Journals →  Eurasian mining →  2016 →  #2 →  Back

PROCESSING AND COMPLEX USAGE OF MINERAL RAW MATERIALS
ArticleName Humic acids of solid fossil fuels — perspectives for application in technology and environment protection
DOI 10.17580/em.2016.02.08
ArticleAuthor Nikitina I. M., Epshtein S. A., Fomenko N. A., Kossovich E. L.
ArticleAuthorData

National University of Science and Technology MISiS, Moscow, Russian Federation:

Nikitina I. M., Candidate of Engineering Sciences, Leading Engineer
Epshtein S. A., Doctor of Engineering Sciences, Head of Laboratory of Physics and Chemistry of Coals, apshtein@yandex.ru
Fomenko N. A., Engineer
Kossovich E. L., Candidate of Physical and Mathematical Sciences, Senior researcher, Ph.D.

Abstract

Humic acids of solid fossil fuels are very perspective for application in many areas of mining, and also for derivation of advanced technology products for agriculture, production, medicine, etc. Ability of humic acids to bind toxic elements (including heavy metals and radioactive elemens) contained in technogenic soils and waters of mining companies and plants allow them to be used in the area of environment protection and reclamation. Drilling fluids with humic substances as polymeric fillers have rheological properties close to properties of systems that are used for water, oil and gas wells horizontal and deep drilling. Moreover, such solutions allow to reduce the unfavorable effects at the environment. In agriculture, humic acids are primarily used as potassium, calcium and sodium humates as additives for enhancement of plants growth and crop yield enhancers. In construction, humic acids and their derivatives could be used as fillers for improving of cement and concrete Humic acids could find a potentially wide application in the area of medicine. This is reasoned by a number of unique properties such as inflammatory and antiviral ones, sorption, etc. Perspective direction of humic acids in medicine is targeted drug delivery. Some researchers showed that humic acids could suppress growth of cancer cells. In veterinary, humic acids and their derivatives are used as nutrition additives that help to enhance animals’ immune system and activate metabolism along with increase of stress resistance. However currently there exist no sufficient and reliable information on features of humic acids structure and properties with respect to their origin. This considerably complicates humic acids and their derivatives wide utilization in Technology and environment protection. Authors of this paper believe that the solution of such problem could be found by development of humic acids classification based on revealing the most relevant characteristics responsible for humic acids behavior in different processes.

This work was performed within the framework of "Conducting research work (basic research, applied research and experimental development)" task # 2014/113 to provide state-supported research in the field of scientific activities of the base part of the state task 495 "Structure and properties of humic acids within solid fossil fuels of various origins and metamorphism".

keywords Humic acids, peat, coal, sapropel, mining, drilling fluids, agriculture, medicine, environment protection
References

1. Hankins N. P., Lu N., Hilal N. Enhanced removal of heavy metal ions bound to humic acid by polyelectrolyte flocculation. Separation and Purification Technology. 2006. Vol. 51(1). pp. 48–56. doi: 10.1016/j.seppur.2005.12.022.
2. Sposito G., Weber J. H. Sorption of trace metals by humic materials in soils and natural waters. Critical Reviews in Environmental  Control. 1986. No. 16(2). pp. 193–229. doi: 10.1080/10643388609381745.
3. Bahemmat M., Farahbakhsh M., Kianirad M. Humic substances-enhanced electroremediation of heavy metals contaminated soil. Journal of Hazardous Materials. 2016. No. 312. pp. 307–318. doi: 10.1016/j.jhazmat.2016.03.038.
4. Lesnikova E. B., Artemova N. I., Lukicheva V. P. Mine water purification with the use of humic preparations. Solid Fuel Chemistry. 2009. No. 43(6). pp. 387–390. doi: 10.3103/S0361521909060081.
5. Meidel I. M., Epshtein S. A. Effect of the mechanical activation of peat on the yield and sorption properties of humic acids (short communication). Solid Fuel Chemistry. 2014. No. 48(5). pp. 332–334. doi: 10.3103/S0361521914050085.
6. Moulin V. Complexation of Radionuclides with Humic Substances. In: Use of Humic Substances to Remediate Polluted Environments: From Theory to Practice. Berlin/Heidelberg: Springer-Verlag, 2005. pp. 155–173. doi: 10.1007/1-4020-3252-8_7.
7. Ivanov A. A., Yudina N. V., Ilyina A. A. Acidic and ion exchange properties of mechanically activated humic acid peat. Chemistry of plant raw materials. 2010. No. 4. pp. 145–150.
8. Borvka L., Drábek O. Heavy metal distribution between fractions of humic substances in heavily polluted soils. Plant, Soil and Environment. 2004. No. 50(8). pp. 339–345.
9. Shkuratnik V. L, Shulgin А. А. Researching the method of activating brown coal’s humic acids for the purpose of detoxifying and utilizing dangerous waste. Mining informational and analytical bulletin (scientific and technical journal). 2009. No. 7. pp. 23–32.
10. Gombköt I., Madarász T., Szcs P., Lakatos J., Székely I. Novel environmental management application for lignite. In: Litvinenko V., ed. XVIII International Coal Preparation Congress. Springer International Publishing Switzerland, 2016. pp. 673–679. doi: 10.1007/978-3-319-40943-6_104.
11. A method of neutralization and purification of waste water. Patent RF, No. 2174107. Published on 27.09.2001. (in Russian) 12. A method of treatment of industrial waste waters from heavy metals. Patent 2497759. Published on 10.11.2001. (in Russian)
13. Humic acids-based mineral reagent and method for its preparation, method for remediation of contaminated soil, method of detoxification of minerals production and processing wastes and reclamation of rock dumps and tailings, wastewater treatment process and method of disposal of sediments. Patent RF, No. 2233293, IPC: C02F 1/54. Published 27.07.2004. (in Russian)
14. Humic concentrate, its production method, a device for the electrochemical production of humic concentrate (options), water purification method, process of dehydration of thick liquid-like media, the method of detoxification of organic compounds, a method of disposing of sewage sludge, the process of reclamation of natural and artificial soils and restoration of degraded soil fertility, method for of composting organic waste disposal, method for precipitation water treatment. Patent RF, No. 2125039. Published on 20.01.1999. (in Russian)
15. Epstein S. A., Titorova Yu. A., Meidel I. M. Recycling of clearing sediment of industrial sewage by reagents on the basis of peat. Mining informational and analytical bulletin (scientific and technical journal). 2012. No. 5. pp. 307–311.
16. Epstein S. A., Meidel I. M., Nesterova V. G., Minaev V. I., Melik-Gaykazov Ya. I. Industrial waste water treatment reagents on the basis of peat. Mining informational and analytical bulletin (scientific and technical journal). 2012. No. 9. pp. 303–311.
17. Getliff J. M., James S. G. The Replacement of AlkyI-Phenol Ethoxylates to Improve the Environmental acceptability of Drilling Fluid Additives. In: SPE Health, Safety and Environment in Oil and Gas Exploration and Production Conference. Vol SPE 35982. Society of Petroleum Engineers. 1996. doi: 10.2118/35982-MS.
18. Kania D., Yunus R., Omar R., Abdul Rashid S., Mohamad Jan B. A review of biolubricants in drilling fluids: Recent research, performance, and applications. Journal of Petroleum Science and Engineering. 2015. Vol. 135. pp. 177–184. doi: 10.1016/j.petrol.2015.09.021.
19. Caenn R., Darley H. C. H., Gray G. R. Drilling Fluid Components. In: Composition and Properties of Drilling and Completion Fluids. Elsevier, 2011. pp. 535–616. doi: 10.1016/B978–0-12–383858–2.00011–1.
20. Maslov S. G., Dolgikh S. M., Chubik P. S., Godunov E. B. Influence of type and group composition of peat on the properties of drilling fluids. Chemistry of plant raw materials. 2003. No. 3. pp. 57–67.
21. Iakimenko O. S. Commercial Humates from Coal and Their Influence on Soil Properties and Initial Plant Development. In: Use of Humic Substances to Remediate Polluted Environments: From Theory to Practice. Berlin/Heidelberg: Springer-Verlag, 2005. pp. 365–378. doi: 10.1007/1-4020-3252-8_19.
22. Canellas L. P., Olivares F. L., Aguiar N. O., et al. Humic and fulvic acids as biostimulants in horticulture. Scientia Horticulturae. 2015. No. 196. pp. 15–27. doi: 10.1016/j.scienta.2015.09.013.

23. Neverova O. A., Mosiyachina N. N., Zherebtsov S. I., Ismagilov Z. R. Otsenka vliyaniya guminovykh preparatov na rost i urozhay gorokha na chernozemakh Kuzbassa (Estimation of the influence of humic preparations on the growth and harvest of peas on chernozem of Kuzbass). Sovremennye problemy nauki i obrazovaniya = Modern problems of science and education. 2012. No. 6. Available at: http://science-education.ru/ru/article/view?id=7519.
24. Stevenson F. J. Humus Chemistry. Genesis, Composition, Reactions. 2nd ed. Wiley, 1982. 496 p.
25. Fan H., Wang X., Sun X., Li Y., Sun X., Zheng C. Effects of humic acid derived from sediments on growth, photosynthesis and chloroplast ultrastructure in chrysanthemum. Scientia Horticulturae. 2014. No. 177. pp. 118–123. doi: 10.1016/j.scienta.2014.05.010.
26. Kucukersan S., Kucukersan K., Colpan I., Goncuoglu E., Reisli Z., Yesilbag D. The effects of humic acid on egg production and egg traits of laying hen. Veterinarni Medicina. 2005. No. 50(9). pp. 406–410.
27. Sathya Prabha K. Experimental Study on Properties of Concrete USNG Humic Acid. International Journal of Scientific and Research Publications. 2014. No. 5(1). pp. 2250–3153.
28. Ilg M., Plank J. A novel kind of concrete superplasticizer based on lignite graft copolymers. Cement and Concrete Research. 2016. No. 79. pp. 123–130. doi: 10.1016/j.cemconres.2015.09.004.
29. Lewis S., Chatterji J., King B. Cement compositions comprising humic acid grafted fluid loss control additives, US Patent US7576040 B2, 2007.
30. Page C. L., Page M. M. Durability of Concrete and Cement Composites. Woodhead and Maney on behalf of Institute of Materials, Minerals & Mining. 2007. 404 p.
31. Visser S. A. Effect of humic substances on higher animals and man, the possible use of humic compounds in medical treatments. In: International Humic Acid Society Meeting, Sevilla, Spain, 1987. p. 27.
32. Van Rensburg CEJ. The Antiinflammatory Properties of Humic Substances: A Mini Review. Phytotherapy Research. 2015. No. 29(6). pp. 791–795. doi: 10.1002/ptr.5319.
33. Jooné G. K., van Rensburg CEJ. An In Vitro Investigation of the Anti-Inflammatory Properties of Potassium Humate. Inflammation. 2004. No. 28(3). pp. 169–174. doi: 10.1023/B:IFLA.0000039563.90066.5d.
34. Khilko S. L., Efimova I. V., Smirnova O. V. Antioxidant properties of humic acids from brown coal. Solid Fuel Chemistry. 2011. No. 45(6). pp. 367–371. doi: 10.3103/S036152191106005X.
35. Klöcking R, Sprössig M. Antiviral properties of humic acids. Experientia. 1972. No. 28(5). pp. 607–608. doi: 10.1007/BF01931906.
36. Litvin V. A., Minaev B. F. Spectroscopy study of silver nanoparticles fabrication using synthetic humic substances and their antimicrobial activity. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2013. No. 108. pp. 115–122. doi: 10.1016/j.saa.2013.01.049.
37. Lu J., Li Y., Yan X., Shi B., Wang D., Tang H. Sorption of atrazine onto humic acids (HAs) coated nanoparticles. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2009. No. 347(1–3). pp. 90–96. doi: 10.1016/j.colsurfa.2008.12.032.
38. Ting H-C., Yen C-C., Chen W-K., Chang W-H., Chou M-C., Lu F-J. Humic acid enhances the cytotoxic effects of arsenic trioxide on human cervical cancer cells. Environmental toxicology and pharmacology. 2010. No. 29(2). pp. 117–125. doi: 10.1016/j.etap.2009.11.009.
39. Van Rensburg C. E. J., Dekker J., Weis R., Smith T-L., van Rensburg E. J., Schneider J. Investigation of the Anti-HIV Properties of Oxihumate. Chemotherapy. 2002. No. 48(3). pp. 138–143. doi: 10.1159/000064919.
40. Hayes M. H. B., MacCarthy P., Malcolm R. L., Swift R. S. Humic substances II. In search of structure. Humic substances II In search of structure. 1989.
41. Polyakov A. Yu., Goldt A. E., Sorkina T. A., Davydova G. A., Gudilin E. A., Perminova I. V. Synthesis of biocompatible magnetic nanoparticles with different morphologies and stabilization of humic acids. Advanced Materials. 2010. No. 9. pp. 204–210.
42. Grassi M., Rosa M. Humic acids of different origin as modifiers of cadmium-ion chemistry: A spectroscopic approach to structural properties and reactivity. Inorganica Chimica Acta. 2010. No. 363(3). pp. 495–503. doi: 10.1016/j.ica.2009.07.033.

Full content Humic acids of solid fossil fuels — perspectives for application in technology and environment protection
Back