Steel Production |
Название |
Decarbonization of steelmaking from the standpoint of
the electronic theory of metal reduction |
DOI |
10.17580/chm.2023.02.02 |
Автор |
V. E. Roshchin, A. D. Drozin, P. A. Gamov, K. I. Smirnov |
Информация об авторе |
South Ural State University, Chelyabinsk, Russia:
V. E. Roshchin, Dr. Eng., Professor, Chief Researcher, “Hydrogen Technologies in Metallurgy” Laboratory, e-mail: roshchinve@susu.ru A. D. Drozin, Dr. Eng., Professor, Leading Researcher, “Hydrogen Technologies in Metallurgy” Laboratory P. A. Gamov, Cand. Eng., Associate Prof., Acting Head of the “Hydrogen Technologies in Metallurgy" Laboratory K. I. Smirnov, Researcher, “Hydrogen Technologies in Metallurgy” Laboratory |
Реферат |
The inevitability of restructuring the existing steel production scheme is substantiated not only under the pressure of environmental requirements for decarbonization, but also by the need to bring steelmaking technologies in line with the level of modern science. It is shown that the electronic theory of oxidation/reduction can become a scientific basis for new technologies for the reduction of metals, which allows to consider the thermodynamic and kinetic conditions of processes from a unified standpoint with partial or complete replacement of fossil carboncontaining reducing agents with hydrogen. Comparison of two well-known options for technologies with zero carbon dioxide emissions – reduction of iron by “green” hydrogen or its production by ore electrolysis – shows a multiple advantage of electrolysis in terms of energy costs and more favorable kinetic conditions for its implementation. It is concluded that when developing an industry development strategy, priority should be given not to the production and use of "green" hydrogen, but to the electrolysis of ore. The use of hydrogen as a reducing agent can be justified in the selective extraction of iron from complex ores in units such as plasma shaft furnaces, plasma reactors, or suspension reduction reactors, in which, along with reduction, nitriding would also take place to convert soft iron into steel. A. V. Roshchin, Dr. Eng., Associate Prof., Chief Researcher, Dept. of Pyrometallurgical and Foundry Technologies, took part in the work. |
Ключевые слова |
Decarbonization, "green" hydrogen, "green" steel, solid-state reduction, electronic reduction theory, reduction kinetics and thermodynamics, electrolysis |
Библиографический список |
1. The future of steelmaking – How the European steel industry can achieve carbon neutrality. Available at: https://www.rolandberger.com/publications/publication_pdf/rroland_berger_future_of_steelmaking.pdf (accessed: 29.12.2022). 2. Decarbonization of the steel industry: a challenge for the coming decades. Available at: https://gmk.center/wp-content/uploads/2021/07/Decarbonisation-rus_2021.pdf (accessed: 29.12.2022). 3. Patisson F., Mirgaux O. Hydrogen Iron making: How it Works. Metals. 2020. Vol. 10, Iss. 7. p. 922. DOI: 10.3390/met10070922 4. Yan Ma, Isnaldi R., Souza Filho, Yang Bai et al. Hierarchical nature of hydrogen-based direct reduction of iron oxides. Scripta Materialia. 2022. Vol. 213. 114571. DOI: 10.1016/j.scriptamat.2022.114571 5. Ershov Yu. L., Shakurov А. G., Parshin V. М., Kolesnikov А. G., Shishov А. Yu. Hydrogen era in domestic metallurgy. Message 1. Stal. 2021. No. 11. pp. 50–55. 6. Ershov Yu. L., Shakurov А. G., Parshin V. М., Kolesnikov А. G., Shishov А. Yu. Hydrogen era in domestic metallurgy. Message 2. Stal. 2021. No. 12. pp. 48–56. 7. Roshchin V. E., Roshchin A. V. Electron mechanism of reduction processes in blast and ferroalloy furnaces. CIS Iron and Steel Review. 2019. Vol. 17. pp. 14–24. DOI: 10.17580/cisisr.2019.01.03 8. Roshchin V. E., Roshchin A. V. General electronic theory of reduction (oxidation) of metals. Izvestiya vuzov. Chernaya metallurgiya. 2020. Vol. 63. No. 3-4. pp. 271–285. DOI: 10.17073/0368-0797-2020-3-4-271-285 9. Roshchin V. E., Roshchin A. V. Physics of pyrometallurgical processes: textbook. Moscow; Vologda: Infra-Inzheneriya, 2021. 304 p. 10. Galevskiy G. V., Kulagin N. M., Mindis M. Ya. Sirazutdinov G. A. Aluminum metallurgy. Technology, power supply, automation: textbook. Moscow: Flinta, 2008. 529 p. 11. Roshchin A. V. High-temperature electrical conductivity and reactivity of solid oxides. Izvestiya vuzov. Chernaya metallurgiya. 2003. No. 4. pp. 3–7. 12. Roshchin V. E., Roshchin A. V., Kuznetsov Yu. S., Goikhenberg Yu. N. Technological and materials science aspects of the transition in ferrous metallurgy to carbon-free processes. Chernye Metally. 2021. No. 11. pp. 10–17. DOI: 10.17580/chm.2021.11.02 13. Brief reference book of physical and chemical quantities. 10th edition. Saint-Petersburg: Ivan Fedorov, 2003. 240 p. 14. ArcelorMittal suscribe una Manifestación de Interés con el Gobierno de España que contempla una inversión de 1.000 millones de euros en tecnologías para la descarbonización. Available at: https://spain.arcelormittal.com/comunicados/descarbonizacion-espana/ (accessed: 29.12.2022). 15. H2 Green Steel is building a €2.5 billion hydrogen-powered steel plant. Available at: http://decarbonization.ru/news/industry/krupneishii-zavod-po-vypusku-zelenoi-stali-postroiat-vshvetcii/?ysclid=ladunmcrai48315917 (accessed: 29.12.2022). 16. The Swedish consortium announced the delivery of the first batch of "clean" steel. Available at: https://trends.rbc.ru/trends/green/611fa0f19a7947f2c66ca05e (accessed: 29.12.2022). 17. ThyssenKrupp accelerates green transformation: decision is taken to build Germany's largest plant to directly reduced low-CO2 steel production. Available at: https://www.thyssenkrupp.com/en/newsroom/press-releases/pressdetailpage/thyssenkrupp-is-accelerating-the-greentransformation--decision-taken-on-the-construction-of-germanys-largest-direct-reductionplant-for-low-co2-steel-146809 (accessed: 29.12.2022). 18. Boston Metal: electrolysis as a clean alternative to steel production. Available at: https://econet.ru/articles/boston-metal-elektroliz-kak-chistaya-alternativa-proizvodstvu-stali (accessed: 29.12.2022). 19. Korepanova S. Boston Metal Boston Metal promises sustainable steelmaking. Available at: https://www.vedomosti.ru/business/articles/2021/10/26/892901-boston-metal-obeschaet (accessed: 29.12.2022). 20. Boston Metal`s reactors will produce "green steel" with a current of 25 thousand amperes. Available at: https://hightech.plus/2022/07/17/reaktori-boston-metal-budut-proizvodit-stalbez-uglya-tokom-v-25-tis-amper (accessed: 29.12.2022). 21. A scientific consortium for the development of hydrogen technologies has been created in Russia. Available at: https://ria.ru/20201113/tpu-1584487143.html (accessed: 29.12.2022). 22. A special economic zone "Green Steel" is being created in the Belgorod Region. Available at: https://www.belpressa.ru/ekonomics/biznes/43506.html?ysclid=l9w97g0m1l146095654# (accessed: 29.12.2022). |
Language of full-text |
русский |
Полный текст статьи |
Получить |