Журналы →  Tsvetnye Metally →  2015 →  №10 →  Назад

LIGHT METALS, CARBON MATERIALS
Название Baked anode design improvement
DOI 10.17580/tsm.2015.10.11
Автор Lysenko A. P., Kirov S. S., Selnitsyn R. S., Nalivayko A. Yu.
Информация об авторе

National University of Science and Technology “MISiS”, Chair of Nonferrous Metals and Gold, Moscow, Russia:

A. P. Lysenko, Assistant Professor, e-mail: reikis@yandex.ru
S. S. Kirov, Assistant Professor
R. S. Selnitsyn, Engineer
A. Yu. Nalivayko, Leading Electronic Engineer

Реферат

This article tells about the research of influence of baked anode block design in aluminum electrolytic cell on its operating characteristics. Different types of аnodes were considered: classic (solid) anode; anode with gas-outlet hole without sacrificial coating; and anode with gas-outlet hole, protected by alundum insert. The electrolytic cell operation was analyzed using various types of anode blocks. The reduction mechanism of application efficiency of anodes with unprotected gas-outlet holes was defined, while the method for removing of this reduction was offered. Material application for sacrificial protection of gas-outlet element of baked aluminum electrolytic cell anode was proposed and substantiated. The experimental setup diagram was developed and shown for assessment of application efficiency of baked anode with various designs. There are shown the experimental data about aluminum obtaining by cryolite-aluminous melt electrolysis using various design anode. The application advantage of baked anode with alundum inset protected gas-outlet hole is shown regarding the solid anode, expressed in energy saving, electrolytic bath voltage reduction and current efficiency growth.
This work was carried out with the financial support of the Ministry of Education and Science of Russian Federation within the fulfillment of the obligations under the Subsidy Agreement of October 23, 2014. No. 14.578.21.0072 (unique identifier of Agreement is RFMEFI57814X0072).

Ключевые слова Coating, sacrificial protection, carbon base, electrolytic cell, aluminum electrolytic cell, anode with gas-outlet element, coal foam, carbon consumption, operation indicators
Библиографический список

1. Кiss L. L., Poncsak S., Antille J. Simulation of the bubble layer in aluminum electrolysis cells. Light Metals. 2005. 559 р.
2. Thorne R. J., Sommerseth C., Ratvik A. P., Linga H., Svensson A. M. Bubble evolution and anode surface properties in aluminium electrolysis. Journal of the Electrochemical Society. 2015. Vol. 162 (8). pp. E104–E114.
3. Wang Y.-L., Tie J., Tu G.-F., Zhao R.-T., Zhang Z.-F. Effect of gas bubble on cell voltage oscillations based on equivalent circuit simulation in aluminum electrolysis cell. Transactions of Nonferrous Metals Society of China (English Edition). 2015. Vol. 25 (1). pp. 335–344.
4. Richards N., Gudbrandsen H., Rolseth S., Thonstad J. Characterization of the fluctuation in anode current density and “bubble events” in industrial reduction cells. Light Metals. 2003. pp. 315-322.
5. Wang Y., Tie J., Tu G., Zhao R., Zhang Z. Dynamic Simulation of Cell Voltage Resonance Effect in Aluminum Electrolysis Cell. Light Metals. 2014. pp. 697–702.
6. Lysenko A. P., Kirov S. S., Selnitsyn R. S., Nalivayko A. Yu. Vliyanie konstruktsii obozhzhennykh anodov na effektivnost gazootvoda i tekhnicheskie pokazateli protsessa elektroliza alyuminiya (Influence of baked anode design on gas-outlet efficiency and specification figures of aluminium electrolysis process). Tsvetnye Metally = Non-ferrous metals. 2013. No. 9. pp. 115–117.
7. Vetyukov M. M., Tsyplakov A. M., Shkolnikov S. N. Elektrometallurgiya alyuminiya i magniya (Electrometallurgy of aluminium and magnesium). Moscow : Metallurgiya, 1987. 320 p.
8. Baymakov Yu. V., Vetyukov M. M. Elektroliz rasplavlennykh soley (Electrolysis of fused salts). Moscow : Metallurgiya, 1966. 400 p.
9. Moskvitin V. I., Nikoleav I. V., Fomin B. A. Metallurgiya legkikh metallov (Metallurgy of light metals). Moscow : Intermet Inzhiniring, 2005.
10. Lysenko A. P., Kirov S. S., Selnitsyn R. S., Nalivayko A. Yu. Elektrokhimicheskiy sintez diborida titana iz kriolitovykh rasplavov na ugolnom elektrode (Electrochemical synthesis of cryolite melt titanium diboride on coal electrode). Tsvetnye Metally = Non-ferrous metals. 2014. No. 5. pp. 44–48.
11. Lysenko A. P., Selnitsyn R. S. Elektrolizer dlya proizvodstva alyuminiya (Electrolytic cell for aluminium production). Patent RF, No. 2485216. Published: June 20, 2013. Bulletin No. 17.
12. Earnshaw A.,Greenwood N. Chemistry of the Elements. US : Butterworth-Heinemann, 1997. 297 p.

Language of full-text русский
Полный текст статьи Получить
Назад