Название |
Composite physicochemical and energy action on geomaterials and aqueous slurries: theory and practice |
Информация об авторе |
Institute of Integrated Mineral Development – IPKON, Russian Academy of Sciences, Moscow, Russia:
I. Zh. Bunin, Leading Researcher, Doctor of Engineering Sciences, Candidate of Physico-Mathematical Sciences, bunin_i@mail.ru M. V. Ryazantseva, Senior Researcher, Candidate of Engineering Sciences A. L. Samusev, Senior Researcher, Candidate of Engineering Sciences I. A. Khabarova, Senior Researcher, Candidate of Engineering Sciences |
Реферат |
The main results of the theoretical and experimental studies on the directional modification of the surface phase composition as well as the structural, chemical and process properties of non-ferrous, rare and noble metals under physicochemical and pulse energy impact are presented. The main mechanisms of the surface micro- and nanophases formation for the increase in the yield and quality of concentrates during processing of rebellious ore with the complex material constitution are revealed. The rational parameters and conditions for preliminary treatment of sulfide minerals by high-power (high-voltage) nanosecond electromagnetic pulses in order to increase the flotation separation selectivity of sulphides with the similar physicochemical properties, such as pyrite–arsenopyrite, pyrrhotite–pentlandite and chalcopyrite–sphalerite, due to contrast changes in the chemical and phase surface composition, hydrophobicity, sorption activity and floatability of minerals, are determined and experimentally proved. The high efficiency of application of the pulsed energy impact and electrochemically treated water systems is demonstrated in terms of the directional change in the properties of rock-forming minerals of kimberlites and preservation of diamond crystals during milling. The described results confirm the effectiveness of the electrochemical treatment application to mineral suspensions and aqueous systems under leaching of sulphide copper–zinc ore and rebellious gold-bearing concentrate. The study has been supported by the Academician Chanturia School, Grant NSH-7608.2016.5. The authors appreciate participation of Candidate of Engineering Sciences V. G. Minenko, Candidate of Geologo-Mineralogical Sciences E. V. Koporulina, Candidate of Engineering Sciences E. S. Zhuravleva and Leading Engineer N. E. Anashkina, IPKON RAS. |
Библиографический список |
1. Chanturiya V. A., Bocharov V. A. Modern state and basic ways of technology development for complex processing of non-ferrous mineral raw materials. Tsvetnye Metally. 2016. No. 11. pp. 11–18. DOI: 10.17580/tsm.2016.11.01 2. Chanturiya V. A., Gulyaev Yu. V., Lunin V. D. et al. Opening of refractory gold-bearing ores with influence of powerful electromagnetic pulses. Doklady AN. 1999. Vol. 366, No. 5. pp. 680–683. 3. Bunin I. Zh., Bunina N. S., Vdovin V. A. et al. Experimental study of nonthermal influence of powerful electromagnetic pulses on rusty gold-bearing minerals. Izvestiya RAN. Seriya fizicheskaya. 2001. Vol. 65, No. 12. pp. 1788–1792. 4. Chanturiya V. A., Bunin I. Zh., Ryazantseva M. V., Filippov L. O. Theory and application of high-power nanosecond pulses to processing of mineral complexes. Mineral Processing and Extractive Metallurgy Review. 2011. Vol. 32. No 2. pp. 105–136. 5. Rostovtsev V. I. Technological and economic effect of nonmechanical energy use in rebellious mineral processing. Fiziko-tekhnicheskie problemy razrabotki poleznykh iskopaemykh. 2013. No. 4. pp. 145–155. 6. May F., Hamann S., Quade A., Brüser V. Study on Cu2S mineral surface modification by low temperature Ar/O2 plasmas. Minerals Engineering. 2013. Vol. 50-51. pp. 48–56. 7. Hirajima T., Mori M., Ichikawa O, et al. Selective flotation of chalcopyrite and molybdenite with plasma. Minerals Engineering. 2014. Vol. 66-68. pp. 102–111. 8. Parker T., Shi F., Evans C., Powell M. The effects of electrical comminution on the mineral liberation and surface chemistry of a porphyry copper ore. Mineral Engineering. 2015. Vol. 82, No. 10. pp. 101–106. 9. Aditya S., Tapas K. N., Samir K. P., Arun K. M. Pre-treatment of rocks prior to comminution – A critical review of present practices. International Journal of Mining Science and Technology. 2017. Vol. 27, No. 2. pp. 339–348. 10. Cherepenin V. A. Relativistic multiwave oscillators and their possible applications. Uspekhi fizicheskikh nauk. 2006. Vol. 176, No. 10. pp. 1124–1130. 11. Kuzmenko A. P., Leonenko N. A., Khrapov I. V. Defragmentation, thermo-capillar extraction and agglomeration of ultradisperse inclusions in mineral and technogenic raw materials during the laser treatment. Kursk : ZAO Universitetskaya kniga, 2014. 137 p. 12. Chanturiya V. A., Minenko V. G., Kaplin A. I., Samusev A. L., Chanturiya E. L. Electrochemical technology of water preparation during Cu-Zn ores leaching. Tsvetnye Metally. 2011. No. 4. pp. 11–15. 13. Samusev A. L., Minenko V. G. Effects of sulfate-ions on the quality of electrochemical leaching of gold from rebellious minerals. Gornyy informatsionno-analiticheskiy byulleten. 2016. No. 10. pp. 276–282. 14. Chanturiya V. A., Bunin I. Zh., Kovalev A. T. Energy concentration in electric discharges between particles of semiconducting sulfide minerals under the action of high-power nanosecond pulses. Izvestiya RAN. Seriya fizicheskaya. 2008. Vol. 72, No. 8. pp. 1118–1121. 15. Chanturiya V. A., Ivanova T. A., Khabarova I. A., Ryazantseva M. V. Effect of ozone on physico-chemical and flotation properties of surface of pyrrhotite under the nanosecond electromagnetic pulse treatment. Fiziko-tekhnicheskie problemy razrabotki poleznykh iskopaemykh. 2007. No. 1. pp. 91–99. 16. Ryazantseva M. V. Mechanism of effect of nanosecond electromagnetic pulses on structural-chemical and flotation properties of pyrite and arsenopyrite : Dissertation … of Candidate of Engineering Sciences. Moscow : IPKON RAN, 2009. 111 p. 17. Khabarova I. A. Increasing of contrast range of physical-chemical and flotation properties of pyrrhotite and pentlandite on the basis of use of electromagnetic pulse effect : Dissertation … of Candidate of Engineering Sciences. Moscow: IPKON RAN, 2011. 112 p. 18. Chanturiya V. A., Nazarova G. N. Electrochemical technology in concentration and hydrometallurgical processes. Moscow : Nauka, 1977. 160 p. 19. Chanturiya V. A., Vigdergauz V. E. Electrochemistry of sulfides. Theory and practice of flotation. Moscow : IPKON RAN, 2008. 272 p. 20. Chanturiya E. L. Theoretical aspects of electrochemical methods of water preparation in the conditions of flotation of rare-metal raw materials. Complex processing of mineral raw materials. 1992. pp. 165– 174. 21. Zyryanov M. N., Leonov S. B. Chloride metallurgy of gold. Moscow : SP Intermet Engineering, 1997. 288 p. 22. Khalezov B. D. Investigations and development of technology of heap leaching of copper and copperzinc ores : Dissertation … of Doctor of Engineering Sciences. Ekaterinburg, 2008. 548 p. 23. Samusev A. L., Minenko V. G. Influence of chemical-electrochemical leaching parameters on gold recovery from rebellious minerals. Gornyy informatsionno-analiticheskiy byulleten. 2016. No. 5. pp. 301–308. 24. Garrels R. M., Christ Ch. L. Solutions, Minerals and Equilibria. New York: Harper & Row, 1965. 368 p. |