Journals →  Obogashchenie Rud →  2023 →  #5 →  Back

TECHNOLOGICAL MINERALOGY
ArticleName Khodzhakul kaolins of Uzbekistan: composition, physical and chemical properties, and processing methods
DOI 10.17580/or.2023.05.06
ArticleAuthor Matchonov Sh. K., Ruzmetova A. Sh., Yakubov Yu. Kh., Kurbanov D. Sh.
ArticleAuthorData

Urgench State University (Urgench, Republic of Uzbekistan)

Matchonov Sh. K., Associate Professor, Candidate of Engineering Sciences, mbsh76@mail.ru
Ruzmetova A. Sh., Associate Professor, PhD in Engineering Sciences
Yakubov Yu. Kh., Trainee Teacher
Kurbanov D. Sh., Senior Lecturer, PhD Student

Abstract

This article identifies promising kaolin deposits in the territory of the Republic of Uzbekistan. It describes studies of the characteristics of kaolin ore of the Khodzhakul deposit, its reserves, physical and chemical properties, as well as methods for obtaining valuable products from this ore, such as metakaolin and technical alumina, in compliance with relevant standards. The results of X-ray, IR spectrographic, and differential thermal analyzes are presented; usability of Khodzhakul kaolin for obtaining the specified products is theoretically and practically studied. The experimental part of the work uses traditional qualitative and quantitative chemical analysis methods, instrumental mineral composition analysis methods, and kaolin rock sample processing experiments. The test samples were selected and prepared in compliance with the applicable standards and technical specifications for the specific products. The effects of the kaolin calcination temperatures on the production process and metakaolin properties were studied. The pozzolanic activity of metakaolin samples was established by the amount of CaO absorbed from the lime solution over 60 days. The paper describes a process flow for obtaining metakaolin by heat treatment, including the stages of kaolin drying, grinding, and roasting. A technology has been developed for isolating kaolin from the quartz-kaolin rock of the Khodzhakul deposit and for producing technical alumina by acid treatment. Three types of acids were used in the experiments: sulfuric, hydrochloric, and nitric acids. The paper proposes a process flow for obtaining technical alumina by acid treatment of metakaolin generated from the Khodzhakul kaolin. The resulting products are in great demand in many industrial sectors of Uzbekistan. This indicates the importance and relevance of the research conducted and process flows presented.

keywords Kaolin, deposits of Uzbekistan, ore reserves, ore properties, processing, metakaolin, technical alumina
References

1. Vaisberg L. A., Kononov O. V., Ustinov I. D. Fundamentals of geometallurgy. St. Petersburg: Russian Collection, 2020. 376 p.
2. Overview of the raw kaolin and enriched kaolin market in the CIS. Moscow: Infomain, 2019. 16 p. URL: http://www.infomine.ru/files/catalog/64/file_64.pdf (accessed: 09.08.2023).
3. Eminov A. M., Kadirova Z. R., Zhumanov Yu. K. Study of physico-chemical properties of promising kaolin deposits of Navoi viloyat. Uzbekskiy Khimicheskiy Zhurnal. 2019. No. 6. pp. 31–37.
4. Eminov A. A. Study of the chemical and mineralogical composition of kaolins from the Alliance deposit and their ceramic and technological properties. Problems of geology and subsoil development. Proc. of the XXI International symposium named after Academician M. A. Usov, Tomsk, April 3–7, 2017. Vol. 2. pp. 445–447.
5. Zhumanov Yu. K. Physico-chemical study of kaolins of the Zarafshan region. Universum: Tekhnicheskie Nauki. Electron. scientific journal. 2018. No. 10. URL: http://7universum.com/ru/tech/archive/item/6489 (accessed: 11.08.2023).
6. Kaolin. Methodological recommendations for the application of the Classification of deposit reserves and predicted mineral resources. Moscow: Geoinformmark, 2007. pp. 3–9.
7. Summary review of deposits and occurrences of solid minerals in the Republic of Karakalpakstan. Tashkent: Gosgeolinformotsentr, 2001. 388 p.
8. Babaev Z. K., Ruzmetova A. Sh., Musaev A. A. Kaolins of the Khodzhakul deposit – valuable raw materials for the production of refractory conditions. Actual problems of development of chemistry, chemical technology, oil and gas and light industry in the Republic of Karakalpakstan. Nukus, 2019. pp. 82–83. (In Uzbek)
9. Zhumaniyazov M. Zh., Yunusov M. Yu., Babaev Z. K. Physico-chemical analysis of coarse-grained quartz-kaolin sands and technology of their processing. Сomposite Materials. 2021. No. 1. pp. 53–55. (In Uzbek)
10. Mikhailyuta E. S., Alekseev E. V., Koleda V. V., Shevchenko T. A. Specifics of the phase composition formation
of metakaolins and its influence on their properties. Tsement i Yego Primenenie. 2012. No. 9. pp. 66–69.
11. Gerasimov A. M., Eremina O. V. Application microwave radiation for directional changes of layered silicates properties. Eurasian Mining. 2021. No. 1. pp. 55–60.
12. Bauman A. V., Stepanenko A. I., Baranova A. A. Water consumption calculation methodology in the design of clay mineral washing systems. Obogashchenie Rud. 2022. No. 2. pp. 3–8.
13. Potapova E. N., Manushina A. S., Urbanov A. V. Influence of kaolin heat treatment on its properties. Novye Ogneupory. 2017. No. 10. pp. 26–30.
14. Shepelev I. I., Sakhachev A. Yu., Zhyzhaev A. M., Dashkevich R. Y., Golovnykh N. V. Extraction of valuable components from alumosilicate natural and technogenic materials under alumina production by sintering. Vestnik Irkutskogo Gosudarstvennogo Tekhnicheskogo Universiteta. 2018. Vol. 22, No. 4. pp. 203–212.
15. Arsentyev V. A., Gerasimov A. M., Mezenin A. O. Kaolines beneficiation technology study with application of hydrothermal modification. Obogashchenie Rud. 2017. No. 2. pp. 3–8
16. Choudhary R. P., Sheoran A. S., Trivedi S. K. A small kaolin beneficiation unit: State of art. International Journal of Earth Sciences and Engineering. 2012. No. 4. pp. 775–781.
17. Wang N., Gu H., Wen H. Enrichment of niobium and titanium from kaolin using an acid–alkali leaching process. Metallurgical and Materials Transactions. 2018. Vol. 49. pp. 3552–3558.
18. Bagherzadeh Y., Golmakani M. H., Karimi E. Z. Straight synthesis of α and γ alumina from kaolin by HCl acid leaching. Journal of Mining and Metallurgy Section B Metallurgy. January 2023. DOI: 10.2298/JMMB230101017B
19. Dondi M., Bertolotti G. P. Basic guidelines for prospecting and technological assessment of clays for the ceramic industry. Part 1. Interceram — International Ceramic Review. 2021. Vol. 70. pp. 36–46.
20. Erdemoğlu M., Birinci M., Uysal T. Alumina production from clay minerals: Current reviews. Journal of Polytechnic. 2018. Vol. 21, Iss. 2. pp. 387–396.
21. Bu X., Evans G., Xie G., Peng Y., Zhang Z., Ni C. Removal of fine quartz from coal-series kaolin by flotation. Applied Clay Science. 2017. Vol. 143. pp. 437–444.
22. Pat. WO 2009 114404 (USA).

Language of full-text russian
Full content Buy
Back