant
E. S. Shchukina, Research Assistant

Abstract

Studied are conditions of synthesizing frame-structured titanium-containing exchanger with a structure similar to ivanyukite out of (NH4)2TiO(SO4)2·H2O salt. To increase hydrolysis stability, partial reduction of initial solution has been fulfilled by electrochemical method with Ti4+ conversion to Ti3+. This expedient allows avoiding an amorphous phase generation and directing the process to creation of crystalline ivanyukite in a form of two structural modifications: trigonal (Na4(TiO)4(SiO4)3.6H2O) and cubic (Na3H(TiO)4(SiO4)3·4H2O); the precipitate crystallinity degree is 90–95%. Crystallization proceeds under five times system oversaturation by sodium silicate. Determined have been optimal conditions for titanium- siliceous precursor sol-gel obtaining and consequent hydrothermal transformation of the obtained gel to crystalline phase: content of Ti2O3 in the solution after reduction is 30–45 g/l, molar ratio TiO2:SiO2 = 1:4. It has been shown that the pore system (total volume of pores) of crystalline ivanyukite particles is approximately 1.5 times larger than that of X-ray amorphous samples and that it is mainly represented by mesopores of medium size, which are characterized by the most activity in sorption processes. Natrium and potassium ions situated in the ivanyukite frame space along with water provide high exchange velocity of cations absorption in sorption processes due to minimal diffusive obstacles. The reported preliminary data on sorption allow to describe the frame-structured crystalline alkaline titanosilicates as effective sorbents of cations of non-ferrous metals, strontium, as well as univalent cations, caesium in particular.

The research has been implemented thanks to the grant of the Russian Science Foundation (project No. 17-19-01522).

keywords Titanium-containing sorbents, titanosilicates, synthesis, sol-gel process, crystallization, surface behaviour, sorption kinetics, uni- and bivalent cations
References

1. Gerasimova L. G., Maslova M. V., Shchukina E. S. Sphen concentrate technology with titanium salts obtaining. Khimicheskaya tekhnologiya. 2008. No. 6. pp. 241–246.
2. Maslova M.V., Rusanova D., Naydenov V., Antzutkin O., Gerasimova L. G. Extended study on synthesis of amorphous titanium phosphates with tailored sorption properties. Journal of Non-Crystalline Solids. 2012. Vol. 358. pp. 2943–2950.
3. Gerasimova L. G., Nikolaev A. I., Maslova M. V., Yakovenchuk V. N., Ivanyuk G. Yu., Krivovichev S. V. Method of processing titanium-containing concentrate. Patent RF, No. 2467953, IPC C01G 23/00, C22B 3/08 (2006.01). Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials (Kola Science Center RAS). No. 2011127614/05. Applied: 05.07.11. Published: 27.11.12. Bulletin No. 33.
4. Gerasimova L. G., Maslova M. V. Titanium hydroxides and compositions on their basis. Obtaining and use. Moscow : LLC «Izdatel’stvo LKM-press». 2011. 86 p.
5. L. Gerasimova, M. Maslova, A. Nikolaev, E. Shchukina. Alkali titanosilicates from titanite. Production and properties. AMAM-2015, Taranto, Italy, June 7–12, 2015 Scientific research abstracts. 2015. Vol. 4. p.114.
6. Yanicheva N.Yu., Ganicheva Ya.Yu., Kalashnikova G. O. Prospects of use of titanium raw materials in Kola Peninsula for synthesis of microporous titanium silicates. Materials of the XIX Inter-region scientific-technical conference «Scientificpractical problems in chemistry and chemical technologies». Apatity, 15–17 April 2015. Apatity: Izdatelstvo KNTs RAN, 2015. pp. 21–24.
7. Dimova L. M. Inorganic ion exchangers. Irkutsk: Izdatelstvo IGU, 2012. 62 p.
8. Maslova M. V., Chugunov A. S., Gerasimova L. G., Konovalova N. V. Acid-base and sorption properties of amorphous titanium phosphate. Radiokhimiya. 2013. No. 4. pp. 323–328.
9. Lu Lv, Fabing Su, X. S. Zhao. A reinforced study on the synthesis of microporous titanosilicate ETS-10. Microporous and mesoporous materials. 2004. Vol. 76. pp. 113–122.
10. Zhaoxia Ji, Bilge Yilmaz, Juliusz Warzywoda, Albert Sacco Jr. Hydrothermal synthesis of titanosilicate ETS-10 using Ti(SO4)2. Microporous and mesoporous materials. 2005. Vol. 81. pp. 1–10.
11. Hsuan-Fu Yu, Shenq-Min Wang. Effects of water content and pH on gel-derived TiO2–SiO2. Journal of Non-Crystalline Solids. 2000. Vol. 261, Iss. 1–3. pp. 260–267.
12. Yakovenchuk V. N., Nikolaev A. I., Selivanova E. A., Pakhomovsky Ya. A., Korchak Yu. A., Spiridonova D. V., Zalkind O. A., Krivovichev S. V. Ivanyukite–Na–T, ivanyukite–Na–C, ivanyukite–K and ivanyukite–Cu: New microporous titanosilicates from the Khibiny massif (Kola Peninsula, Russia) and crystal structure of ivanyukite–Na–T. American Mineralogist. 2009. Vol. 94. pp. 1450–1458.
13. Yanicheva N. Yu., Kalashnikova G. O. Synthetic ivanyukite — perspective ion-exchange material. Vestnik Murmanskogo GTU. 2014. Vol. 17, No. 1. pp. 106–111.
14. Ludmany A., Nagy L. G. Preparation, characterization and application of titanium phosphate inorganic sorbents. Radiochemical and Radioanalytical Letters. 1982. Vol. 51, No. 5. pp. 301–310.

Full content Synthesis of a titanium (IV)-based sorbent and potentialities of its usage for extracting cations of non-ferrous metals
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