Journals →  Gornyi Zhurnal →  2018 →  #10 →  Back

PROCESSING AND COMPLEX USAGE OF MINERAL RAW MATERIALS
ArticleName Promising trends in development of technologies for tungsten-containing ore and waste processing
DOI 10.17580/gzh.2018.10.13
ArticleAuthor Shepeta E. D., Samatova L. A., Voronova O. V.
ArticleAuthorData

Institute of Mining, Far East Branch, Russian Academy of Sciences, Khabarovsk, Russia:

E. D. Shepeta, Senior Researcher, Candidate of Engineering Sciences, elenashepeta56@mail.ru
L. A. Samatova, Head of Laboratory, Candidate of Engineering Sciences
O. V. Voronova, Researcher

Abstract

Processing of low-grade tungsten ore and waste governs a cardinally new strategy of beneficiation. This article discusses possible processing of low-grade scheelite ore and waste of the Vostok-2 and Skrytoe deposits by X-ray radiometric and X-ray absorption separation. In tests of the highly contrast material, it was succeeded to remove 60–65 % of tailings before the stage of deep processing. Recovery of WO3 in flotation feed made 95 % in case of ore and 84–87 % in case of mining waste, while concentration of WO3 reached 2.3–3 relative units. The tests were carried out on the industrial separators SRF-2–200RRS and TOMRA COM Tertiary XRT. The studies of transparent polished sections by the mineralogical and petrographic analyses revealed the main difficult-to-treat associations of scheelite with pyroxene, amphibole, chlorite and biotite. It is observed that scheelite occurs in the form of disseminated shots in quartz veins, in quartz zones of hedenbergite skarn and at the quartz–sulfi de interfaces. The crystals of scheelite in the associations reach 0.03 mm to 2(3) mm in size. In terms of the low-contrast scheelite–quartz–amphibole and scheelite–carbonate ore of the Skrytoe deposit, the concentration of 1.5–1.7 relative units is reached, the separation efficiency makes 81–85 %. The mentioned ore features high content of calcite (15–9 %) and low content of scheelite. The sheelite grains are mainly 0.03–0.15 mm in size. To improve contrast properties of mineral surfaces, it is proposed to use high-energy acoustic vibrations. The tests were conducted on the machine UZDN-2T: working frequency was 22 kHz, average acoustic intensity Iuz = 15 W/cm2, size grade of the test material was –3+2 mm. Efficient mineral dissociation was observed in specimens with vein-impregnated texture and in marmorized limestone, selective recovery of scheelite was reached at the quartz–scheelite interface. The processing circuit proposed in this article for low-grade tungsten ore and mining waste includes preliminary concentration by means of X-ray absorption separation and treatment of second stage milling sand by high-frequency acoustic vibrations.

keywords Tungsten ore, scheelite, mineral associations, X-ray absorption separation, X-ray radiometric separation, contrast properties, high-frequency acoustic vibrations
References

1. Barskiy L. A., Kononov O. V., Ratmirova L. I. Selective Flotation Calcium-Bearing Minerals. Moscow : Nedra, 1979. 232 p.
2. Gao Z., Bai D., Sun W., Cao X., Hu Y. Selective flotation of scheelite from calcite and fluorite using a collector mixture. Minerals Engineering. 2015. Vol. 72. pp. 23–26.
3. Abramov A. A., Khober Kh. Mechanism and effect of genesis of adsorption and flotation properties of minerals. Tsvetnye metally. 2008. No. 2. pp. 26–34.
4. Gao Y., Gao Z., Sun W., Hu Y. Selective flotation of scheelite from calcite: A novel reagent scheme. International Journal of Mineral Processing. 2016. Vol. 154. pp. 10–15.
5. Bo F., Xianping L., Jinqing W., Pengcheng W. The flotation separation of scheelite from calcite using acidified sodium silicate as depressant. Minerals Engineering. 2015. Vol. 80. pp. 45–49.
6. Khanchuk A. I., Gonevchuk G. A., Seltmann R. Metallogeny of the Pacific Northwest (Russian Far East): Tectonics, Magmatism and Metallogeny of Active Continental Margins : Excursion Guidebook. Vladivostok : Dalnauka, 2004.176 p.
7. Kobzev A. S. Mineral Processing by Radiometric Methods. Moscow : Gornaya Kniga, 2015. 125 p.
8. Shepeta E. D., Samatova L. A., Alushkin I. V., Yushina T. I. Prospect of preliminary beneficiation use in the poor tungsten ores processing practice. Non-Ferrous Metals. 2016. No. 1. pp. 9–15. DOI: 10.17580/nfm.2016.01.02
9. Analysis of Grain Size Composition and Contrast Properties of Minerals for Estimating Possibility of Processing by Radiometry Techniques: Guidelines. Moscow : VIMS, 1983. 24 p.
10. Russian Geological Society Standard STO RosGeo 08–009–98. Solid Incombustible Minerals. Mineral Processing Methods. Radiometric Treatment Techniques. Moscow : RosGeo, 1998. 74 p.
11. Standards of Studying Mineral Dressability by Radiometric Methods during Exploration of Metalliferosu and Nonmetalliferous Deposits. State Commission for Mineral Resources of the Ministry of Natural Resources and Environment of Russian Federation. Moscow, 1993. 26 p.
12. Shepeta E. D., Samatova L. A., Alushkin I. V., Shchipchin V. B., Korneev I. G. Enhancement of low-grade scheelite ore processing efficiency. Journal of Mining Science. 2016. Vol. 52, No. 1. pp. 195–200.
13. Mokrousov V. A., Lileev V. A. Radiometric Treatment of Nonradioactiver Ore. Moscow : Nedra, 1979. 192 p.
14. Revnivtsev V. I., Rybakova T. G., Leman E. P. X-Ray Radiometric Separation of Complex Ferrous and Rare Metals. Moscow : Nedra, 1990. 120 p.
15. Agranat B. A. Basic Physics of Ultrasound and Supersonics. Moscow : Nedra, 1987. 352 p.
16. Gvozdev V. I. Magmatic rocks of ore-forming systems in skarn–scheelite–sulfide deposit in east Russia. Noble and Rare Metals of Siberia and Russian Far East: Ore-Forming Systems of Complex and Nonconventional Type Ore Deposits : Scientific Conference Proceedings. Irkutsk : Institut Geografi i SO RAN, 2005. Vol. 1. pp. 33–36.
17. Tomra.COM.XRT. Available at: https://www.tomra.com/en/sorting/mining/sorting-equipment/com-series/com-xrt (accessed: 19.04.2018).
18. Haslam A. Developments in the Tungsten Industry. Australia. 21st ITIA Annual General Meeting. Xiamen, China, 2008.

Language of full-text russian
Full content Buy
Back