Журналы →  Gornyi Zhurnal →  2016 →  №4 →  Назад

PROCESSING AND COMPLEX USAGE OF MINERAL RAW MATERIALS
Название Increase in quality of potash fertilizers based on improvement of physical-chemical properties in the initial product
DOI 10.17580/gzh.2016.04.15
Автор Andreeva N. K.
Информация об авторе

VNII Galurgy Stock Co., St. Petersburg, Russia:

N. K. Andreeva, Senior Researcher, Candidate of Engineering Sciences, alekskim@mail.ru

Реферат

Potash products of all brands being manufactured are the disperse material with such principal characteristics as looseness (flow ability) and particle size distribution. Disperse material has good mechanical properties if it is able to retain them under the influence of moisture and temperature of ambient environment in the course of transportation and storage. This work has given substantiation and developed the process for production of potassium chloride, which provides the physical and mechanical product properties upgrading on the base of physical and chemical mechanics of disperse structures, according to which disperse properties of disperse materials are determined and its depend on energy state of constituting material grains, crystals, granules, agglomerates. During sylvinite ore processing on the stages of crushing, benification, vacuum-crystalization, drying, crystal disperse material obtains additional energy, which is to be realized and compensated. Excess surface energy of finished disperse material particles is realized in the agglomeration process on the warehouse and during transportation, at that the products become caked and lose flowability. It is proposed to solve this problem by including into the process the upgrading stage of particle structure of potassium chloride concentrate of wet flotation or hot leaching before drying. According to the developed technology it is proposed to make crystal structure upgrading into the special apparatus – speed turbo-bladed mixer-granulator providing close contact interaction of potassium chloride concentrate particles. Obtained in the agglomeration process the wet disperse material, which has ideal equilibrium excess energy free structure is exposed to the drying in the apparatus of any construction at the temperature not more, than 110 °C. Into the turbo-bladed mixer, along with wet KCl — is supplied dry hot product — cyclone dust from drying stage and, if necessary, agglomeration reagent solution.

Ключевые слова Disperse material, agglomeration, dislocation, equilibrium structure, flowability, moisture resistance, turbo-bladed mixer, plastic deformation
Библиографический список

1. Lomakin A. G. Rynok Kalinykh udobreniy: problemy i perspektivy (potassium fertilizers market: problems and prospects). Saint Petersburg : Print, 2004. pp. 168–187.
2. Buksha Yu. V., Kozel Z. L., Rogozin M. D. Problemy stabilizatsii kachestva khloristogo kaliya (Stabilization problems of potassium chloride quality). Aktualnye voprosy dobychi i pererabotki prirodnykh soley : Sbornik nauchnykh trudov otkrytogo aktsionernogo obshchestva “VNII Galurgii”. Tom 2: Pererabotka prirodnykh soley (Urgent issues of mining and processing of natural salts: Collection of scientific works of VNII Galurgy. Vol. 2: Processing of natural salts). Edited by Yu. V. Buksha. Saint Petersburg : LIK, 2001. pp. 7–11.
3. Gerzhberg Yu. I., Deryabin P. A. Aglomeratsiya kak sposob uluchsheniya fiziko-mekhanicheskikh svoistv khlorida kaliya (Agglomeration as a way to improve the physical and mechanical properties of potassium chloride). Aktualnye voprosy dobychi i pererabotki prirodnykh soley : Sbornik nauchnykh trudov otkrytogo aktsionernogo obshchestva “VNII Galurgii”. Tom 2: Pererabotka prirodnykh soley (Urgent issues of mining and processing of natural salts: Collection of scientific works of VNII Galurgy. Vol. 2: Processing of natural salts). Edited by Yu. V. Buksha. Saint Petersburg : LIK, 2001. pp. 70–85.
4. Kozel Z. L., Rogozin M. D., Goyko N. A., Aliferova S. N. Fiziko-mekhanicheskie svoistva granulirovannogo khlorida kaliya (Physical and mechanical properties of granular potassium chloride). Aktualnye voprosy dobychi i pererabotki prirodnykh soley : Sbornik nauchnykh trudov otkrytogo aktsionernogo obshchestva “VNII Galurgii”. Tom 2: Pererabotka prirodnykh soley (Urgent issues of mining and processing of natural salts: Collection of scientific works of VNII Galurgy. Vol. 2: Processing of natural salts). Edited by Yu. V. Buksha. Saint Petersburg : Saint Petersburg State University, 2006. pp. 181–195.
5. Berezin A. L. Gerzhberg Yu. I. Aglomeratsiya melkodispersnykh fraktsii khloristogo kaliya v skorostnykh turbolopastnykh apparatakh (Agglomeration of fine dispersed fractions of potassium chloride in high-speed turbo-bladed machines). Aktualnye voprosy dobychi i pere rabotki prirodnykh soley : Sbornik nauchnykh trudov otkrytogo aktsionernogo obshchestva “VNII Galurgii”. Tom 2: Pererabotka prirodnykh soley (Urgent issues of mining and processing of natural salts: Collection of scientific works of VNII Galurgy. Vol. 2: Processing of natural salts). Edited by Yu. V. Buksha. Saint Petersburg : Saint Petersburg State University, 2006. pp. 214–224.
6. Gazaleeva G. I., Tsypin E. F., Chervyakov S. A. Rudopodgotovka – droblenie, grokhochenie, obogashchenie (Ore preparation – crushing, screening, concentrationiation). Ekaterinburg : UTsAO, 2014. pp. 392–405.
7. Shemyakina M. G., Pleshkova L. D., Molokovich S. O., Smychkova A. N., Stromskiy A. S. Novaya kompozitsiya dlya modifitsirovanniya granulirovannogo chloristogo kaliya (A new composition for granulated potassium chloride modification). Obogashchenie rud = Mineral processing. 2009. No. 2. pp. 39–41
8. Rebinder P. A. Fiziko-Khimicheskaya mekhanika dispersnykh struktur (Physical and chemical mechanics of disperse structures). Moscow: Nauka, 1966. 187 p.
9. Rebinder P. A. Fiziko-Khimicheskaya mekhanika – novaya oblast nauki (Physical and chemical mechanics – a new field of science). Moscow : Znanie, 1958. 69 p.
10. Rebinder P. A. Izbrannye trudy. Fiziko-Khimicheskaya mekhanika (Physical and chemical mechanics. Selected works). Moscow: Nauka, 1980. 217 p.
11. Khopunov E. A. Rol struktury i prochnostnykh kharakteristik mineralov v razrushenii i raskrytii rud (Role of structure and strength characteristics of minerals in ore breaking and opening). Obogashchenie rud = Mineral processing. 2011. No. 1. pp. 27–33.
12. Pankov I. L., Morozov I. A. Issledovanie vliyaniya koeffitsienta treniya mezhdu tortsami obraztsov razlichnoy vysoty i plitami pressa na mekhanicheskie pokazateli solyanykh porod (Investigation of effect of friction coefficient between the specimen ends with different height and press plates on mechanical performances of saline rocks). Izvestiya vuzov. Gornyi zhurnal = News of the Higher Institutions. Mining journal. 2015. No. 2. pp. 107–113.
13. Malkin A. I. Regularities and mechanisms of the Rehbinder's effect. Colloid Journal. 2012. Vol. 74, No. 2. pp. 223–238.
14. Resume of academic conference : Grinding, classifying and particle characterization in research and product development. AT Mineral Processing. 2011. No. 4. pp. 22–23.
15. Lampke J., Messerschmidt C., Folgner T., Lieberwirth H. Granulation of mineral fertilisers. AT Mineral Processing. 2015. No. 01-02. pp. 56–64.
16. Govender I. Granular flows in rotating drums: A rheological perspective. Minerals Engineeeing. 2016. Vol. 92. pp. 168–175.
17. Sabirov R. R., Ignateva G. P., Seballo V. A. Izuchenie prochnosnykh svoistv granulirovannykh kaliynykh udobrenii (The study of the strength properties of granular potassium fertilizers). Obogashchenie rud = Mineral processing. 2005. No. 3. pp. 11–13.
18. Kozel Z. L., Rogozin M. D., Goiko N. A., Zakharova Yu. M. Issledovanie fiziko-mekhanicheskikh svoistv khloristogo kaliya (Study of physical and mechanical properties of potassium chloride). Gornyi zhurnal = Mining Journal. 2007. No. 8. pp. 86–88.
19. Kazakov A. I. Tekhnologicheskie vozmozhnosti turbolopastnykh smesiteley – granulyatorov (Technological capabilities of turbo-bladed mixers – granulators). Khimicheskaya Promyshlennost = Industry & Chmistry. 2001.Vol. 78, No. 6. pp. 35–38.
20. Timofeev I. E., Zagigulin S. Kh., Kalegin A. D., Timofeev I. I. Izuchenie nekotorykh zakonomernostey sushki tekhnicheskogo khloristogo kaliya (The study of some regularities of technical potassium drying). Khimicheskaya Promyshlennost = Industry & Chmistry. 2005. Vol. 82, No. 12. pp. 610–615.
21. N. K. Andreeva, Yu. V. Buksha, V. A. Seballo et al. Sposob polucheniya vlagostoykogo khloristogo kaliya s uluchshennymi reologicheskimi svoistvami (Production method of moisture-resistant potassium chloride with improved rheological properties). Patent RF, No. 2359910. Applied: June 27, 2007. Published: January 10, 2009. Bulletin No. 8.
22. Andreeva N. K., Safrygin Yu. S., Timofeev V. I., Buksha Yu. V., Osipova G. V. Sposob polucheniya granulirovannogo khloristogo kaliya (Production method of granulated potassium chloride). Patent RF, No. 2422363. Applied: December 01, 2009. Published: June 27, 2011. Bulletin No. 18.
23. N. K. Andreeva, Yu. S. Safrygin, V. I. Timofeev, Yu. V. Buksha, G. V. Osipova. Sposob polucheniya khloristogo kaliya s uluchshennymi reologicheskimi svoistvami (Production method of potassium chloride with improved rheological properties). Patent RF, No. 2428379. Applied: November 03, 2009. Published: September 10, 2011. Bulletin No. 25.

Полный текст статьи Increase in quality of potash fertilizers based on improvement of physical-chemical properties in the initial product
Назад