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LIGHT METALS, CARBON MATERIALS
Название Waste water treatment using silica-alumina sorbents
DOI 10.17580/tsm.2015.12.07
Автор Sviridov A. V., Ganebnykh E. V., Maltsev G. I., Timofeev K. L.
Информация об авторе

JSC Research Center “Uralelektromed”, Verkhnyaya Pyshma, Russia:

A. V. Sviridov, Assistant Professor
E. V. Ganebnykh, Post-Graduate Student
G. I. Maltsev, Chief Specialist, e-mail: mgi@elem.ru
K. L. Timofeev, Chief Hydrometallurgist

Реферат

One of the possible ways to increase the efficiency of waste w ater treatment technologies is the use of new highly disperse sorbents acting as sorbentscoprecipitators of toxic components, which basis are natural silica-alumina, which surface is modified by inorganic and organic substances (in particular, montmorillonite MMT). During the sorbent synthesis, their sorption, electric-surface, hydrophilic-oleophilic and rheological properties were adjusted by varying the nature and concentration of the modifiers, such as: soda ash; sodium aluminate; sodium ferrate; polyphosphates; organic compounds, containing carboxyl and ether groups. The reagent “Ecosol-401” (“Экозоль-401”) was obtained on MMT basis, containing carboxyl groups. During metal extraction from solutions of JSC "Uralelektromed", the best results were reached with a dosage of 65 mg/dm3 of reagent “Ecosol-401”, together with 0.2 mg/dm3 of flocculant “Praestol 650 TR” (“Праестол 650 ТР”) by the technology of contact lightening of treated water carried on loading from quartz sand (loading height is 210 mm, equivalent diameter of silica sand grains is 1.5–2.0 mm, column diameter is 30 mm) at filtration rate of 2.5 dm3/hour. Residual concentrations of metal impurities meet the environmental discharge standards.

Ключевые слова Sorbent, precipitant, flocculant, waste waters, copper, nickel, zinc
Библиографический список

1. Available at: http://www.rg.ru/2006/06/08/voda-kodeks.html (in Russian).
2. Hamidiana А., Ghorbanib М., Abdolshahnejadc М. Qanat. Traditional Eco-Technology for Irrigation and Water Management. Agriculture and Agricultural Science Procedia. 2015. Vol. 4. pp. 119–125.
3. Stojkovi I. J., Stamenkovi O. S., Povrenovi D. S., Veljkovi V. B. Purification technologies for crude biodiesel obtained by alkali-catalyzed transesterification. Renewable and Sustainable Energy Reviews. 2014. Vol. 32. pp. 1–15.
4. Ermakov D. V., Sviridov A. V., Ibatulina Yu. R. Izvlechenie kationov medi (II) s pomoshchyu kolloidnykh sorbentov (Extraction of copper (II) cations using colloid sorbents). Izvestiya Chelyabinskogo nauchnogo tsentra = Proceedings of Chelyabinsk Science Center. 2004. No. 1 (22). pp. 164–168.
5. Vezentsev A. I. Issledovanie effektivnosti sorbtsii ionov Cu (II) i Pb (II) nativnymi formami montmorillonitovykh glin Belgorodskoy oblasti (Investigation of sorption efficiency of Cu (II) and PB (II) ions by native form of montmorillonite clays of Belgorod Oblast). Sorbtsionnye i khromatograficheskie protsessy = Sorption and chromotographic processes. 2008. Vol. 8, Iss. 5. pp. 807–811.
6. Ergozhin E. E., Akimbaeva A. M. Otsenka sorbtsionnoy sposobnosti montmorillonita i anionita na ego osnove po otnosheniyu k ionam svintsa (II) (Assessment of sorption ability of montmorillonite and anionite on its basis according to the lead (II) ions). Tsvetnye Metally = Non-ferrous metals. 2005. No. 3. pp. 39–42.
7. Bhattacharrya K. G., Gupta S. S. Removal of Cu (II) by natural and acid-activated clays: An insight of adsorpion isotherm, kinetic and thermodynamics. Desalination. 2011. Vol. 272, No. 1–3. pp. 66–75.
8. Kormosh E. V. Modifitsirovanie montmorillonitsoderzhashchikh glin dlya kompleksnoy sorbtsionnoy ochistki stochnykh vod : avtoreferat dissertatsii … kandidata tekhnicheskikh nauk (Modification of montmorillonitecontaining clays for the complex sorption waste water treatment : thesis of Inaugration of Dissertation ... of Candidate of Engineering Sciences). Belgorod, 2009. 20 p.
9. Zhu Z., Gao C., Wu Y., Sun L. Removal of heavy metals from aqueous solution by lipopeptides and lipopeptides modified Na-montmorillonite. Bioresource Technology. 2013. Vol. 147. pp. 378–386.
10. Sviridov A. V., Ermakov D. V., Elizarov V. A., Ganebnykh E. V. Issledovanie protsessov sorbtsii kationov nikelya i geterokoagulyatsii pri vzaimodeystvii s vysokodispersnymi alyumosilikatami (Investigation of the processes of sorption of nickel cations and heterocoagulation during the interaction with high-disperse silica-alumina). Ekologicheskaya bezopasnost gosudarstv — chlenov Shankhayskoy organizatsii sotrudnichestva i X Mezhdunarodnyy simpozium i vystavka “Chistaya voda Rossii – 2008” : sbornik materialov (Environmental safety of the Shanghai Cooperation Organisation countries and the X International symposium and exhibition “Pure water of Russia – 2008” : collection of materials). Ekaterinburg : Russian Scientific-Research Institute of Complex Use and Protection of Water Resources (RosNIIVKh), 2008. pp. 574–580.
11. Lee S. K., Sung S. The effect of network-modifying cations on the structure and disorder in peralkaline Ca – Na aluminosilicate glasses: O-17 3QMAS NMR study. Chemical Geology. 2008. Vol. 256, Iss. 3/4. pp. 326–333.
12. Thompson L. M., Stebbins J. F. Non-stoichiometric non-bridging oxygens and five-coordinated aluminum in alkaline earth aluminosilicate glasses: Effect of modifier cation size. Journal of Non-Crystalline Solids. 2012. Vol. 358, Iss. 15. pp. 1783–1789.
13. Lee S. K., Stebbins J. F. Disorder and the extent of polymerization in calcium silicate and aluminosilicate glasses: O-17 NMR results and quantum chemical molecular orbital calculations. Geochimica et Cosmochimica Acta. 2006. Vol. 70, Iss. 16. pp. 4275–4286.
14. Akimbaeva A. M., Ergozhin E. E., Tovasarov A. D. Sorbtsiya ionov medi (II) organomineralnym kationitom na osnove bentonita (Sorption of copper (II) ions by organic-mineral bentonite-based cationite). Uspekhi sovremennogo estestvoznaniya = Advances in Current Natural Sciences. 2006. No. 4. pp. 23–25.
15. Sviridov V. V., Sviridov A. V. Sposob ochistki prirodnykh i stochnykh vod, soderzhashchikh iony zheleza tyazhelykh i tsvetnykh metallov (Method of purification of natural and waste waters, containing iron ions of heavy and non-ferrous metals). Patent RF, No. 2118296. Applied : April 14, 1995. Published : August 27, 1998. Bulletin No. 26.
16. Korobeynikova E. Yu., Avtonomova A. Yu., Merkulov D. A. Geteroligandnoe kompleksoobrazovanie medi (II) s 2-fosfobutan 1, 2, 4-trikarbonovoy kislotoy i karbonovymi kislotami v vodnykh rastvorakh (Heteroligand complex formation of copper (II) with 2-phosphobutane 1, 2, 4-tricarbon acid and carbon acids in water solutions). Vestnik Udmurtskogo universiteta = Bulletin of Udmurt University. 2012. Iss. 2. pp. 61–68.
17. Galkin Yu. A., Epshteyn S. I. Opredelenie gidravlicheskikh parametrov kamery flokulyatsii otstoynika-flokulyatora (Definition of hydraulic parameters of precipitation flocсulator tank flocсulation chamber). Ekologiya i promyshlennost Rossii = Ecology and Industry of Russia. 2009. No. 2. pp. 38–42.

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