Journals →  Non-ferrous Мetals →  2024 →  #1 →  Back

MATERIALS SCIENCE
ArticleName Structure and properties of cast in-situ metal matrix composites with strontium addition
DOI 10.17580/nfm.2024.01.06
ArticleAuthor Deev V. B., Prusov E. S., Ri E. Kh., Shabaldin I. V.
ArticleAuthorData

Wuhan Textile University, Wuhan, China1 ; National University of Science and Technology “MISiS”, Moscow, Russia2 ; Vladimir State University named after Alexander and Nikolay Stoletovs, Vladimir, Russia3

V. B. Deev*, Professor, Chief Researcher3, Professor at the Faculty of Mechanical Engineering and Automation1,
Professor at the Department of Metal Forming2, e-mail: deev.vb@mail.ru

 

Vladimir State University named after Alexander and Nikolay Stoletovs, Vladimir, Russia

E. S. Prusov, Associate Professor, Department of Functional and Constructional Materials Technology

I. V. Shabaldin, Research Assistant, Department of Functional and Constructional Materials Technology

 

Pacific National University, Khabarovsk, Russia

E. Kh. Ri, Professor, Head of the Department of Foundry Engineering and Metal Technology

 

*Correspondence author.

Abstract

The paper investigates the influence of a strontium modifying additive in the range of 0.05 to 0.3 wt.% on the structure formation and tribological properties of cast aluminum matrix composites based on the pseudo-binary Al – Mg2Si system (in the hypereutectic composition range). It is shown that strontium modification (0.2 wt.% Sr) of cast aluminum matrix composites Al + 15 wt.% Mg2Si leads to a reduction in the average size of Mg2Si reinforcing particles to 24 μm (by Feret diameter) with an aspect ratio of 1.28 and a particle distribution uniformity index in the cast material structure of 0.44. For a highly hypereutectic composition (25 wt.% Mg2Si), strontium modification in the same amount results in a decrease in the average size of Mg2Si particles to 44.8 μm and a change in their morphology to blocky, compact, and close to equiaxed, with a distribution uniformity index of 0.24. Further increase in the concentration of the modifying additive lead to some particle coarsening, likely due to the over-modification effect, as well as the precipitation of excess intermetallic phases with needle-like morphology. Tribological tests under dry friction conditions using a ball-on-disc scheme in conjunction with steel reveal a significant reduction in the coefficient of friction (by 25–30%) and mass wear (by more than an order of magnitude) for strontium-modified cast samples of Al – Mg2Si composites.

This research was funded by the Russian Science Foundation (Project № 20-19-00687-П, https://rscf.ru/project/23-19-45019/).

keywords Cast aluminum matrix composites, strontium, modification, primary Mg2Si crystals, pseudobinary eutectic, structural and morphological characteristics, tribological properties
References

1. Taha M. A. Industrialization of Cast Aluminum Matrix Composites (AMCCs). Materials and Manufacturing Processes. 2001. Vol. 16, Iss. 5. pp. 619–641.
2. Miracle D. B. Metal Matrix Composites – from Science to Technological Significance. Composites Science and Technology. 2005. Vol. 65, Iss. 15-16. pp. 2526–2540.
3. Mavhungu S. T., Akinlabi E. T., Onitiri M. A., Varachia F. M. Aluminum Matrix Composites for Industrial Use: Advances and Trends. Procedia Manufacturing. 2017. Vol. 7. pp. 178–182.
4. Prasad S., Asthana R. Aluminum Metal-Matrix Composites for Automotive Applications: Tribological Conside rations. Tribology Letters. 2004. Vol. 17. pp. 445–453.
5. Sivananthan S., Ravi K., Samson Jerold Samuel C. Effect of SiC Particles Reinforcement on Mechanical Properties of Aluminium 6061 Alloy Processed Using Stir Casting Route. Materials Today: Proceedings. 2020. Vol. 21, Pt. 1. pp. 968–970.
6. Singh P., Gupta R., Izan S., Singh S., Sharma R., Dwivedi S. P. Tribo-Mechanical Behaviour of Aluminium-Based Metal Matrix Composite: a Review. Materials Today: Proceedings. 2021. Vol. 47, Pt. 13. pp. 3828–3832.
7. Rohatgi P. K., Ajay Kumar P., Chelliah Nagaraj M., Rajan T. P. D. Solidification Processing of Cast Metal Matrix Composites Over the Last 50 Years and Opportunities for the Future. JOM. 2020. Vol. 72. pp. 2912–2926.
8. Kandpal B. C., Kumar J., Singh H. Manufacturing and Technological Challenges in Stir Casting of Metal Matrix Composites – a Review. Materials Today: Proceedings. 2018. Vol. 5, Iss. 1, Pt. 1. pp. 5–10.
9. Prusov E.S., Panfilov A.A. Properties of Cast Aluminum-Based Composite Alloys Reinforced by Endogenous and Exogenous Phases. Russian Metallurgy (Metally). 2011. No. 7. P. 670–674.
10. Zhang J., Fan Z., Wang Y. Q., Zhou B. L. Equilibrium Pseudobinary Al–Mg2Si Phase Diagram. Materials Science and Technology. 2001. Vol. 17, Iss. 5. P. 494–496.
11. Georgatis E., Lekatou A., Karantzalis A. E., Petropoulos H., Katsamakis S., Poulia A. Development of a Cast Al – Mg2Si – Si in Situ Composite: Microstructure, Heat Treatment, and Mechanical Properties. Journal of Materials Engineering and Performance. 2013. Vol. 22. pp. 729–741.
12. Ghiasinejad J., Emamy M., Ghorbani M. R., Malekan A. Wear behavior of Al-Mg2Si cast in-situ composite: Effect of Mg2Si Different Volume Fractions. AIP Conference Proceedings. 2010. Vol. 1252. P. 1012–1017.
13. Biswas P., Mondal M. K., Mandal D. Effect of Mg2Si Concentration on the Dry Sliding Wear Behavior of Al-Mg2Si Composite. Journal of Tribology. 2019. Vol. 141, Iss. 8. 081601.
14. Liu Z., Xie M., Liu X. M. Microstructure and Properties of in-Situ Al–Si–Mg2Si Composite Prepared by Melt Superheating. Applied Mechanics and Materials. 2011. Vol. 52. pp. 750–754.
15. Si Y., Kevluzov D. S. Research on the Long-Lasting and Remelting Properties of Nd Modification Effect on Cast Al–Mg2Si Metal Matrix Composite. Materials Science Forum. 2020. Vol. 1001. pp. 196–201.
16. Zhao Y. G., Qin Q. D., Zhou W., Liang Y. H. Microstructure of the Ce-Modified in Situ Mg2Si/Al – Si – Cu Composite. Journal of Alloys and Compounds. 2005. Vol. 389, Iss. 1-2. pp. L1–L4.
17. Si Y. Effect of Pr Modification Treatment on the Microstructure and Mechanical Properties of Cast Al – Mg2Si Metal Matrix Composite. Advanced Materials Research. 2014. Vol. 936. pp. 23–27.
18. Jin Y., Fang H., Wang S., Chen R., Su Y., Guo J. Effects of Eu Modification and heat Treatment on Microstructure and Mechanical Properties of Hypereutectic Al–Mg2Si Composites. Materials Science and Engineering: A. 2022. Vol. 831. 142227.
19. Liu Y.T., Tong X., Lin J.X., Niu L.Y., Li G.Y. The influences of holmium on microstructure and properties of in situ Mg2Si/Al composites. Advanced Materials Research. 2014. Vol. 900. pp. 154–159.
20. Deev V., Prusov E., Shurkin P., Ri E., Smetanyuk S., Chen X., Konovalov S. Effect of La Addition on Solidification Behavior and Phase Composition of Cast Al – Mg – Si Alloy. Metals. 2020. Vol. 10, Iss. 12. 1673.
21. Prusov E., Shabaldin I., Deev V. Quantitative Characterization of the Microstructure of in Situ Aluminum Matrix Composites. Journal of Physics: Conference Series. 2021. Vol. 2131. 042040.

Full content Structure and properties of cast in-situ metal matrix composites with strontium addition
Back