Название |
Main problems of neutralization of cyanide-containing solutions and pulps
of russian gold-mining industry. Part 1. Common approaches to issues of neutralization of cyanide wastes in Russia and abroad |
Информация об авторе |
SRK Consulting, Moscow, Russia:
D. V. Ermakov, Senior Concentration Engineer
“Polymetal Engineering” JSC, Saint Petersburg, Russia: N. V. Vorobev-Desyatovskiy, Head of Hydrometallurgy Office, e-mail: vdesjatovsky@polymetal.spb.ru |
Реферат |
There were considered the key approaches to resolving of problems, arising in the time of exploitation of Russian and CIS countries gold-mining enterprises, where alkaline cyanide solutions are used. There were compared the international and Russian requirements to neutralization of cyanide wastes of goldmining industry. International cyanide classification was carried out. Processes of natural detoxification of cyanide compounds in tailings impoundment were considered. There were described the current Russian regulations, relating to purification of waste waters from cyanide ions and thiocyanates which are free and bounded to complex compound with metal ions. Efficiency of purification of cyanide waste waters and possibility of their discharge into water flows have the following determining indices: values of maximum allowable concentrations, dissolved in water; standard of admissible exposure and standard of admissible discharge. This article shows the Russian approach to assessment of hazard of solid wastes, which appear as a result of semi-dry storage of cyanide leaching cakes in complete sludge process, and gold heap leaching. It was noted that it is rather easy to destroy the most toxic free cyanides by a variety of methods, harmless for humans and fauna. However, even after complete destruction of cyanide compounds, dissolved in water, obtained waste waters should be dissolved by pure water or with additional purification measures. The indicators, which most frequently exceed the standard concentrations in de-cyanided water, include рН value, total salt content, products of decomposition of cyanide ions and cyanide destroying reagents, and some by-products of ore and concentrate leaching process which do not contain CN anions. |
Библиографический список |
1. Ritcey G. M. Tailings management: problems and solutions in the mining industry. Amsterdam, New York : Elsevier, 1989. 970 p. 2. Young C. A., Twidwell L. G., Anderson C. G. Cyanide: social, industrial, and economic aspects. Warrendale : TMS, 2001. 582 p. 3. Mudder T. I., Botz M. M., Smith A. The Chemistry and Treatment of Cyanidation Wastes. London : Mining Journal Books Ltd, 2001. 373 p. 4. Dzombak D. A., Ghosh R. S., Wong-Chong G. M. Cyanide in water and soil: chemistry, risk and management. Boca Raton : Taylor & Francis, 2005. 616 p. 5. Kuyucak N., Akcil A. Cyanide and removal options from effluents in gold mining and metallurgical processes. Minerals Engineering. 2013. Vol. 50/51. pp. 13–29. 6. Kotlyar Yu. A., Meretukov M. A., Strizhko L. S. Metallurgiya blagorodnykh metallov (Metallurgy of noble metals). Moscow : Ore and Metals, 2005. Vol. 2. 392 p. 7. Ershov Yu. A., Pletneva T. V. Mekhanizmy toksicheskogo deystviya neorgani cheskikh soedineniy (Mechanisms of toxic influence of inorganic compounds). Moscow : Meditsina, 1989. 272 p. 8. Guidelines for Drinking-water Quality. First addendum to third edition. Vol. 1. Recommendations. Р. 188, 339. Available at : www.who.int/water_sanitation_health/dwq/gdwq0506.pdf. 9. U.S. EPA 440/5-88/016. Water Quality Standards Criteria Summaries A Compilation of State/Federal Criteria. Published: September 1988. NTIS order number PB89-141485. 10. Environmental, Health and Safety Guidelines for Mining. International Finance Corporation. World Bank Group. 10 December, 2007. p. 26. Available at : http://www.elaw.org/system/files/FinalMining_0.pdf. 11. Available at: http://docs.pravo.ru/document/view/27494297/27618198/. 12. Akcil A. A New Approach of Cyanide Management: International Cyanide Management Code for Manufacture, Transport, and use of cyanide in the Production of Gold. Mineral Processing and Extractive Metallurgy Review. 2010. Vol. 31, No. 3. pp. 135–149. 13. SanPiN 2.1.4.1074-01. “Pitevaya voda. Gigienicheskie trebovaniya k kachestvu vody tsentralizovannykh sistem pitevogo vodosnabzheniya. Kontrol kachestva” (Sanitary Regulations and studies 2.1.4.1074-01. “Potable water. Hygienic requirements to quality of water of centralized drinking water supply systems. Quality control”). Introduced : September: 26, 2001. 14. Marsden J. O., House C. I. The Chemistry of Gold Extraction. Littleton : Soc. For Mining, Metallurgy, and Exploration Inc., 2006. 651 p. 15. Lorösch Jü. Process and Environmental Chemistry of Cyanidation. Frankfurt am Main : Degussa AG, 2001. 504 p. 16. Metodika razrabotki normativov dopustimykh sbrosov veshchestv i mikroorganizmov v vodnye obekty dlya vodopolzovateley (Method of development on standards of possible dumping of substances and microorganisms in water objects for water suppliers). Federal agency of Water Resources. Available at : http://www.voda.mnr.gov.ru/regulatory/detail.php?ID=2821. 17. Metodicheskie ukazaniya po razrabotke normativov do pustimogo vozdeystviya na vodnye obekty (Methodological Regulations on development of standards of admissible impact on water objects). Federal agency of Water Resources. Available at : http://www.voda.mnr.gov.ru/regulatory/detail.php?ID=2829. |