Название |
Technological features of surface alloying of metal products
with Cr – Ni complexes in the medium of low-melting metal melts |
Информация об авторе |
St. Petersburg Mining University, St. Petersburg, Russia:
E. I. Pryakhin, Dr. Eng., Professor, Head of the Dept. of Materials Science and Technology of Art Products, e-mail: e.p.mazernbc@yandex.ru A. V. Mikhailov, Postgraduate Student, Dept. of Materials Science and Technology of Art Products, e-mail: s195084@stud.spmi.ru A. V. Sivenkov, Cand. Eng., Associate Prof., Dept. of Materials Science and Technology of Art Products, e-mail: sivenkov@mail.ru |
Реферат |
One of the promising trends to increase the effective performance of steel parts working in conditions of simultaneous exposure to corrosive environment and abrasive loads is the use of surface alloying technology from the medium of fusible metal melts, allowing the formation of resistant diffusion coatings on their surfaces with the specified characteristics. Despite the fact that the mechanism of diffusion saturation from liquid-metallic medium has long been known, this technology is applied rarely in real industry due to the high cost of special vacuum units applied and the complexity of their operation and maintenance. Application of open heating devices does not allow to obtain defect-free smooth coatings - alloyed surface layers, because of the process of high-temperature oxidation of the items surface and the liquid-metallic transport melt. In previous studies, the concept of transport melt and workpiece protection through the use of hightemperature fluxes was proposed, however, despite the increased quality of the protected surface of the workpiece and transport melt, it was not possible to provide full protection from oxidation. Therefore, in order to increase the efficiency of protection against oxidation, this study proposes the combined use of high-temperature fluxes and purging the reaction chamber of the unit with inert gas. As a result the existing experimental unit was equipped with a protective gas supply system, which allowed to completely exclude the presence of oxide formations during the process of item heating in liquid metal medium and to obtain uniform, smooth and defect-free diffusion coatings based on Cr and Ni on the surface of 1020 steel samples, capable of providing increased characteristics of resistance to corrosion and wear. |
Библиографический список |
1. Bolobov V., Chupin S., Bochkov V., Akhmerov E., Plaschinskiy V. The effect of finely divided martensite of austenitic high manganese steel on the wear resistance of the excavator buckets teeth. Key Engineering Materials. 2020. Vol. 854. pp. 3-9. DOI: 10.4028/www.scientific.net/KEM.854.3 2. Zakharova А. А., Voytekhovsky Yu. L. Methodology for predicting of washability of apatite ores (Kirovsky mine, Kola Peninsula). Obogashchenie Rud. 2022. No. 1. pp. 27–30. DOI: 10.17580/or.2022.01.05 3. Slobodov A. A., Syrkov A. G., Yachmenova L. A., Kushchenko A. N., Prokopchuk N. R., Kavun V. S. Effect of temperature on solid-state hydride metal synthesis according to thermodynamic modeling. Journal of Mining Institute. 2019. Vol. 239. p. 550. DOI: 10.31897/pmi.2019.5.550 4. Baake E., Shpenst V. A. Recent scientific research on electrothermal metallurgical processes. Journal of Mining Institute. 2019. Vol. 240. p. 660. DOI: 10.31897/pmi.2019.6.660 5. Kasyanov A., Belousov A. Popov G. Determination of factors affecting on grooving corrosion. Topical Issues of Rational Use of Natural Resources. 2019. No. 1. pp. 393-399. DOI: 10.1201/9781003014577-49 6. Bazhin V. Y., Aleksandrova T. A., Kotova E. L., Suslov A. P. A Modern view of anomalies in the metal groups of the periodic system of D. I. Mendeleev. Journal of Mining Institute. 2019. Vol. 239. p. 520. DOI: 10.31897/pmi.2019.5.520 7. Sokolov А. G. Development of theoretical and technological foundations for increasing the durability of cutting and stamping tools due to diffusion metallization from the medium of low-melting liquid metal solutions: Dissertation … of Doctor of Engineering Sciences. Krasnodar, 2008. 384 p. 8. Mikhaylov А. V., Sivenkov А. V., Serdyuk N. А., Pryakhin Е. I. Development of an experimental installation for surface alloying from a medium of low-melting metal melts. Naukoemkie tekhnologii v mashinostroenii. 2020. No. 5. pp. 9–14. 9. Bazhin V. Y., Issa B. Influence of heat treatment on the microstructure of steel coils of a heating tube furnace. Journal of Mining Institute. 2021. Vol. 249. pp. 393–400. DOI: 10.31897/PMI.2021.3.8 10. Vologzhanina S., Peregudov A. Research of Properties of Austenitic Steels. Key Engineering Materials. 2021. Vol. 887. pp. 242–246 . DOI: 10.4028/www.scientific.net/KEM.887.242 11. Maksarov V. V., Gorshkov I. V., Khalimonenko A. D. Improvement of the performance of a multi-blade tool based on selective equipment with cutting ceramics. Chernye Metally. 2022. No. 6. pp. 75–80. DOI: 10.17580/chm.2022.06.12 12. GOST 3778–98. Lead. Technical specification. Introduced: 01.07.2001. 13. GOST 10928–90. Bismuth. Technical specification. Introduced: 01.01.1992. 14. GOST 5905–2004. Metallic chromium. Technical requirements and delivery conditions. Introduced: 01.07.2005. 15. Shatinskiy V. F., Zbozhnaya O. M., Maksimovich G. G. Obtaining diffusion coatings in the environment of low-melting metals. Kiev: Naukova dumka, 1976. 97 p. 16. Sokolov A. G., Bobylyov E. E. Diffusion saturation by titanium from liquid-metal media as way to increase carbide-tipped tool life. Solid State Phenomena. 2017. Vol. 265. pp. 181–186. DOI: 10.4028/www.scientific.net/SSP.265.181 17. Artemyev V. P. Development of scientific and technological foundations for the chemicalthermal treatment of steels in liquid metal melts: Dissertation … of Candidate of Engineering Sciences. KubGTU – Krasnodar, 2001. 346 p. 18. Sokolov А. G., Iosifov V. V., Skhirtladze А. G. Technologies for the formation of the required mechanical and physico-chemical properties of product surfaces in mechanical engineering: textbook. Krasnodar: Izdatelskiy Dom – YuG, 2016. 212 p. 19. Serdiuk N. A., Pryakhin E. I., Sivenkov A. V. Technological basis for the process of application of diffusion coatings in liquid metal melts with use of electric furnaces with air atmosphere. CIS Iron and Steel Review. 2022. Vol. 23. pp. 61–66. DOI: 10.17580/cisisr.2022.01.12 20. Semenychev V. V., Panarin A. V. The use of sclerometry to increase the information content of the measured characteristics of chromium and nickel coatings. Novosti materialovedeniya. Nauka i tekhnika. 2016. No. 3 (21). pp. 37–45. 21. Gogolinskiy К. V., Reshetov V. N., Useinov A. S. Hardness measurements in the submicro- and nanometer ranges of linear dimensions. Mir izmereniy. 2010. No. 8. pp. 41–47. 22. Chen L., Chen P., Zhang D. Thermodynamic simulation of complex Pb−Bi concentrate oxidative bath smelting process. Transactions of Nonferrous Metals Society of China. 2021. Vol. 31. pp. 1165-1174. DOI: 10.1016/S1003-6326(21)65569-3 23. Sokolov Е. G., Artemyev V. P. Influence of pores in powder materials on the formation of diffusion titanium and chromium coatings. MiTOM. 2002. No. 10. pp. 42–43. 24. Nikitin V. I. Physico-chemical phenomena under the influence of liquid metals on solid. Moscow: Atomizdat, 1967. 442 p. 25. Bolobov V. I., Chupin S. A., Bochkov V. S., Akhmerov E. V., Plaschinskiy V. A. The effect of finely divided martensite of austenitic high manganese steel on the wear resistance of the excavator buckets teeth. Key Engineering Materials. 2020. Vol. 854. No. 10. pp. 3–9. DOI: 10.4028/www.scientific.net/KEM.854.3 26. Sivenkov A. V., Konchus D. A., Mihailov A. V., Chirkova O. S. Development of flux for protection of the surface of liquid-metallic low-melting-point fusible melt. Key Engineering Materials. 2020. Vol. 854. pp. 126–132. DOI: 10.4028/www.scientific.net/KEM.854.126 27. Pimentel N. B., Mastelaro V., M'Peko J., Martin S. W., Rojas S. S., De Souza J. E.. Structural and electrical characterization of glasses in the Li2O-CaO-B2O3 system. Journal of Non-Crystalline Solids. 2018. Vol. 499. pp. 272–277. DOI: 10.1016/j.jnoncrysol.2018.07.024 28. Shakhnazarov K. Y. Property anomalies of unalloyed pre-eutectoid steel melts at ~0.5 % C as a consequence of the intermediate Fe42C phase. Steel in translation. 2020. Vol. 50, Iss. 4. pp. 261–265. DOI: 10.3103/S0967091220040087 29. Bezlyudnaya V., Kondrashov V., Frolova N., Gorokhovskii V. The effect of a protective gas atmosphere on the reducing potential of the melt tank. Glass and Ceramics – Glass Ceram. 2002. Vol. 59. pp. 264-266. DOI: 10.1023/A:1020995632548 30. Ţunea D., Mircea B. Research on argon protection when using WIG welding. Advanced Materials Research. 2014. Vol. 1029. pp. 20–24. DOI: 10.4028/www.scientific.net/AMR.1029.20 31. Shpilrain E., Skovorodko S., Mozgovoi A. The solubility of inert gases in liquid-metal heattransfer agents. High Temperature. 2000. Vol. 38. pp. 384–388. DOI: 10.1007/BF02755996 32. Liu R. L., Yan M. F., Qiao Y. Preparation and corrosion resistance of low temperature thermal diffusion layer on stainless steel. Cailiao Rechuli Xuebao. Transactions of Materials and Heat Treatment. 2016. Vol. 37. pp. 1–9. 33. Takashi Y., Michihisa F., Yoshiyuki S. Formation of Si diffusion layer on SUS430 and SUS304 steels and high temperature corrosion resistance. Journal of the Japan Institute of Metals. 2007. Vol. 71. pp. 528–533. DOI: 10.2320/jinstmet.71.528. 34. Ivanov R., Ivanova Ts. Diffusion coatings as corrosion inhibitors. Acta Scientifica Naturalis. 2016. Vol. 3, Iss. 1. pp. 39–43. DOI: 10.1515/asn-2016-0006 35. Kashkarov E., Sidelev D., Syrtanov M. S., Tang Ch., Steinbrück M. Oxidation kinetics of Cr-coated zirconium alloy: Effect of coating thickness and microstructure. Corrosion Science. 2020. Vol. 175. 108883. DOI: 10.1016/j.corsci.2020.108883 36. Zgonnik P. V., Kuzhaeva A. A., Berlinskiy I. V. The study of metal corrosion resistance near weld joints when erecting building and structures composed of precast structures. Applied Sciences. 2022. Vol. 12. No. 5. pp. 2518–2530. 37. Vologzhanina S., Ermakov S., Ermakov B. Features of obtaining Ni-Cr-Fe alloy powders by plasma atomization. Materials Science Forum. 2021. Vol. 1040. pp. 1–7. DOI: 10.4028/www.scientific.net/MSF.1040.1 38. Nikitina V. O., Serdiuk N. A., Konchus D. A., Creating a model of diffusion deposition of metal coatings from melts of low-melting metals. IOP Conference Series: Materials Science and Engineering. 2019. Vol. 560 (1). pp. 1–6. DOI: 10.1088/1757-899X/560/1/012188 39. GOST 9905–2007. United system of protection for corrosion and aging. Methods of corrosion resistance testing. Introduced: 01.07.2009. |