ArticleName |
Integrated use prospects
for low-carbon schungite-bearing rocks in Karelia |
ArticleAuthorData |
Institute of Geology, Karelian Research Center, Russian Academy of Sciences, Petrozavodsk, Russia:
O. V. Myasnikova, Researcher, Candidate of Engineering Sciences, okmyasn@krc.karelia.ru A. V. Pervunina, Senior Researcher, Candidate of Geologo-Mineralogical Sciences |
Abstract |
Aiming to expand minerals and raw materials base in the Republic of Karelia, deposits of low-carbon schungite-bearing rocks are discussed from the viewpoint of application in construction industry. These rocks are mostly developed within the Onega Paleo-Proterozoic structure inside the Ludicovian (1920–2100 million years) and Kalevian (1800–1920 million years) upper horizons in the south-east of the Fenno-Scandinavian Shield. The basic low-carbon schungite-bearing rocks in Karelia are argillite, siltstone, sandstone and lyddite. Schungite content of rocks ranges as 0.1–5%. Schungite is a metamorphosed Proterozoic organic substance at meta-anthracite stage of carbonization. Most often schungite occurs in rocks as a uniform dissemination from 1 to 10 μm in size. Schungite content is maximum in lyddite and minimum in sandstone. This study analyzes two types of low-carbon schungite bearing rocks—sandstone and siltstone—from four deposits. The mineral and chemical compositions of rocks are studied by the methods of electron microscopy and X-ray fluorescent spectrometry. The mineralogical and lithochemical singularities are revealed, and the petrophysical properties which govern processing and application trends are determined. In terms of the Nigozero and Myagrozero deposits, detailed laboratory experiments are carried out. Quality of the nonmetallic minerals is evaluated. The studies of physical and mechanical properties of rocks and gravel fractions are presented; applicability of gravel in production of construction materials is considered. In siltstone areas of the deposits, it is recommended to cut rocks into slabs for external and internal lining of building, and for other architectural and constructional works. |
References |
1. General stratigraphic scale of the lower Preсambrian age in Russia : Explanatory note. Apatity : KNTs RAN, 2002. 13 p. 2. Filippov M. M., Esipko O. A. Geologo-geophysical marking horizons of Paleo-Proterozoic age in the Onega structure. Petrozavodsk : KarNTs RAN, 2016. 257 p. 3. Melezhik V. A., Prave A. R., Fallick A. E., Kump L. R., Strauss H. et al. Reading the Archive of Earth’s Oxygenation. Berlin : Springer-Verlag. 2013. Vol. 1. The Palaeoproterozoic of Fennoscandia as Context for the Fennoscandian Arctic Russia – Drilling Early Earth Project. 501 p. 4. Filippov M. M., Golubev A. I., Medvedev P. V. Organic substance of schungite-bearing rocks in Karelia (genesis, evolution, study). Petrozavodsk : KarNTs RAN, 1994. 208 p. 5. Filippov M. M. Shungite Rocks of the Onega Structure. Petrozavodsk : KarNTs RAN, 2002. 280 p. 6. Glushanin L. V., Sharov N. V., Shchiptsov V. V. (Eds.). Paleoproterozoic Onega structure (geology, tectonics, deep structure and mineralogeny). Petrozavodsk : KarNTs RAN, 2011. 431 p. 7. Sokolova I. V. Sorption humidity of light polymer-silicate concrete for exterior walls of buildings with wet-gas media. Inzhenernyi vestnik Dona. 2018. No. 1. Available at: http://www.ivdon.ru/uploads/article/pdf/IVD_175_Sokolova_doc__3_.pdf_b0f6bdac15.pdf (accessed: 19.10.2018). 8. Filippov M. M. Shungite-bearing shales of Karelia as valuable mineral raw materials for Russian construction industry. Gornyi Zhurnal. 2012. No. 5. pp. 27–29. 9. Smirnova O. M. Technology of increase of nanoscale pores volume in protective cement matrix. International Journal of Civil Engineering and Technology. 2018. Vol. 9, Iss. 10. pp. 1991–2000. 10. Greshner S. G. Large deposit of schungite shale in West Mugodzhary (South Ural). Stroitelnye Materialy. 2007. No. 5. pp. 20–21. 11. Kalinin Yu. K., Filippov M. M., Kaputin Yu. E., Mutygullin R. Kh. Quality and efficiency of schungizite material of Karelia. Petrozavodsk : KF AN SSSR, 1988. 146 p. 12. Belogurova T. P., Mikhanoshina I. A., Kameneva E. E., Petrov V. E. Walkway slab production arrangement using schungite-bearing rocks from the Myagrozero deposit. Building Stone – From Geology to Architecture : Collected Works. Petrozavodsk : KarNTs, 2015. pp. 144–145. 13. Antonets I. V., Golubev E. A., Shavrov V. G., Shcheglov V. I. Dynamic Microwave Conductivity of Graphene-Based Shungite. Technical Physics Letters. 2018. Vol. 44, Iss. 5. pp. 371–373. 14. Kwiecinska B., Pusz S., Krzesinska M., Pilawa B. Physical properties of shungite. International Journal of Coal Geology. 2007. Vol. 71, Iss. 4. pp. 455–461. 15. Alimzhanova M., Adilbekov E., Kapar A., Sagandykova G., Ashimuly K. A stationary phase for solidphase extraction based on natural nanomaterial shungite. Proceedings of the 16th International Multidisciplinary Scientific GeoConference. Albena, 2016. Book 5, Vol. 2. pp. 17–24. 16. Beryoza I. G., Bryushkovskaya T. S., Balakireva K. A., Avanesova T. P. The use of natural sorbents in the ship water purification equipment. Morskie intellektualnye tekhnologii. 2018. Vol. 1, No. 1(39). pp. 95–99. 17. Polunina I. A., Goncharova I. S., Polunin K. E., Buryak A. K. Effect of Chemical Composition of Shungite Material on Its Sorption Properties. Inorganic Materials: Applied Research. 2018. Vol. 9, Iss. 4. pp. 772–776. 18. Filippov M. M., Pervunina A. V. Schungite-bearing rocks of Karelia: use in construction of Saint-Petersburg, modern application trends. Building Stone – From Geology to Architecture : Collected Works. Petrozavodsk : KarNTs, 2015. pp. 143–144. 19. Klyuchnikova N. V., Genov I., Mukhacheva V. D., Piskareva A. O. Protective coatings based on modified phenolformaldehyde composites. Vestnik Belgorodskogo gosudarstvennogo tekhnologicheskogo universiteta im. V. G. Shukhova. 2018. No. 12. pp. 91–97. |