ArticleName |
Cleaning-up of oil-polluted gypsum deposits in karst areas |
ArticleAuthorData |
Natural Science Institute, Perm State University, Perm, Russia:
N. G. Maksimovich, Deputy Director of Scientific Work, Associate Professor, Candidate of Geologo-Mineralogical Sciences, nmax54@gmail.com O. Yu. Meshcheryakova, Senior Researcher, Candidate of Engineering Sciences
Tula State University, Tula, Russia: N. M. Kachurin, Head of a Chair, Professor, Doctor of Engineering Sciences |
Abstract |
The article addresses the problem of pollution of gypsum mining sites during oil recovery in the same area. The process of purification is complicated by numerous karst voids. The mechanism of oil pollution means that a lens of oil forms on the surface of fracture-and-ground water as the pollutant freely flows under conditions of absent overburden, highly developed porosity and due to formation of hydrodynamic trap in the shoreland when soluble oil products flow with underground water with the subaqueous discharge in water basins. In connection with this, the model of the pollutant permeation and diffusion through a gypsum bed is developed. The technology of oil protection of sulphates has been trialed and patented; the technology accounts for features of oil pollution and specific requirements imposed on removal of a pollution source located nearby a large water basin, and includes two approaches: pumping of oil from the lens on the surface of underground water without water discharge on the ground surface and biological destruction of oil products by activated native microorganisms. The article illustrates the efficiency of the proposed technology: high-rate removal of oil products, availability of pumped oil for further treatment, low cost of the microbiological method, short payback time and possibility of development of a cleaned-up promising deposit, which will enlarge economic resource base and exert favorable effect on the regional economy of West Ural. After the adequate treatment of a polluted area is performed, due to revealing the described pollution mechanism, it is possible to start development of gypsum deposits. This study has been supported by the Russian Foundation for Basic Research, Project No. 16-35-00104 mol_a, entitled “Hydrocarbon Migration by Permeation and Diff usion in Karst Areas”, and by the Ministry of Education and Science of the Russian Federation, in the framework of the basic part of the Governmental Contract No. 2014/153 No. 269. |
References |
1. Mineral resourses of Perm krai : encyclopedia. Ed.: A. I. Kudryashov. Perm : Knizhnaya ploshchad, 2006. 464 p. 2. Darovskikh N. A., Kudryashov A. I. Geology and searches of ornamental gypsum deposits. Perm : GI UrO RAN, 2001. 161 p. 3. Gorbunova K. A., Andreychuk V. N., Kostarev V. P., Maksimovich N. G. Karst and caves of Perm oblast. Perm : Izdatelstvo Permskogo universiteta, 1992. 200 p. 4. Seredin V. V., Pushkareva M. V., Leybovich L. O., Bakharev A. O., Tatarkin A. V., Filimonchikov A. A. Geological environment changes during oil fi elds mining in complex mining and geological conditions. Neftyanoe khozyaystvo. 2014. No. 12. pp. 153–155. 5. Isaev S. V. Methods of study the natural-technical systems of the oil fi elds in Perm Krai. Izvestiya Samarskogo nauchnogo tsentra Rossiyskoy Akademii Nauk. 2016. No. 2-1, Vol. 18. pp. 88–91. 6. Bartolomeo V., Federico M. Engineering problems in Karst: Three case history. Engineering Geology for Society and Territory. Vol. 5. Urban Geology, Sustainable Planning and Landscape Exploitation. Switzerland : Springer International Publishing, 2015. pp. 595–601. 7. Krasilnikov P. A., Seredin V. V., Leonovich M. F. Investigation of the distribution of hydrocarbons to cut the soil mass. Fundamentalnye issledovaniya. 2015. No. 2-14. pp. 3100–3104. 8. Bazhenova O. K., Burlin Yu. K., Sokolov B. A., Khain V. E. Geology and geochemistry of oil and gas. Moscow : Izdatelstvo MGU, 2004. 415 p. 9. Davydova S. L., Tagasov V. I. Oil and oil products in environment : tutorial. Moscow : Izdatelstvo RUDN, 2004. 163 p. 10. Pikovskiy Yu. I. Natural and technogenic flows of hydrocarbons in environment. Moscow : Izdatelstvo MGU, 1993. 208 p. 11. Polozov M. B. Ecology of oil and gas mining complex : tutorial. Izhevsk : Izdatelstvo «Udmurtskiy universitet», 2012. 174 p. 12. Tetelmin V. V., Yazev V. A. Geoecology of hydrocarbons : tutorial. Dolgoprudnyy : ID «Intellekt», 2009. 304 p. 13. Bykov V. N. Oil and gas carst mining. Perm : Izdatelstvo Permskogo uniersiteta, 2002. 351 p. 14. Maksimovich N. G., Meshcheryakova O. Yu. Methods of struggle with oil pollution on carsted banks of water reserves. Ekologiya urbanizirovannykh territoriy. 2009. No. 4. pp. 55–58. 15. Gabbasova I. M., Suleymanov R. R., Garipov T. T. Degradation and remediation of soils polluted with oil-field wastewater. Pochvovedenie. 2013. No. 2. pp. 226–234. 16. Marchand C., St-Arnaud M., Hogland W., Bell T. H., Hijri M. Petroleum biodegradation capacity of bacteria and fungi isolated from petroleum-contaminated soil. International Biodeterioration and Biodegradation. 2017. Vol. 116. pp. 48–57. 17. Varjani S. J. Microbial degradation of petroleum hydrocarbons. Bioresource Technology. 2017. Vol. 223. pp. 277–286. 18. Wu M., Li W., Dick W. A., Ye X., Chen K., Kost D., Chen L. Bioremediation of hydrocarbon degradation in a petroleum-contaminated soil and microbial population and activity determination. Chemosphere. 2017. Vol. 169. pp. 124–130. 19. Popov L. N., Maksimovich N. G. Unit for oil-bearing liquid pumping from well. Patent RF, No. 81522. Applied: 07.10.2008. Published: 20.03.2009. Bulletin No. 8. 20. Maksimovich N. G., Khmurchik V. T. Consortium of strains of hydrocarbon oxidation bacteria pseudomonas aeruginosa nd kz-1 and pseudomonas fluorescens nd kz-2 as a destructor of oil products and method of purification of oil-contaminated underground waters. Patent RF, No. 2312719. Applied: 15.02.2006. Published: 20.12.2007. Bulletin No. 35. |