Journals →  Eurasian Mining →  2024 →  #2 →  Back

PROCESSING AND COMPLEX USAGE OF MINERAL RAW MATERIALS
ArticleName A comprehensive study of thermodynamics and electrochemical processes involving modified iron(II)-bearing sphalerite ions with thiol collectors
DOI 10.17580/em.2024.02.15
ArticleAuthor Kyaw Z. Y., Goryachev B. E., Adigamov A. E.
ArticleAuthorData

Science and Technological Research Center, Pyin Oo Lwin, Myanmar1 ; National University of Science and Technology—NUST MISIS, Moscow, Russia2

Kyaw Z. Y.1,2, Associate Professor, Candidate of Engineering Sciences, kokyawgyi49@gmail.com

 

National University of Science and Technology—NUST MISIS, Moscow, Russia
Goryachev B. E., Professor, Doctor of Engineering Sciences
Adigamov A. E., Associate Professor, Candidate of Engineering Sciences

Abstract

This article presents a comprehensive study of interactions between sphalerite surfaces and various compounds, including iron sulfate, butyl xanthate and sodium dibutyl dithiophosphate, shedding light on their effects on the kinetics of sphalerite flotation, through a combination of thermodynamic and potentiometric analyses. It delves into impact of non-ferrous sulfates and thiol collectors on flotation of spha lerite, both in isolation and in the presence of iron-containing compounds. These investigations provide valuable insights into the complex dynamics of mineral flotation processes and offer crucial information for optimizing mineral processing in the mining industry.

keywords Flotation, sphalerite, potassium butyl xanthate, sodium butyl dithiophosphate, thermodynamics, electrochemistry, iron(II)-bearing sphalerite, modified sphalerite surface, isobaric–isothermal potential calculation, potentiometric studies of sphalerite in aqueous solutions
References

1. Rybak Y., Khayrutdinov M. M., Kongar-Syuryun Ch. B., Tyulyayeva Y. S. Resource-saving technologies for development of mineral deposits. Sustainable Development of Mountain Territories. 2021. Vol. 13, No. 3. pp. 405–415.
2. Krasyukova E., Aynbinder I., Ivannikov A. A rational approach to the management of underground mining in complex hydrogeological and geomechanical conditions based on a risk assessment. IOP Conference Series: Earth and Environmental Science. 2021. Vol. 684. ID 012006.
3. Cherkasova T. G., Cherkasova E. V., Tikhomirova A. V. et al. Study of matrix and rare elements in ash and slag waste of a thermal power plant concerning the possibility of their extraction. Metallurgist. 2022. Vol. 65, No. 11-12. pp. 1324–1330.
4. Gendler S. G., Prokhorova E. A. Methodical framework for selecting occupational safety management priorities in underground coal mining on the basis of integrated occupational illness and injury risk dynamics analysis. Gornyi Zhurnal. 2023. No. 9. pp. 41–48.
5. Klyuev R. V., Bosikov I. I., Gavrina O. A., Lyashenko V. I. Assessment of operational reliability of power supply of the developed ore mining areas at the high-altitude mine. Mining Sciences and Technologies. 2021. Vol. 6, No. 3. pp. 211–220.
6. Stroykov G. A., Babyr N. V., Ilin I. V., Marchenko R. S. System of comprehensive assessment of project risks in energy industry. International Journal of Engineering. 2021. Vol. 34, Iss. 7. pp. 1778–1784.
7. Rzazade U., Deryabin S., Temkin I., Kondratev E., Ivannikov A. On the issue of the creation and functioning of energy efficiency management systems for technological processes of mining enterprises. Energies. 2023. Vol. 16, Iss. 13. ID 4878.
8. Lyashenko V. I., Golik V. I., Klyuev R. V. Evaluation of efficiency and environmental impact (on subsoil and groundwater) of underground block leaching (UBL) of metals from ores. Mining Science and Technology. 2022. Vol. 7, No. 1. pp. 5–17.
9. Marinin M. A., Afanasyev P. I., Sushkova V. I., Ustimenko K. D., Akhmetov A. R. The experience of using the Kuz-Ram model in describing grain size distribution of blasted rock mass. MIAB. 2023. No. 9-1. pp. 96–109.
10. Didmanidze O. N., Afanasev A. S., Khakimov R. T. Mathematical model of the liquefied methane phase transition in the cryogenic tank of a vehicle. Journal of Mining Institute. 2020. Vol. 243. pp. 337–347.
11. Bondarenko I. S. Elaboration of plans-forecasts based on engineering-andeconomic performance of mines. MIAB. 2022. No. 3. pp. 97–107.
12. Gendler S. G., Kryukova M. S. Thermal management of metro lines, including double-track and single-track tunnels. MIAB. 2023. No. 9-1. pp. 248–269.
13. Khayrutdinov M. M., Golik V. I., Aleksakhin A. V. et al. Proposal of an algorithm for choice of a development system for operational and environmental safety in mining. Resources. 2022. Vol. 11, No. 10. 88 p.
14. Kovalski E. R., Kongar-Syuryun Ch. B., Petrov D. N. Challenges and prospects for several-stage stoping in potash mining. Sustainable Development of Mountain Territories. 2023. Vol. 15, No. 2(56). pp. 349–364.
15. Chumakov A., Prischepov V., Melekhina K., Ivannikov A. Improving the control system of concentration plants based on express control of dissemination of magnetic minerals. IOP Conf. Series: Earth and Environmental Science. 2021. Vol. 684. ID 012005.
16. Wu Y., Zhang Q., Zhu R. et al. Studying the effect of Cr and Si on the hightemperature oxidation-resistance mechanism of hot stamping steel. Metals. 2023. Vol. 13, Iss. 10. ID 1670.
17. Vasilyeva М. А., Volchikhina А. А., Kuskildin R. B. Improvement of water segregation in backfilling. MIAB. 2023. No. 4. pp. 125–139.
18. Kongar-Syuryun Ch., Aleksakhin A., Khayrutdinov A., Tyulyaeva Y. Research of rheological characteristics of the mixture as a way to create a new backfill material with specified characteristics. Materials Today: Proceedings. 2021. Vol. 38, P. 4. pp. 2052–2054.
19. Khayrutdinov M. M., Kaung P. A., Chzho Z. Ya., Tyulyaeva Y. S. Ensuring environmental safety in the implementation of the resource-renewable technologies. Occupational Safety in Industry. 2022. No. 5. pp. 57–62.
20. Cheynesh B. K., Aleksakhin A. V., Eliseeva E. N. et al. Modern technologies providing a full cycle of geo-resources development. Resources. 2023. Vol. 12, Iss. 4. ID 50.
21. Aleksandrova T. N., Afanasova A. V., Kuznetsov V. V., Aburova V. A. Selection of copper–nickel sulfide ore flotation parameters based on floatability ranking of flotation components. MIAB. 2022. No. 1. pp. 131–147.
22. Glembockij V. A., Klassen V. I. Flotation Enrichment Methods. Moscow : Nedra, 1981. 304 p.
23. Kravcov A., Dudchenko O. L., Svoboda P. et al. Broadband ultrasonic pulseecho method for estimation of local density of tungsten samples. Journal of Physics: Conference Series. 2019. Vol. 1172. ID 012064.
24. Herrera-Urbina R., Hanson J. S., Harris G. H., Fuerstenau D. W. Principles and practice of sulphide mineral flotation. Sulphide Deposits — Their Origin and Processing. Springer, Dordrecht. 1990. DOI: 10.1007/978-94-009-0809-3_6
25. Horeshok A. A., Solodov V. S., Papin A. V. et al. Enrichment and processing of coke dust. Coke and Chemistry. 2022. Vol. 65, No. 3. pp. 98–101.
26. Aleksandrova T. N., Afanasova A. V., Kuznetsov V. V., Babenko T. A. Process analysis of selective disintegration of Zapolyarny copper–nickel ore. MIAB. 2021. No. 12. pp. 73–87.
27. Ryaboy V. I., Asonchik K. M., Polkin V. N., Poltavskaya L. M., Repina N. V. Selective collector application in copper–zinc ores flotation. Obogashchenie Rud. 2008. No. 3. pp. 20–22.
28. Kaung P. A., Semikin A. A., Khayrutdinov A. M., Dekhtyarenko A. A. Recycling of industrial waste is a paradigm of resource provision for sustainable development. Development of Mountain Territories. 2023. Vol. 15, No. 2. pp. 385–397.
29. Tihonov O. N. Laws of Effective Separation of Minerals in Mineral Processing. Moscow : Nedra, 1984. 207 p.
30. Abramov A. A. Technology of Enrichment of Ores of Nonferrous Metals. Moscow : Nedra, 1983. 358 p.
31. Will B. A. Wills’ mineral processing technology. Butterworth-Heinemann. 2005. DOI: 10.1016/B978-0-7506-4450-1.X5000-0
32. Adamov Je. V. Technology of Nonferrous Metal Ores. Moscow : Nedra, 1993. 412 p.
33. Abramov A. A. Technology of Processing and Enrichment of Nonferrous Metal Ores. Moscow : Vysshee gornoe obrazovanie, 2005. Vol. 3. 215 p.
34. Goryachev B. E., Kyaw Z. Y., Nikolaev A. A. The effect of cooper, zinc and iron sulfates on sphalerite flotation by sulphydryl collectors. Tsvetnye Metally. 2017. No. 3. pp. 7–12.
35. Kyaw Z. Y., Htet Z. O., Shekhirev D. V., Goryachev B. E. The effect of ferrous sulfate, sodium sulfide and their mixtures on the flotation of sphalerite in the alkaline medium. Sustainable Development of Mountain Territories. 2023. Vol. 15, No. 1(55). pp. 122–133.
36. Kyaw Z. Y., Htet Z. O., Phyoe K. K., Wai Z. K. Optimization of processing flow charts for double refractory sulfide gold ore. MIAB. 2022. No. 9. pp. 143–155.
37. Goryachev B. E., Kyaw Zay Ya., Nikolaev A. A., Polyakova Yu. N. Peculiarities of sphalerite flotation by butyl potassium xanthate and sodium dithiophosphate in lime medium. Tsvetnye Metally. 2015. No. 11. pp. 14–19.
38. Kyaw Z. Y., Goryachev B., Adigamov A., Nurgalieva K., Narozhnyy I. Thermodynamics and electrochemistry of the interaction of sphalerite with iron(II)-bearing compounds in relation to flotation. Resources. 2022. Vol. 11, Iss. 12. ID 108.
39. Nikolaev A. A., So Tu, Goryachev B. E. Prospect for shale gas production. MIAB. 2015. No. 9. pp. 95–106.
40. Shehirev D. V., Smajlov B. B. Kinetics of recovery of particles with different mineral composition in lead–zinc ore flotation. Obogashchenie Rud. 2016. No. 2. pp. 20–26.
41. Pankin A. V., Makaveckas A. R., Shehirev D. V. An automated mineralogical analysis for beneficiation processes. Obogashchenie Rud. 2013. No. 1. pp. 40–43.

Full content A comprehensive study of thermodynamics and electrochemical processes involving modified iron(II)-bearing sphalerite ions with thiol collectors
Back