Journals →  Tsvetnye Metally →  2022 →  #10 →  Back

REACTOR FUNCTIONAL MATERIALS
ArticleName Effect of ion beam radiation on the microstructure and porosity of dysprosium hafnate
DOI 10.17580/tsm.2022.10.06
ArticleAuthor Urusov A. A., Chuvikov S. V., Polunin K. K., Tenishev A. V.
ArticleAuthorData

Luch Research & Production Association, Podolsk, Russia:

A. A. Urusov, Head of Laboratory
S. V. Chuvikov, Research Fellow
K. K. Polunin, Research Fellow

 

National Research Nuclear University MEPhI, Moscow, Russia:
A. V. Tenishev, Associate Professor, Candidate of Technical Sciences, e-mail: avt@onil709.ru

Abstract

This paper looks at the effect of ion beam radiation on a dysprosium hafnate material (Dy2O3 – HfO2) that can potentially serve as a neutron absorber. The study was based on a serial radiography with helium and nickel ions at the temperatures of 350 and 550 oС to the doses of 20, 100, 200 and 300 dpa. Using scanning and transmission electron microscopy, the authors examined the microstructure of specimens both in their initial state and after exposure. Electron probe microanalysis helped determine the concentration of the elements in the specimens. The paper demonstrates that exposure of dysprosium hafnate to a damaging dose of 20 dpa does not lead to any visible structural changes. When the dose exceeded 100 dpa, the authors observed changes in the surface morphology of the specimens and a gradual closing-up of process-related pores. Calculation results indicate that the swelling of the dysprosium hafnate specimens does not exceed 0.1% at the maximum accumulated radiation of 200 to 300 dpa.
The authors would like to thank P. S. Dzhumaev, M. S. Staltsov and O. V. Emelianova for their support with scanning electron microscopy and electron probe microanalysis; D. P. Shornikov for his support with systematization and processing of experimental data.

keywords Absorbers, dysprosium hafnate, ion beam radiation, porosity, scanning, transmission microscopy
References

1. Risovanyi V. D., Zakharov A. V., Ponomarenko V. B., Klochkov E. P. et al. Dysprosium in nuclear engineering. Dimitrovgrad : OAO “GNTs NIIAR”, 2011. 204 p.
2. Risovanyi V. D., Zakharov A. V., Muraleva E. M., Sokolov V. F. Developing and streamlining the production of dysprosium hafnate as an absorbing material for control elements of innovative thermal reactors. Research papers of GNTs NIIAR. 2011. No. 2. pp. 8–13.
3. Risovanyi V. D., Zakharov A. V., Muraleva E. M. New promising absorbing materials for thermal reactors. Voprosy atomnoy nauki i tekhniki. Seriya “Fizika radiatsionnykh povrezhdeniy i radiatsionnoe materialovedenie”. 2005. No. 3. pp. 87–93.
4. The results of tests an absorbing material specimens manufactured in Russia and France carried out in the SM and Osiris reactors. International symposium. Vol. 1. Proceedings Contribution of Materials Investigation to the Resolution of Problems Encountered in Pressurized Water reactors. 23–27 September 2002. Fontevraud 5. pp. 529–545.
5. Risovany V. D., Zakharov A. V., Muraleva E. M., Rozhdestvensky et al. Experience and development of WWER-1000 control rod materials. Contribution of Materials Investigations to Improve the Safety and Performance of LWRs. 18–22 September. Fontevraud, 2006.
6. Shevchenko A. V., Lopato L. M., Nazarenko L. V. HfO2 systems with samarium, gadolinium and terbium oxides and dysprosium at high temperatures. Bulletin of the Academy of Sciences of the USSR: Inorganic materials. 1984. Vol. 20, No. 11. pp. 1862–1866.
7. Koshkin V. M., Dmitriev Yu. N., Zabrodskiy Yu. R., Tarnopolskaya R. L. et al. Abnormal radiation resistance of porous crystalline structures. Fizika i tekhnika poluprovodnikov. 1984. Vol. 18, Iss. 8. pp. 1373– 1378.
8. Sickafus K. E., Grimes R. W., Valdez J. A., Cleave A. et al. Radiationinduced amorphization resistance and radiation tolerance in structurally related oxides. Nature Materials. 2007. No. 6. pp. 217–223.
9. Krasnorutskiy V. S., Belash N. N., Chernov I. A. et al. Understanding how production and alloying techniques influence the properties of dysprosium hafnate tablets. Voprosy atomnoy nauki i tekhniki. 2012. No. 5. pp. 62–68.
10. Eremeeva Zh. V., Vorotylo S. A., Kaplanskiy Yu. Yu., Akhmetov A. et al. Understanding the process of sintering briquettes made of mechanically synthesized dysprosium titanate and hafnate powders. Sovremennye materialy, tekhnika i tekhnologii. Seriya: Metallurgiya i materialovedenie. 2021. No. 5. pp. 4–9.
11. Petrunin V. F., Korovin S. A. Nanocrystalline powders of dysprosium hafnate and ceramics made with them. Kristallografiya. Seriya: Nanomaterialy i keramika. 2019. Vol. 64, No. 2. pp. 314–320.
12. Gosset D. Absorber materials for Generation IV reactors. Structural Materials for Generation IV Nuclear Reactors. Woodhead Publishing, 2017. pp. 533–567.
13. Zakharov A. V. Hafnates of rare earth elements as multifunctional absorbing materials for thermal reactor control rods. Research papers of GNTs NIIAR. 2019. No. 3. pp. 89–95.

Language of full-text russian
Full content Buy
Back