Название |
Improving the grades
of fine-grained magnetite concentrates by combining sulfide
and silicate flotation |
Реферат |
The practical experience of processing fine-grained magnetite ores shows that silicon dioxide and sulfur are the main impurities in iron ore concentrates negatively affecting the concentrate grade. Reverse flotation is the most effective method for improving concentrate grade, as it efficiently extracts gangue minerals into the froth product. Using magnetite concentrates obtained from ore at one of the Arctic Zone deposits in Northwestern Russia as an example, this study explores the potential to enhance their grades through flotation methods. The majority of the concentrate samples studied consisted of material sized at 92–93 % of the –0.05 mm class. Optimal conditions for sulfide and silicate flotation have been established. It has been demonstrated that sulfide flotation using xanthate as the collector is most effective at natural pH values, without the addition of pH regulators. Higher silicate recovery is observed when using cationic collectors at pH 9.4–10.0. Sulfide flotation followed by silicate flotation on two iron ore concentrate samples, initially containing 69.7 % and 68.5 % iron, produced high-grade concentrates with iron content ranging from 70.2 % to 70.6 %. The iron losses to tailings under the optimal conditions were 11.3 % (for sample K-1) and 8.5 % (for sample K-2). In order to reduce iron losses, it is advisable to include cleaner flotation of the silicate product at pH 9.2–9.4 using sodium oxalate as a depressant of iron-containing minerals. The resulting products can be returned for additional processing, thereby reducing iron losses to tailings. |
Библиографический список |
1. Yushina T. I., Chanturia E. L., Dumov A. M., Myaskov A. V. Modern trends of technological advancement in iron ore processing. Gornyi Zhurnal. 2021. No. 11. pp. 75–83. 2. Gurman M. A., Aleksandrova T. N. Study of the dressability of poor iron ores. Gornyi Informatsionno-analiticheskiy Byulleten'. 2010. No. S4. pp. 289–297. 3. Terekhin E. P., Chueva E. A., Khvorostyanova V. I. Improvement of additional mineral processing technology to increase the quality of iron ore concentrate. Tekhnika i Tekhnologiya Gornogo Dela. 2023. No. 3. pp. 82–93. 5. Fan G., Wang L., Cao Y., Li Ch. Collecting agent–mineral interactions in the reverse flotation of iron ore: A brief review. Minerals. 2020. Vol. 10. DOI: 10.3390/min10080681 6. Kolokoltsev V. M., Kotok A. P., Dolbilov K. A. Problem with sulfur in cast steel. Vestnik Magnitogorskogo Gosudarstvennogo Tekhnicheskogo Universiteta im. G. I. Nosova. 2014. No. 3. pp. 30–32. 7. Ismagilov R. I., Kozub A. V., Gridasov I. N., Shelepov E. V. Case study: Advanced solutions applied by JSC Andrei Varichev Mikhailovsky GOK to improve ferruginous quartzite concentration performance. Gornaya Promyshlennost'. 2020. No. 4. pp. 98–103. 8. Pelevin A. E., Sytykh N. A. Fine hydraulic screening for staged separation of titanium-magnetite concentrate. Obogashchenie Rud. 2021. No. 1. pp. 8–14. 9. Ismagilov R. I., Chanturiya E. L., Shekhirev D. V., Rakhimov Kh. K. Experimental evaluation of the effectiveness of cationic collectors in the reverse flotation of the over-lattice product of fine sieving of ordinary magnetite concentrate of the Mikhailovsky GOK named after A. V. Varichev. Modern problems of complex and deep processing of natural and nontraditional raw materials (Plaksinsky Readings – 2023). Мoscow: Sputnik+ Publishing House, 2023. pp. 251–255. 10. Zhang X., Gu X., Han Yu. et al. Flotation of iron ores: A review. Mineral Processing and Extractive Metallurgy Review. 2021. Vol. 42, Iss. 3. pp. 184–212. 11. Nakhaei F., Irannajad M. Reagents types in flotation of iron oxide minerals: A review. Mineral Processing and Extractive Metallurgy Review. 2017. Vol. 39. pp. 89–124. 12. Opalev A. S., Alekseeva S. A. Methodological substantiation of the choice for optimal modes of equipment operation during the stage-wise concentrate removal in iron ores beneficiation. Zapiski Gornogo Instituta. 2022. Vol. 256. pp. 593–602. 13. Tereshchenko S. V., Shibaeva D. N., Kompanchenko A. A., Alekseeva S. A. Research of the influence of material composition and size of iron quartzites of the Olenegorsk deposit on the results of dry magnetic separation. Obogashchenie Rud. 2020. No. 6. pp. 15–20. 14. Ma X., Marques M., Gontijo C. Comparative studies of reverse cationic/anionic flotation of Vale iron ore. International Journal of Mineral Processing. 2011. Vol. 3–4. pp. 179–183. 15. Ma M. Froth flotation of iron ores. International Journal of Mining Engineering and Mineral Processing. 2012. Vol. 1, Iss. 2. pp. 56–61. 16. Filippov L. O., Severov V. V., Filippova I. V. An overview of the beneficiation of iron ores via reverse cationic flotation. International Journal of Mineral Processing. 2014. Vol. 127. pp. 62–69. 17. Houot R. Beneficiation of iron ore by flotation — Review of industrial and potential applications. International Journal of Mineral Processing. 1983. Vol. 10, Iss. 3. Р. 183–204. 18. Avdokhin V. M., Gubin S. L. Reverse cationic flotation of fine flotation concentrates. Gornyi Informatsionno-analiticheskiy Byulleten'. 2006. No. 5. pp. 324–331. 19. Liu A., Fan M., Li Z. Synergistic efect of a mixture of dodecylamine and kerosene on separation of magnetite ore. Physicochemical Problems of Mineral Processing. 2016. Vol. 52, Iss. 2. pp. 647–661. 20. Tohry A., Dehghan R., Mohammadi-Manesh H., Filho L., Chelgani S. C. Effect of ether mono amine collector on the cationic flotation of micaceous minerals — A comparative study. Sustainability. 2021. Vol. 13. DOI: 10.3390/su131911066 21. Araujo V. A., Lima N., Azevedo A., Bicalho L., Rubio J. Column reverse rougher flotation of iron bearing fine tailings assisted by HIC and a new cationic collector. Minerals Engineering. 2020. Vol. 156. DOI: 10.1016/j.mineng.2020.106531 22. Filippov L. O., Filippova I. V., Severov V. V. The use of collectors mixture in the reverse cationic flotation of magnetite ore: The role of Fe-bearing silicates. Minerals Engineering. 2023. Vol. 2. pp. 91–98. 23. Filippov L. O., Silva K., Piçarra A. et al. Iron ore slimes flotation tests using column and amidoamine collector without depressant. Minerals. 2021. Vol. 11. DOI: 10.3390/min11070699 24. Braga Junior M. M., Peres A. E. C. Effect of coarse quartz scalping on the reverse cationic flotation of iron ore. Revista de la Facultad de Ingenieria. 2011. No. 25. pp. 1–9. 25. Chanturia E. L., Gzogyan S. R. Features of sulfide ferruginous quartzite mineralization. Fiziko-tekhnicheskie Problemy Razrabotki Poleznykh Iskopayemykh. 2009. No. 5. pp. 95–98. 26. Gzogyan S. R. The question of removal of sulphur from magnetite concentrates deposits of KMA. Nauchnye Vedomosti. Seriya: Estestvennye Nauki. 2018. Vol. 42, No. 1. pp. 56–63. 27. Kameneva E. E., Rukhlenko E. D. Ways to increase grade of magnetite concentrate produced by the «Kovdorsky GOK» JSC. Obogashchenie Rud. 2002. No. 1. pp. 27–31. |