Journals →  Non-ferrous Metals →  2024 →  #2 →  Back

MATERIALS SCIENCE
ArticleName Microhardness of gas-dynamic coatings from aluminum powder multi-reinforced with fullerenes and aluminum oxide
DOI 10.17580/nfm.2024.02.08
ArticleAuthor Aborkin A. V., Babin D. M., Elkin A. I., Ryabkova V. V.
ArticleAuthorData

Vladimir State University named after Alexander and Nikolay Stoletovs, Vladimir, Russia

А. V. Aborkin, Candidate of Technical Sciences, Associated Professor, Department of Technology of Mechanical Engineering, e-mail: aborkin@vlsu.ru
D. M. Babin, Senior Researcher, e-mail: necros-m2@yandex.ru
A. I. Elkin, Candidate of Technical Sciences, Associated Professor, Head of Department of Technology of Mechanical Engineering, e-mail: elkin@vlsu.ru
V. V. Ryabkova, Junior Researcher, e-mail: vvryabkova@mail.ru

Abstract

This study presents data on the influence of aluminum oxide content in the powder mixture on the microhardness of gas-dynamic coatings based on the nanocomposite powder AlMg6/C60. The synthesis of the powders was carried out through a two-stage high-energy processing of the initial components in a planetary ball mill. Powder characterization was conducted using scanning electron microscopy, granulometric analysis, and X-ray phase analysis. The obtained powders were used for cold gas-dynamic spraying. Microstructure analysis of the coatings revealed a uniform distribution of reinforcing particles throughout their volume. It was established that the addition of 10–50 wt.% Al2O3 into the powder mixture, along with mechanical treatment in the planetary mill, increases the coating’s microhardness by approximately 30–45% compared to the material reinforced solely with C60.

The research was carried out within the state assignment in the field of scientific activity of the Ministry of Science and Higher Education of the Russian Federation (theme FZUN-2024-0004, state assignment of the VlSU).

keywords Gas-dynamic spraying, coatings, fullerenes, microhardness, structure
References

1. Yin S., Cavaliere P., Aldwell B., Jenkins R., Liao H., Li W., Lupoi R. Cold Spray Additive Manufacturing and Repair: Fundamentals and Applications. Additive Manufacturing. 2018. Vol. 21. pp. 628–650.
2. Spencer K., Fabijanic D. M., Zhang M.-X. The Use of Al – Al2O3 Cold Spray Coatings to Improve the Surface Properties of Magnesium Alloys. Surface and Coatings Technology. 2009. Vol. 204, Iss. 3. pp. 336–344.
3. Shockley J. M., Strauss H. W., Chromik R. R., Brodusch N., Gauvin R., Irissou E., Legoux J.-G. In Situ Tribometry of Cold-Sprayed Al-Al2O3 composite Coatings. Surface and Coatings Technology. 2013. Vol. 215. pp. 350–356.
4. Raoelison R. N., Xie Y., Sapanathan T., Planche M. P., Kromer R., Costil S., Langlade C. Cold Gas Dynamic Spray Technology: A Comprehensive Review of Processing Conditions for Various Technological Developments Till to Date. Additive Manufacturing. 2018. Vol. 19. pp. 134–159.
5. Adaan-Nyiak M. A., Tiamiyu A. A. Recent Advances on Bonding Mechanism in Cold Spray Process: A Review of Single-Particle Impact Methods. Journal of Materials Research. 2023. Vol. 38. pp. 69–95.
6. Xie X., Yin S., Raoelison R.-nirina, Chen C., Verdy C., Li W., Ji G., Ren Z., Liao H. Al Matrix Composites Fabricated by Solid-State Cold Spray Deposition: a Critical Review. Journal of Materials Science & Technology. 2021. Vol. 86. pp. 20–55.
7. Li W., Assadi H., Gaertner F., Yin S. A Review of Advanced Composite and Nanostructured Coatings by Solid-State Cold Spraying Process. Critical Reviews in Solid State and Materials Sciences. 2018. Vol. 44, Iss. 2. pp. 109–156.
8. Prusov E. S., Deev V. B., Shurkin P. K., Arakelian S. M. The Effect of Alloying Elements on the Interaction of Boron Carbide with Aluminum Melt. Non-ferrous Metals. 2021. No. 1. pp. 7–33.
9. Mansurov Yu. N., Kurbatkina E. I., Buravlev I. Yu., Reva V. P. Features of Structure’s Formation and Properties of Composite Aluminum Alloy Ingots. Non-ferrous Metals. 2015. No. 2. pp. 40–47.
10. Aborkin A. V., Alymov M. I., Arkhipov V. E., Khrenov D. S. Formation of Heterogeneous Powder Coatings with a Two-Level Micro-and Nanocomposite Structure under Gas-Dynamic Spraying Conditions. Doklady Physics. 2018. Vol. 63. pp. 50–54.
11. Evdokimov I. A., Perfilov S. A., Pozdnyakov A. A., Blank V. D., Bagramov R. Kh., Perezhogin I. A., Kulnitsky B. A., Kirichenko A. N., Aksenenkov V. V. Nanostructured Composite Materials Based on Al – Mg Alloy Modified with Fullerene C60. Inorganic Materials: Applied Research. 2018. Vol. 9. pp. 472–477.
12. Choi H. J., Shin J. H., Bae D. H. Self-Assembled Network Structures in Al/C60 Composites. Carbon. 2010. Vol. 48, Iss. 13. pp. 3700–3707.
13. Reshetniak V., Reshetniak O., Aborkin A., Nederkin V., Filippov A. Effect of the Interface on the Compressibility of Substances with Spherical Nano-Inhomogeneities on the Example of Al/C60. Nanomaterials. 2022. Vol. 12. 2045.
14. Popova O. I., Glebov V. A., Glebov A. V. Enhancement of Composite Magnets Mechanical Strength by Using of Fullerenes. Tsvetnye Metally. 2010. No. 12. pp. 60–63.
15. Fernandez R., Jodoin B. Cold Spray Aluminum–Alumina Cermet Coatings: Effect of Alumina Content. Journal of Thermal Spray Technology. 2018. Vol. 27. pp. 603–623.
16. Fernandez R., Jodoin B. Cold Spray Aluminum–Alumina Cermet Coatings: Effect of Alumina Morphology. Journal of Thermal Spray Technology. 2019. Vol. 28. pp. 737–755.
17. Kuang Nguyen, Aleshchenko A. S., Guseynov E. R. Understanding the Process of Installing Al + Al2O3 Powder Coatings by Cold Gas Dynamic Spraying on Substrates with Different Surface Roughness. Tsvetnye Metally. 2021. No. 7. pp. 52–57.
18. Aborkin A., Babin D., Belyaev L., Bokaryov D. Enhancing the Microhardness of Coatings Produced by Cold Gas Dynamic Spraying through Multi-Reinforcement with Aluminum Powders Containing Fullerenes and Aluminum Nitride. Journal of Manufacturing and Materials Processing. 2023. Vol. 7, Iss. 6. 203.
19. Aborkin A. V., Arkhipov V. E., Sachkova N. V., Sychev A. E., Alymov M. I. Effect of Al2O3 on the Microhardness of AMg2/Graphite Nanocomposite Powder Gas Dynamic Coatings on Aluminum Alloys. Metal Science and Heat Treatment. 2019. Vol. 61. pp. 360–365.
20. Aborkin A. V., Alymov M. I., Kireev A. V., Sobol’kov A. V., Arkhipov V. E. Structure and Efficiency of Gas-Dynamic Deposition of Hybrid Coatings Based on a Nanocrystalline Aluminum Matrix. Metallurgist. 2018. Vol. 62. pp. 809–814.
21. Popov V. A. X-ray Micro-Absorption Enhancement for non-Agglomerated Nanodiamonds in Mechanically Alloyed Aluminium Matrix Composites. Physica Status Solidi A. 2015. Vol. 212. pp. 2722–2726.
22. Aborkin A. V., Alymov M. I., Kireev A. V., Elkin A. I., Sobol’kov A. V. Mechanically Synthesized Composite Powder Based on AMg2 Alloy with Graphite Additives: Particle Size Distribution and Structural-Phase Composition. Nanotechnologies in Russia. 2017. Vol. 12. pp. 395–399.

Full content Microhardness of gas-dynamic coatings from aluminum powder multi-reinforced with fullerenes and aluminum oxide
Back