Журналы →  Chernye Metally →  2022 →  №3 →  Назад

Ecology and Recycling
Название Assessment of the possibility of ferrous metallurgy decarbonization
DOI 10.17580/chm.2022.03.13
Автор I. V. Butorina, M. V. Butorina, A. A. Vlasov, A. V. Semenova
Информация об авторе

Peter the Great St. Petersburg Polytechnic University, St. Petersburg, Russia:

I. V. Butorina, Dr. Eng., Associate Professor, e-mail: butorina_irina@mail.ru

A. V. Semencha, Cand. Chem., Director of High School of Physics and Materials Technology

 

2 Baltic State Technical University “Voenmekh”, St. Petersburg, Russia:
M. V. Butorina, Associate Professor

 

Young Metallurgists Association, Krasnoyarsk, Russia:
A. A. Vlasov, Cand. Eng., Chairman

Реферат

The analysis of the known methods of decarbonization of the production process ferrous metals is given. It is shown that the most effective ways to reduce CO2 emissions from metallurgical enterprises into the environment are sorption from exhaust gases and replacing carbon fuel with hydrogen. However, sorption methods for capturing CO2 are too expensive due to the high cost of sorbents and are accompanied by the formation of a large amount of waste (4.5–8 t/t of rolled stock), for the placement of which large areas are required. Abandoning sinter-blast furnace production and switching to conversion metallurgy will reduce the carbon footprint by 75 %, however, due to the scarcity of scrap, the possibilities of this method are limited. Switching to directpr duction of iron, provided that all types of fuel are replaced by hydrogen, will reduce the carbon footprint by 90 %. At the same time, it will be necessary to have 181 kg of H2 for the production of 1 ton of rolled metal throughout the cycle. To supply all world steel companies with hydrogen, the existing hydrogen-producing capacities will have to be increased at least sixfold. Obtaining hydrogen for the needs of ferrous metallurgy using the cheapest conversion method will increase the cost of rolled products by at least one third, and obtaining this gas by electrolysis will double the cost of rolled products. It will be necessary to create power plants operating with alternative energy sources such as solar panels and wind generators to cover the needs of the metallurgical plant in electricity taking into account the cost for generating hydrogen. The allocation of such plants will require large areas, that are difficult to withdraw from farmland. Decarbonization of ferrous metals production is a complex and costly task, and therefore can be realized only in the long run.

Ключевые слова Ferrous metallurgy, carbon tax, decarbonization, sorption, conversion of carbon fuel, hydrogen technologies, hydrogen production, alternative energy sources
Библиографический список

1. European Parliament resolution of 10 March 2021 towards a WTO-compatible EU carbon border adjustment mechanism (2020/2043(INI)). Available at: https://www.europarl.europa.eu/doceo/document/TA-9-2021-0071_EN.html (accessed: 02.07.2021).
2. Roginko S. А., Shevelev L. N. Paris Agreement: New Challenges for Russian Iron & Steel Industry. Chernye Metally. 2019. No. 11. pp. 59–66.
3. Roginko S. А. EU cross-border carbon tax: hedging risks. Chernye Metally. 2021. No. 10. pp. 61–65.
4. Butorina I. V., Butorina М. V. Calculation of carbon index of steel rolled products. Chernye Metally. 2021. No. 3. pp. 53–60.
5. Shevelev L. N. Evaluation of the economic, energy and environmental efficiency of the production of iron and steel from ore-coal briquettes in an electric steel-smelting unit using hydrogen fuel. Chernaya Metallurgiya. Byulleten nauchno-tekhnicheskoy i ekonomicheskoy informatsii. 2021. Vol. 77. No. 8. pp. 918–924.
6. Matkovskiy P. Е., Sedov I. V., Savchenko V. I. et al. Synthesis gas production and processing technologies. Gazokhimiya. 2011. Vol. 19–20. No. 3–4. pp. 74–84.
7. Galkeeva А. А., Mingaleeva G. R. Comparative analysis of the calorific value of generator gases obtained during the gasification of coal dust and hydrogen-coal fuel under various mode parameters. Sovremennaya nauka. Issledovaniya, idei, rezultaty i tekhnologii. 2013. Vol. 13. No. 2. pp. 74–77.
8. Akhmetova V. R. , Smirnov О. V. Capture and storage of carbon dioxide – challenges and prospects. Bashkirskiy khimicheskiy zhurnal. 2020. Vol. 27. No. 3. pp. 103–113.
9. Terpugov D. G., Akinin N. I., Monakhov А. А. Study of carbon dioxide capture in a tubular column. Uspekhi khimii i khimicheskiy tekhnologiy. 2017. No. 13. pp. 81–83.
10. Buy Monoethanolamine wholesale, price from the manufacturer (alhgr.ru). Available at: https://alhgr.ru/catalog/bazovoe-syre/monoetanolamin/ (accessed: 28.02.2022).
11. Yousef Samy. Hydrogen as a clean and sustainable energy for green future. JVE Journals. 2021. Vol. 1, Iss. 1. pp. 8–13.
12. Pleshchenko V. I. Prospects for the transition of Russian ferrous metallurgy enterprises to the use of carbon-free technologies. Chernaya Metallurgiya. Byulleten nauchno-tekhnicheskoy i ekonomicheskoy informatsii. 2021. Vol. 77. No. 8. pp. 913–917.
13. Alabushev Е. А., Bersenev I. S., Bragin V. V., Stepanova А. А. Assessment of risks of using hydrogen to replace carbon-containing fuels in ferrous metallurgy. Chernaya Metallurgiya. Byulleten nauchno-tekhnicheskoy i ekonomicheskoy informatsii. 2021. Vol. 77. No. 8. pp. 925–930.
14. Kaihui Ma, Junyi Deng, Gang Wang, Qi Zhouet. Utilization and impacts of hydrogen in the ironmaking processes: a review from lab-scale basics to industrial practices. International Journal of Hydrogen Energy. 2021. Vol. 46, Iss. 4. pp. 26646–26664.
15. Yanbiao Chen, Hai-bin Zuo. Review of hydrogen-rich ironmaking technology in blast furnace. Ironmaking and Steelmaking. 2021. Vol. 48. pp. 749–768.
16. Power generation. Alternative energy Hydropower. Small HPP (present5.com). Available at: https://www.sciencedirect.com/science/book/9780444595669 (accessed: 28.02.2022).
17. Okolie J., Biswa R. P. et al. Futuristic applications of hydrogen in energy, biorefining, aerospace, pharmaceuticals and metallurgy. International Journal of Hydrogen Energy. 2021. Vol. 46. pp. 8885–8905.
18. Cormos A.-M., Szima S., Fogarasi S., Cormos C.-C. Economic assessments of hydrogen production processes based on natural gas reforming with carbon capture. Chemical engineering transactions. 2018. Vol. 70. pp. 1231–1236.
19. Adams T. A., Yaser Khojestah Salkuyeh, Jake Nease. Processes and simulations for solvent-based CO2 capture and syngas cleanup. Reactor and process design in sustainable energy technology. 2014. pp. 163–231.
20. Zherlitsin А. G., Korzhenko D. V., Shiyan V. P. Obtaining hydrogen in a microwave discharge at atmospheric pressure. Gazovaya promyshlennost. 2017. No. 11. pp. 104–113.
21. Hart P. W. Alternative «green» lime kiln fuels: Part II. Woody biomass, bio-oils, gasification, and hydrogen. Tappi Journal. 2020. Vol. 19. No. 5. pp. 263–269.

Language of full-text русский
Полный текст статьи Получить
Назад