Institute of Chemistry of Far East Division of Russian Academy of Sciences | |
Название | Prospects of gold mining from technogenic objects of Nagima deposit |
DOI | 10.17580/tsm.2015.03.16 |
Автор | Ageev O. A., Medkov M. A., Ivannikov S. I., Yudakov A. A. |
Информация об авторе | Amur Scientific Center of Far East Division of Russian Academy of Sciences, Blagoveshchensk, Russia: O. A. Ageev, Head of Department of Complex Use of Mineral Raw Materials and Innovation Developments, e-mail: vip.ageev2014@mail.ru
Institute of Chemistry of Far East Division of Russian Academy of Sciences, Vladivostok, Russia: M. A. Medkov, Head of Laboratory of Processing of Mineral Raw Materials, e-mail: medkov@ich.dvo.ru S. I. Ivannikov, Junior Researcher, Laboratory of Sorption Processes A. A. Yudakov, Deputy Executive Officer on Scientific Work and Innovations (Engineering-Technological Center) |
Реферат | ammonium thiosulfate leaching method, which allows to extract up to 97% of gold in solution: 0.1 mol/l of sodium thiosulfate; 0.2 mol/l of aqueous solution of ammonia; 0.015 mol/l of copper sulfate; pH = 10.4, L:S = 1:2. Anion-exchange resin AB-17 showed the best results in gold precipitation from solution leaching. Extraction rate without adjustment of pH at L:S = 1:100 reached 95%. The optimum composition of leaching solution for thiocarbamide leaching method, allowing to extract up to 93% of gold in solution, was established: 30 g/l of thiocarbamide; 10 g/l of sulfuric acid; 2 g/l of ferric chloride; 20 g/l of peroxodisulfate ammonium; L:S = 1:3. Method of electrochemical deposition on carbon fiber cathode showed the best results during the gold precipitation from leaching solution. Graphite rod was used as shunt. Efficiency of gold extraction on carbon material from leaching solution reached 95%, at the current density of 300 A/m2. This work was carried out with the financial support of the Ministry of Education and Science of Russian Federation (agreement No. 02. G25.31.0035) and the grant of the Presidium of Far East Division of Russian Academy of Sciences (project No. 15-I-3-014). This work was carried out with the financial support of the Ministry of Education and Science of Russian Federation (agreement No. 14.578.21.0015 of June 05, 2014. Unique identifier of the agreement is RFMEFI57814X0015). |
Ключевые слова | Technogenic deposits, gold, assay analysis, neutron-activation analysis, ammonia-thiosulfate leaching, thiocarbamide leaching |
Библиографический список | 1. Lokerman A. A. Rossypnye mestorozhdeniya zolota (Iz istorii odnogo otkrytiya) (Placer deposits of gold (From the history of one invention)). Novoe v zhizni, nauke, tekhnike. Seriya “Nauka o Zemle” = New in life, science, technology. Series “Earth Science”. 1997. No. 1. 48 p. 2. Kavchik B. K., Pyatakov V. G. Geologicheskoe stroenie tekhnogennykh rossypey i ego vliyanie na vybor sposoba otrabotki (Geological structure of technogenic placers and its influence on the choice of mining method). Zolotodobycha = Gold mining. 2010. February, No. 135. 3. Sorokin A. P., Belousov V. I., Kuzminykh V. M., Artemenko T. V. Raspredelenie tonkogo i melkogo zolota v paleogen-neogenovykh rossypyakh Verkhnego Priamurya (Distribution of fine gold in paleogene and neogene placers of Upper Amur River region). Gornyy Informatsionno-Analiticheskiy Byulleten = Mining Informational-Analytical Bulletin. 2007. No. 16. pp. 123–130. 4. Zamyatin O. V. Melkoe zoloto v rossypyakh i osnovnye puti snizheniya ego poter (Fine gold in placers and basic ways of its losses decreasing). Zolotodobycha = Gold mining. No. 10. pp. 16–17. 5. Khanchuk A. I., Berdnikov A. A., Cherepanov A. A. Tonkodispersnoe zoloto i platinoidy v grafitovykh slantsakh Bureyskogo massiva — novyy tip blagorodno-metallnogo orudeneniya na Dalnem Vostoke Rossii (Finedisperse gold and platinoids in graphite shales of Burey massif – new type of noble-metal mineralization at Russian Far East). Gornyy Informatsionno-Analiticheskiy Byulleten. Dalniy Vostok-2 = Mining Informational-Analytical Bulletin. Far East-2. 2009. pp. 9–18. 6. Shilo N. A., Ippolitov E. G., Ivanenko V. V., Kustov V. N., Zheleznov V. V., Aristov G. N., Shtan A. S., Ivanov I. N., Kovalenko V. V., Kondratev N. B. Instrumental neutron activation determination of gold in mineral raw materials using a californium neutron source. Journal of Radioanalytical and Nuclear Chemistry. 1983. Vol. 79. pp. 309–316. 7. Instruktsiya NSAM №242-yaf. Neytronno-aktivatsionnoe opredelenie zolota v probakh zolotokvartsevykh rudnykh mestorozhdeniy s ispolzovaniem kalifornievogo istochnika i stsintillyatsionnogo spektrometra (Instruction NSAM No.242-yaf. Neutron-activation definition of gold in the samples of gold-quarts ore deposits using californium source and scintillation spectrometer). Moscow : Ministry of Geology of USSR, 1987. 8 p. (in Russian) 8. Zheleznov V. V., Medkov M. A., Krysenko G. F., Epov D. G., Ivannikov S. I., Molchanov V. P., Medvedev E. I. Sposob opredeleniya zolota v rudakh i produktakh ikh pererabotki (Method of gold definition in ores and their processing products). Patent RF, No. 2494378. Applied: 2011.10.13. Published: 2013.09.27. Bulletin of inventions No. 27. 9. Valiev N. G. Nauchno-metodicheskie i tekhnologicheskie osnovy gidromekhanizirovanoy podgotovki zolotosoderzhashchikh porod dlya izvlecheniya melkogo zolota : dissertatsiya doktora tekhnicheskikh nauk (Scientificmethodical and technological basis of hydro-mechanized preparation of gold-bearing ores for fine gold extraction: Dissertation of Doctor of Engineering Sciences). Ekaterinburg : Ural State Mining-Geological Academy, 2002. pp. 27–36. 10. Aylmore M. G., Muir D. M. Thiosulfate leaching of gold — а review. Minerals Engineering. 2001. Vol. 14. pp. 135–174. 11. Klimantsev V. S., Voronina O. B., Kononova O. N., Kholmogorov A. G. Issledovanie sorbtsionnogo izvlecheniya zolota iz rud Olimpiadinskogo mestorozhdeniya. Sorbtsiya zolota iz tiosulfatnykh rastvorov (Research of sorption extraction of gold from Olimpiadinskoe deposit ores. Sorption of gold from thiosulfate solutions). Vestnik Krasnoyarskogo gosudarstvennogo universiteta. Seriya “Estestvennye Nauki” = Bulletin of Krasnoyarsk State University. Series “Natural Sciences”. 2003. No. 2. pp. 143–148. 12. Radomskaya V. I., Loseva O. V., Radomskiy S. M. Primenenie tiomocheviny dlya kontsentrirovaniya zolota iz vtorichnogo syrya (Application of thiourea for gold concentration from secondary raw materials). Vestnik Dalnevostochnogo otdeleniya Rossiyskoy Akademii Nauk = Bulletin of Far East Division of Russian Academy of Sciences. 2004. No. 1. pp. 80–86. 13. Haas l. A. Thiourea leaching of carbonaceous gold ores. Mining Engineering. 1983. May. p. 462. |
Language of full-text | русский |
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