Journals →  Tsvetnye Metally →  2023 →  #10 →  Back

MATERIALS SCIENCE
ArticleName Effect of ageing parameters on the formation of metastable strengthening T' and η' precipitates in aluminium alloy V-1977
DOI 10.17580/tsm.2023.10.11
ArticleAuthor Zavodov A. V., Lukina E. A., Shlyapnikova T. A.
ArticleAuthorData

Kurchatov Institute National Research Centre – VIAM, Moscow, Russia

A. V. Zavodov, Category 2 Engineer, Candidate of Technical Sciences, e-mail: zavodovad@gmail.com
E. A. Lukina, Head of Laboratory, Candidate of Technical Sciences, e-mail: evaluk69@gmail.com
T. A. Shlyapnikova, Deputy Head of Laboratory, Candidate of Technical Sciences, e-mail: tanusha1607@yandex.ru

Abstract

This study compared the effects of one-, two- and three-step ageing of aluminium alloy V-1977 on the mechanical and corrosion properties, as well as on the characteristics of metastable strengthening T′ and η′ precipitates. With the help of scanning electron microscopy and quantitative analysis, it is shown that the maximum strengthening effect (720 MPa) can be reached after applying a one-step ageing mode T1 at the temperature of 120 oC in the course of 24 hours. This effect becomes the result of type I Guinier–Preston zones forming simultaneously with lamellar metastable η′ precipitate having the respective sizes of 3.2 and 4.0 nm. Application of a three-step ageing mode T12 brings the strength of the alloy down to 680 MPa due to the coarsening of the η′ precipitate grain from 4.0 to 5.7 nm, a double growth of the η precipitate at the grain boundaries and the formation of the second metastable spherical T' precipitate with the size of 3.3 nm instead of type I Guinier–Preston zones. It is shown that the presence of zirconium intermetallides Al3Zr, which have a completely coherent interface, does not affect the nucleation of the metastable η′ precipitate. It is highlighted that the application of the three-step ageing mode T12 helps maintain the high strength properties in V-1977 alloy by weakening its proneness to layer corrosion from 7–8 to 4–5 points.

keywords η′ precipitate, MgZn2, V-1977 alloy, Al – Zn – Mg – Cu system, artificial ageing, metastable precipitates
References

1. Fridlyander I. N. High-strength aluminium alloys with zinc, magnesium and copper. Metallovedenie i termicheskaya obrabotka metallov. 2003. No. 9. pp. 1–13.
2. Senatorova O. G. et al. High-strength alloys and superalloys of the conventional Al – Zn – Mg – Cu system, their role in engineering and development prospects. Tekhnologiya legkikh splavov. 2016. No. 2. pp. 43–49.
3. Kablov E. N. et al. Effect of heat treatment on the structure and properties of extruded semi-finished products made of innovative extra-strength aluminium alloy V-1977. Metallovedenie i termicheskaya obrabotka metallov. 2023. No. 1. pp. 28–33.
4. Kablov E. N. et al. Understanding the applicability of combination anodic dissolution of the Al – Mg – Si – Cu alloy with the aim to predict the loss of mechanical properties as a result of atmospheric corrosion. Aviatsionnye materialy i tekhnologii. 2020. No. 2. pp. 63–73. DOI: 10.18577/2071-9140-2020-0-2-63-73
5. Abramova M. G. On confirming the identity of the mechanism of corrosive failure of aluminium alloys (A review). Part 1. Atmospheric corrosion. Aviatsionnye materialy i tekhnologii. 2020. No. 4. pp. 86–94. DOI: 10.18577/2071-9140-2020-0-4-86–94
6. Abramova M. G. On confirming the identity of the mechanism of corrosive failure of aluminium alloys (A review). Part 2. Sea water corrosion. Aviatsionnye materialy i tekhnologii. 2021. No. 1. pp. 95–103. DOI: 10.18577/2713-0193-2021-0-1-95–103
7. Senatorova O. G. et al. Effect of various minor additions on the structure and properties of high-strength Al – Zn – Mg – Cu alloy plates. Aviatsionnye materialy i tekhnologii. 2002. No. 2. pp. 91–95.
8. Senatorova O. G. et al. Understanding the structure and properties of extrastrength Al – Zn – Mg – Cu alloys. Metallurg. 2016. No. 9. pp. 78–82.
9. Dai P. et al. Thermal stability analysis of a lightweight Al – Zn – Mg – Cu alloy by TEM and tensile tests. Materials Characterization. 2019. Vol. 153. pp. 271–283.
10. Astashkin A. I. et al. Structure and properties of solid forgings with low residual stresses made of aluminium alloy 1933sb of balanced composition. Trudy VIAM. 2021. No. 7. pp. 13–21. DOI: 10.18577/2307-6046-2021-0-7-13–21

11. Tai C.-L. et al. The effect of minor addition of Mn in AA7075 Al – Zn – Mg – Cu aluminum alloys on microstructural evolution and mechanical pro perties in warm forming and paint baking processes. International Journal of Lightweight Materials and Manufacture. 2023. Vol. 6, Iss. 4. pp. 521–533.
12. Fridlyander I. N. Regularities in aluminium alloy ageing. Metallovedenie i termicheskaya obrabotka metallov. 1980. No. 6. pp. 22–28.
13. Fridlyander I. N., Gerchikova N. S., Zaytseva N. I. Understanding the ageing kinetics of V92Ts alloy of the Al – Zn – Mg system. Metallovedenie i termicheskaya obrabotka metallov. 1966. No. 8. pp. 11–15.
14. Zou Y. et al. Co-precipitation of T′ and η′ phase in Al – Zn – Mg – Cu alloys. Materials Characterization. 2020. Vol. 169. 110610.
15. Zou Y. et al. Investigation on microstructure and mechanical properties of Al – Zn – Mg – Cu alloys with various Zn/Mg ratios. Journal of Materials Science & Technology. 2021. Vol. 85. pp. 106–117.
16. Zou Y. et al. Tailoring phase fractions of T' and η′ phases in dualphase strengthened Al – Zn – Mg – Cu alloy via ageing treatment. Transactions of Nonferrous Metals Society of China. 2022. Vol. 32, Iss. 10. pp. 3182– 3196.
17. Bendo A. et al. Atomic scale HAADF-STEM study of η′ and η1 phases in peak-aged Al – Zn – Mg alloys. Journal of Materials Science. 2018. Vol. 53, Iss. 6. pp. 4598–4611.
18. Chung T.-F. et al. Transmission electron microscopy investigation of separated nucleation and in-situ nucleation in AA7050 aluminium alloy. Acta Materialia. 2018. Vol. 149. pp. 377–387.
19. Chung T.-F. et al. An atomic scale structural investigation of nanometresized η precipitates in the 7050 aluminium alloy. Acta Materialia. 2019. Vol. 174. pp. 351–368.
20. Onishchenko G. G., Kablov E. N., Ivanov V. V. Scientific and technological development of Russia in the context of achieving national goals: Issues and solutions. Innovatsii. 2020. No. 6. pp. 3–16.
21. Nechaykina T. A. et al. Understanding the effect of T1 heat strengthening mode on the structure and properties of extruded strips made of innovative extra-strength aluminium alloy of the Al – Zn – Mg – Cu system. Materialovedenie. 2020. No. 10. pp. 11–16.
22. Dorward R. C. Precipitate coarsening during overaging of Al – Zn – Mg – Cu alloy. Materials Science and Technology. 1999. Vol. 15, Iss. 10. pp. 1133– 1138.
23. GOST 1497–84. Metals. Methods of tension test. Introduced: 01.01.1986.
24. GOST 9.904–82. Unified system of corrosion and ageing protection. Alluminium alloys. Accelerated test method for exfoliating corrosion. Introduced: 01.07.1983.
25. Cahn R. W., Haasen P. T. Physical metallurgy: In 3 volumes. Vol. 2: Phase transformations in metals and alloys and alloys with special physical properties. 3rd revised edition. Translated from English. Moscow : Metallurgiya, 1990. 624 p.
26. Vakhromov R. O. et al. Effect of homogenization annealing on the structure and properties of ingots of 1933 alloy of the Al – Zn – Mg – Cu system. Trudy VIAM. 2015. No. 11. 01. DOI: 10.18577/2307-6046-2015-0-11-1-1
27. Wang W. Z. et al. Revisiting the role of Zr micro-alloying in a Mg – Nd – Zn alloy. Journal of Alloys and Compounds. 2020. Vol. 832. 155016.
28. Sha G., Cerezo A. Early-stage precipitation in Al – Zn – Mg – Cu alloy (7050). Acta Materialia. 2004. Vol. 52, Iss. 15. pp. 4503–4516.
29. Fridlyander I. N., Senatorova O. G., Gubareva T. F. The kinetics of twostep ageing of V95 alloy. Metallovedenie i termicheskaya obrabotka metallov. 1978. No. 6. pp. 27–30.
30. Yang X. B. et al. A high-strength Al – Zn – Mg alloy hardened by the T-phase precipitates. Journal of Alloys and Compounds. 2014. Vol. 610. pp. 69–73.

Language of full-text russian
Full content Buy
Back