Журналы →  Tsvetnye Metally →  2018 →  №7 →  Назад

50th ANNIVERSARY OF PRIARGUNSKY INDUSTRIAL MINING AND CHEMICAL UNION
Название Indentify of the possibility of sorption concentration of scandium and rare-earth metals from return solutions at producing uranium by drillhole in situ leaching
DOI 10.17580/tsm.2018.07.01
Автор Solovev A. A., Meshkov E. Yu., Bobyrenko N. A., Parygin I. A.
Информация об авторе

JSC “VNIPIpromtechnologies”, Moscow, Russia:

A. A. Solovev, Head of the Research Laboratory of NIL-311, e-mail: solovev.a.a@vnipipt.ru
E. Yu. Meshkov, Chief Specialist of Research Laboratory of NIL-311, e-mail: meshkov.e.j@vnipipt.ru
N. A. Bobyrenko, Senior Researcher of Research Laboratory of NIL-311, e-mail: bobyrenko.n.a@vnipipt.ru
I. A. Parygin, Leading Engineer of the Research Laboratory of NIL-311, e-mail: parygin.i.a@vnipipt.ru

Реферат

Rare earth metals (REM), Sc content in process solutions, ion-exchange resins and technical production at general technological studies of processing sorption solutions at producing uranium by drillhole in situ leaching is determined. It is shown, that REM do not take by ion-exchange resin AMP, that is used in producing of ammonium polyuranates at JSC “Khiagda” and “Dalur”. The contents of REM in productive and return solutions are equal and take 40–50 mg/dm3. The contents of REM in process solutions, ion-exchange resin and commercial production are below detection limits of used chemical-analytic methods. There is no concentration REM and Sc at general technological studies because it is used ion-exchange resin of anion type on main producing of uranium, and it does not take REM and Sc, which exist mainly in cationic form in productive solutions. It is possible that REM and Sc flow with interstitial water and solutions during transportation of saturated sorbent from sorption to regeneration in revolving technological solutions. The investigations of sorption of Sc and REM from filtrate of sorption uranium by resins of LANXESS, Purolite, and The Dow Chemical Company, produced on an industrial scale nowadays were conducted. These studies gave an opportunity to select prospective kinds of resins for sorption Sc and REM from filtrate of sorption uranium.

Ключевые слова Rare-earth metals, scandium, uranium, drillhole in situ leaching, ion-exchange resins, sorption, distribution factor, separation factor
Библиографический список

1. Rare Earth Elements: A Review of Production, Processing, Recycling, and Associated Environmental Issues. Washington : United States Environmental Protection Agency, 2012. National Service Center for Environmental Publications (NSCEP). Available at: nepis.epa.govAdobePDFP100EUBC.pdf
2. Lucas J., Lucas P., Le Mercier T., Rollat A., Davenport W. Rare Earths: Science, Technology, Production and Use. Amsterdam : Elsevier, 2015.
3. Kanazawa Y., Kamitani M. Rare earth minerals and resources in the world. Journal of Alloys and Compounds. 2006. Vol. 408–412. pp. 1339–1343.
4. Gupta C. K., Krishnamurthy N. Extractive metallurgy of Rare Earths. Boca Raton : CRC Press, 2005. 537 p.
5. Soldenhoff K. Challenges in rare earth presiding. Proceedings of ALTA 2013 Uranium – REE sessions. Perth, Australia, May 30–31, 2013. p. 169. Available at: www.altamet.com.au/wp-content/uploads/2013/07/ALTA-2013-UREEProceedings-Contents-Abstracts.pdf
6. Zhukovskiy M. V., Ekidin A. A. Ural and monazite: history, ecology, perspective. Vestnik Uralskogo otdeleniya RAN. 2012. No. 1 (39). pp. 45–55.

7. Kosynkin V. D., Selivanovskiy A. K., Fedulova T. T., Smirnov K. M., Krylova O. K. Comprehensive phosphogypsum treatment with the recovery of chemically precipitated chalk, gypsum, and REE concentrate. Tsvetnye Metally. 2012. No. 3. pp. 31–34.
8. Lomaev V. G., Serdyuk S. S. Chuktukon deposit of niobium-rare-earth ores is a priority object for modernization of Russian rare-metal industry. Journal of Siberian Federal University. Engineering & Technologies. 2011. Vol. 4, No. 2. pp. 132–154.
9. Samonov A. E., Melentev G. B., Delitsin L. M. New perspectives of integrated development of natural and technogenic resources of the Khibiny mining complex. Collection of theses of Russian Conference, Annual meeting of the RMS. Mineralogical research and mineral resources of Russia. Moscow : IGEM RAS, 2007. pp. 113–116.
10. Samonov A. E. Prospects for the development of production and consumption of rare-earth products in Russia. Collection of theses of conference, annual meeting of the RMS. Typomorphic minerals and mineral associations are indicators of the scale of natural and technogenic deposits and the quality of ores. Ekaterinburg: IGG UrB RAS, 2008. pp. 140–143.
11. Kosynkin V. D., Glebov V. A. The revival of the Russian production of rareearth metals is the most important task of the domestic economy. III International Conference of Functional nanomaterials and high-purity substances. Suzdal, October 4–8, 2010.
12. Logvinenko I. A., Volkov N. I. et al. On the possibility of extracting scandium and rare-earth elements from productive solutions of PV at the Dalmatovo deposit. Underground and heap leaching of uranium, gold and other metals. Volume 1. Uranium. Moscow : Ore and Metals, 2005. pp. 199–209.
13. Golovko V. V., Solovev A. A., Meshkov E. Yu. Determining the possibility of industrial production of rare and rare-earth metals from technological solutions of complex salt composition. Collection of theses of VII International Congress “Non-Ferrous Metals and Minerals – 2015”. Section VII. Geology of metallurgy and application of REM. Krasnoyarsk, 2015. pp. 934–940.
14. Golovko V. V., Solovev A. A., Meshkov E. Yu., Kadyrov K. K. Determination of the possibility of industrial production of rare and rare-earth metals from technological solutions of complex salt composition. Proceedings of scientificpractical conference with international participation “Geotechnological methods of development of deposits of solid minerals”. Moscow : FGUP VIMS, 2016. pp. 150–156.
15. Shokobaev N. M. Development of technologies for complex processing of ores of exogenous uranium deposits with associated recovery of rhenium, scandium and rare earth metals. Dissertation of Doctor of philosophy. Almaty, 2015. 111 p.
16. Dualetbakov T. S., Shokobaev N. M., Shokobaeva G. T., Murzakhmetova U. A. Sorption extraction of rare earth metals from technological solutions of underground uranium leaching. Kompleksnoe ispolzovanie mineralnogo syrya. 2013. No. 4. pp. 57–64.

Language of full-text русский
Полный текст статьи Получить
Назад