ArticleName |
Hydrometallurgical processes
of selective mineral liberation |
ArticleAuthorData |
All-Russian Scientific-Research Institute of Mineral Resources Named after N. M. Fedorovsky, Moscow, Russia:
E. G. Likhnikevich, Lead Researcher at the Process Department, Candidate of Technical Sciences A. V. Kurkov, Principal Researcher – Adviser to the General Director for Process, Doctor of Technical Sciences, Professor, e-mail: kurkov@vims-geo.ru S. I. Anufrieva, Head of the Process Department, Candidate of Chemical Sciences A. A. Rogozhin, First Deputy General Director Responsible for Core Operations, Candidate of Physical and Mathematical Sciences |
Abstract |
This paper examines advanced hydrometallurgical processes applicable to different types of minerals. Use of selective reagents/solvents for leaching of goldantimony arsenic-bearing concentrates ensures a high recovery of antimony in the solution (>95 %). During alkaline-glycerate leaching, almost all of the harmful impurity – arsenic – concentrates in the cake, and 70% of it remains in the cake during ferro-chloride leaching. The leach reagent can be recovered. The use of nitric acid pressure leaching to process lateritic scandium-cobaltnickel ores ensures the production of solutions with low concentrations of iron and chromium. The recovery of chromium in the solution does not exceed 22%. Following thermohydrolysis all the iron remains in the cake. Purification of the solution with a calcium carbonate suspension results in a scandium deposit and a solution for separation of cobalt and nickel compounds. Alkaline leaching of spodumene concentrates helps omit the conventional operation of high-temperature (1,100 oC) pre-roasting, which will boost the process efficiency and ensure a better environmental protection. A high-efficiency method for processing manganese carbonate ores includes a calcium-chloride (salt) method, which stands for pressure leaching of manganese, recovery of manganese from the solution by limewater precipitation, heat treatment of the precipitate to produce a high-quality manganese concentrate, and the possibility to recover the leach reagent (i.e. calcium chloride). |
keywords |
Hydrometallurgy, autoclave process, ferro-chloride leaching, alkaline-glycerate leaching, calcium-chloride method, gold-antimony arsenicbearing concentrates, lateritic scandium-cobalt-nickel ores, spodumene materials, manganese carbonate ores |
References |
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