Журналы →  CIS Iron and Steel Review →  2011 →  №1 →  Назад

Название Formation of highly resistant carbide and boride coatings by a dual-stage deposition method
Автор W. I. Sawich, O. G. Cherneta, A. N. Korobochka, A. B. Sychkov, A. M. Nesterenko, V. L. Pliuta, M. A. Murikov.
Информация об авторе

University of Guelph (Guelph, Canada):

W.I. Sawich

 

Dneprodzerzhinsk Technical University (Dneprodzerzhinsk, Ukraine):

O.G. Cherneta

A.N. Korobochka

 

East-European Metallurgical Division of JSC Mechel (Tyrgoviste, Romania):

A.B. Sychkov

 

Iron and Steel Institute of the National Academy of Sciences of the Ukraine (Dnepropetrovsk, Ukraine):

A.M. Nesterenko

V.L. Pliuta

 

RUP “Byelorussian Steel Works” (Zhlobin, Belarus):

M.A.Murikov, ofwork@bmz.gomel.by

Реферат

A study of the aspects of forming highly resistant coatings in the surface zone of tool steels and solid carbide inserts by a dual-stage method was made. At the first stage of the method, pure Ta or Nb coatings were electrolytically deposited on samples of tool steel and solid carbide insert in a molten salt bath containing Ta and Nb fluorides. At the second stage, the electrically deposited coating of Ta (Nb) was subjected to carburizing or boriding to form carbide (TaC, NbC) or boride (TaB, NbB) cladding layers.

It has been found that formation of cladding layers consisting of highly resistant carbide (boride) phases in the surface zone of the samples under study is determined by the carbon (boron) atoms outsourcing, that the carbide (boride) coatings deposited by the disclosed method have a higher specific density (free of pores, subsurface cracks and other defects) and a better bond to the base metal, that the intensive outsourcing of carbon (boron) atoms prevents decarburization of the surface zone in the material under study – tool steel and solid carbide insert for cutting tools, that the required thickness and high surface quality of the coating provided by the invented method are insured by the controlled conditions of the electrochemical deposition, including conditions at the initial stage of the process and that the application of the invented method looks promising for producing strengthened working surfaces on replaceable parts in the mining mining-metallurgical equipment, on rolls and guides of cogging and section mills, and on parts of internal combustion engines (ICE).

Machining operations tests carried out to check the durability of cutting tool inserts covered with TaC deposited by the invented method, have demonstrated efficiency of these inserts for finishing cuts. The invented method has been found to be promising for extending the service life of parts in the mining-metallurgical and machine-building equipment.

Ключевые слова Dual-stage deposition, high resistance, carbide and boride coatings, electrically deposited coatings, tool steels, cladding layers
Библиографический список

1. Samsonov G. V., Vinitskiy I. M. Refractory metal compounds (Handbook), М.: Metallurgiya, 1976. p. 560.

2. Merle E. Sibert, John T. Burwull. Electrolytic cladding process. U.S. Patent 2828251. Patented March 25, 1958. Application Sept.. 30, 1953. Serial № 383401.

3. Morris A. Steinberg, Robert G. Mc.Allen. Production of hard surfaces on base metals. U.S. Patent 2950233. Patented Aug. 23, 1960. Filed Apr. 29,1954. Serial № 429553.

4. Walter Sawich. Deposition and thermal diffusion of borides and carbides of refractory metals. U.S. Patent 6458218 B1. Patented Oct. 1, 2002. Application № 09/759299. Filed Jan. 16, 2001.

5. «TD Tool Coating Process Extends Die Life Rework By More than Six Fold for Athletic Locker Manufacturer, List Industries». Modern Application News. July 2003.

6. Levchenko G. V., Nesterenko A. M., Plyuta V. L., Svistelnik O. Y. Combined type wear resistant interchangeable parts for the equipment used in the mining and metallurgical industry. Bulletin “Chernaya Metallurgiya” (“Ferrous Metallurgy”). М. OJSC «Chermetinformatsiya» 2010. Issue 5. p. 27-30.

7. Vorontsov N. M., Zhadan V. T., Shneerov V. Ya., Pavlovskiy V. Ya., Kulak Yu. E., Unin N. V., Handling of cogging mill and section mill rolls. M.: Metallurgiya, 1973. p. 288.

8. Severdenko V. P., Bakhtinov Yu. B., Bakhtinov V. B. Rolls for structural steel products. M.: Metallurgiya, 1979. p. 224.

9. Cherneta O. G., Korobochka O. M. High efficiency materials and coatings for manufacturing and repairing automobile parts. Workbook. DneprodzerzhinskTechnical University. Dneprodzerzhinsk. 2008. p. 143.

Полный текст статьи Formation of highly resistant carbide and boride coatings by a dual-stage deposition method
Назад