MATERIAL SCIENCE | |
ArticleName | Heat resistant alloys of Al – Zr – Sc system for electrical applications: analysis and optimization of phase composition |
DOI | 10.17580/nfm.2015.02.07 |
ArticleAuthor | Alabin A. N., Belov N. A., Tabachkova N. Yu., Akopyan T. K. |
ArticleAuthorData | United Company “RUSAL”, Moscow, Russia.: A. N. Alabin, Head of a Project
National University of Science and Technology “MISiS”, Moscow, Russia:
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Abstract | Aluminium, possessing a high electrical conductivity, is widely used in electrical products, where this quality is the basic one. Recently, there has been increased the interest from power industry in thermally stable aluminium alloys, which should combine high electrical conductivity and strength stability after the heatings up to 300 oC. To solve this problem, the most promising approach is to develop alloys with zirconium and scandium additives. These elements promote the formation of L12 nanoparticles (Al3Zr, Al3Sc and Al3(Zr, Sc)), which enables both the required strengthening and thermal stability. In the present work there was studied the influence of composition and parameters of strain-thermal treatment on the structure (OM, SEM, TEM), strength (UTS, YS), electrical resistivity (ρ) and thermal stability of Al – Zr – Sc alloys containing up to 0.64% (wt.) Zr and up to 0.30% (wt.) Sc. The Thermo-Calc software was used for calculation of liquidus temperatures, the solubilities of Zr and Sc in aluminium solid solution and volume fractions of L12 nanoparticles. In hardened state the additions of Zr and Sc significantly increase value, which is possible to decrease by application of annealing. Parameters of annealing have to be chosen proceeding from ultimate concentration of Zr and Sc in aluminium solid solution and rate of decomposition of the last one. Using desirability function it is shown that ternary alloy Al – 0.24% Zr – 0.1% Sc has the best combination of strength, electrical resistance and thermal stability. After holding at 300 oC during 500 hours, it has the following properties: ρ = 28.3.10–9 Ωm·m, YS = 165 MPa, UTS = 186 MPa. This scientific work was carried out with the support of the grant of the Russian Scientific Funds No. 14-19-00632. |
keywords | Al – Zr – Sc alloys, Al3(Zr, Sc) nanoparticles, electrical resistance, strength, annealing |
References | 1. Uliasz P., Knych T., Mamala A., Smyrak B. Investigation in Properties Design Heat Resistant AlZrSc Alloy Wires Assign for Electrical Application, in Aluminium Alloys. J. Hirsch, B. Skrotzki and G. Gottstein (Eds.). WILEY-VCH, Weinheim, 2008. pp. 248–255. 6. Fuller C. B., Seidman D. N. Temporal evolution of the nanostructure of Al(Sc,Zr) alloys: Part II-coarsening of Al3(Sc1–xZrx) precipitates. Acta Materialia. 2005. No. 53. pp. 5415–5428. |
Language of full-text | english |
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