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Обогащение
Название Результаты промышленных испытаний усовершенствованного реагентного режима флотации на Медной обогатительной фабрике № 1 АО «Алмалыкский ГМК»
DOI 10.17580/tsm.2025.02.02
Автор Нафталь М. Н., Федотова Я. Ю., Кизяев Д. А., Антоненок Д. С.
Информация об авторе

ООО «БАЗИС Про», Москва, Россия.

М. Н. Нафталь, генеральный директор, канд. техн. наук, эл. почта: naftalmn@gmail.com

 

Сибирский федеральный университет, Красноярск, Россия
Я. Ю. Федотова, аспирант, эл. почта: y.fedotova@chemrd.com
Д. А. Кизяев, аспирант, эл. почта: Denis.Kizyaev@yandex.ru
Д. С. Антоненок, магистрант, эл. почта: kazieva.dasha@mail.ru

Реферат

В АО «Алмалыкский ГМК» (далее — АГМК) продолжают совершенствовать действующие технологии обогащения золото-медно-порфировых руд месторождения Олий Зиё. Одним из ключевых направлений дальнейшего развития является применение флотореагентов нового поколения при обогащении руды на действующих и строящихся медных обогатительных фабриках (МОФ) АГМК. Результаты опытно-промышленных испытаний реагентного режима флотации МОФ-1 на основе использования комбинации флотореагентов-собирателей АФИ-4Г10К и ДП-4 российского производства подтвердили его высокую технологическую эффективность. Применение АФИ-4Г10К и ДП-4 в сочетании с бутиловым ксантогенатом калия при обогащении руды Кальмакыра позволило повысить извлечение металлов в коллективный медно-молибденовый концентрат по сравнению со стандартным реагентным режимом: меди — на 1,99 % (абс.); золота — на 3,06 % (абс.) при достижении регламентного качества концентрата по содержанию меди (≥16 % Cu). В связи с успешным проведением опытно-промышленных испытаний принято решение о поэтапном внедрении реагентов АФИ-4Г10К и ДП-4 на МОФ-1 АГМК взамен используемых (регламентных) флотореагентов. АГМК приступил к проработке проекта локализации их производства для МОФ на территории Алмалыка.

В работе принимали активное участие А. А. Абдукадыров, Н. Г. Соломко, А. С. Меджибовский, И. А. Казин, А. М. Сайназаров, У. А. Парпибоев, О. Ю. Исматов, Э. Р. Саппарова, У. М. Абдуразоков, Э. А. Блиев, М. И. Херсонский, А. В. Дементьев, Л. В. Антоненко и др.
Авторы выражают благодарность всему персоналу Медной обогатительной фабрики № 1 АГМК, а также сотрудникам Технологического центра разработки и внедрения инновационных технологий АГМК, внесшим свой вклад в подготовку данной статьи.

Ключевые слова Алмалыкский ГМК, опытно-промышленные испытания, золото-медно-порфировая руда, флотация, медь, золото, извлечение, флотореагенты-собиратели, АФИ-4Г10К, присадка ДП-4
Библиографический список

1. Shcherbakova A. The main metal of green energy is becoming scarce. How is the struggle for copper unfolding in the world? Available at: https://lenta.ru/articles/2023/06/06/med/ (accessed: 09.08.2024).
2. Seck G. S., Hache E., Bonnet C., Simoёn M., Carcanague S. Copper at the crossroads: Assessment of the interactions between low-carbon energy transition and supply limitations. Resources, Conservation & Recycling. 2020. Vol. 163. 105072. DOI: 10.1016/j.resconrec.2020.105072
3. The role of copper in the energy transition. Available at: https://www.dnv.com/article/the-role-of-copper-in-the-energy-transition-247342 (accessed: 9.08.2024).
4. Copper in the energy transition: an essential, structural and geopolitical metal! Available at: https://www.ifpenergiesnouvelles.com/article/copper-energytransition-essential-structural-and-geopolitical-metal (accessed: 9.08.2024).
5. Driving the green revolution: The use of copper in EVs. 25.07.2022. Available at: https://www.innovationnewsnetwork.com/green-revolution-use-ofcopper-in-evs/22503/ (accessed: 9.08.2024).
6. Hursanov A. H. The leader of non-ferrous metallurgy in the CIS. Economic Bulletin of Uzbekistan. Analytical magazine. 2022. No. 2. pp. 66–71.
7. Egorova L., Khvan A. Development of the gold cluster: geology, technology and economics. Globus. Available at: https://www.advis.ru/php/view_news.php?id=6695F9A4-21CC-8649-B40F-98D09C71C292&ysclid=llmmvijg
5z670752657 (accessed: 17.08.2024).
8. A cluster of the copper industry will be created in Uzbekistan. This will increase copper production by more than two times. Available at: https://podrobno.uz/cat/economic/v-uzbekistane-budet-sozdan-klaster-mednoy-promyshlennostieto-pozvolit-uvelichit-proizvodstvo-medi-b/?ysclid=m5qr3ju68z429884975 (accessed: 17.08.2024).
9. Khursanov A. H. Almal yk Mining and Metallurgical Plant celebrates its 70th anniversary! Mining Bulletin of Uzbekistan. 2019. No. 4 (79). pp. 4, 5.
10. Avladov I., Saliev T. Development of geology and reserves of raw materials, prospects for their involvement in the production of Almalyk MMP JSC. Economic Bulletin of Uzbekistan. Analytical magazine. 2022. No. 2. pp. 72–75.
11. Copper. Forecast of global copper supply and demand. Available at: http://www.consultant.ru/document/cons_doc_LAW_144190/b7650296d1989f6d61cc9ae340218b53f1a3bb43/ (accessed: 17.08.2024).
12. Khursanov A. H. Almalyk MMP JSC: responding to global challenges. Globus. Available at: https://www.vnedra.ru/glavnaya-tema/ao-almalykskijgmk-otvechaya-na-globalnye-vyzovy-19488/?ysclid=lpznvoxvxi312290877 (accessed: 17.08.2024).
13. The copper industry is the pride of AMMP. Globus. Available at: https://www.advis.ru/php/view_news.php?id=2C55F07C-C673-A94F-9471-5CC050561201&ysclid=lqdy98hk7z578363268 (accessed: 20.08.2024).
14. Filippovich L. Interview with Sergey Vladimirovich Larionov, Chief Engineer of Almalyk MMP JSC. Tsvetnye Metally. 2023. No. 12. pp. 87, 88.

15. On the 60th anniversary of the Copper Processing Plant. AMMP. Available at: https://ok.ru/sozdandly/topic/153393610708301 (accessed: 20.08.2024).
16. Medzhibovskiy A. S., Naftal M. N., Abdukadyrov A. A. et al. Improving processes of flotation beneficiation of gold-containing porphyry copper ores by using collecting flotation agents produced by LLC NPP Qualitet. Metallurgy of non-ferrous, rare and precious metals : Proceedings of the XV International Conference named after Corresponding Member of the Russian Academy of Sciences Gennady Leonidovich Pashkov. Krasnoyarsk, 6–8 September 2022. Krasnoyarsk : Science and Innovation Center Publishing House, 2022. pp. 61–77.
17. Medzhibovskiy A. S., Naftal M. N., Fedotova Ya. Yu. et al. Flotation processing of gold-bearing porphyry copper ores from the Republic of Uzbekistan deposits optimized through the use of advanced russia-made collecting agents. Tsvetnye Metally. 2023. No. 10. pp. 6–14.
18. Kuchumova A. Malmyzh deposit: in search of enrichment technology. Dobyvayushchaya promyshlennost. 2023. No. 5. pp. 110–114.
19. Bocharov V. A., Yushina T. I., Ignatkina V. A., Hachatryan L. S. et al. Technological assessment of the main directions of resistant polymetallic ores and products complex processing. GIAB. 2014. No. 12. pp. 81–91.
20. Solozhenkin P. M., Kondratiev S. A., Angelova E. I. Quantum mechanical representations of pyrite flotation. Journal of Mining Science. 2013. No. 5. pp. 166–179.
21. Chanturiya E. L. Flotation fractionation of gold-bearing pyrite into products of various quality. GIAB. 2006. No. 5. pp. 339–345.
22. Bocharov V. A., Ignatkina V. A., Lapshina G. A., Hachatryan L. C. Features of gold extraction from gold-bear ing sulfide ores. GIAB. 2004. No. 12. pp. 297–301.
23. Bocharov V. A., Chanturiya E. L. Study of the nature and technological properties of gold in sulfide ores. Tsvetnye Metally. 2001. No. 6. pp. 61–65.
24. Chanturiya E. L., Bortnikov N. S., Krinov D. I., Kerzin A. L. On the relation of the internal structure, chemical composition, and technological properties of pyrite using the example of the Gayskoye deposit. Journal of Mining
Science. 2005. No. 3. pp. 90–98.
25. Bocharov V. A. Complex processing of sulfide ores based on fractional release and separation of minerals. Tsvetnye Metally. 2002. No. 2. pp. 30–33.
26. Mitrofanov S. I. Selective flotation. Moscow : Nedra, 1967. 585 p.
27. Plaksin I. N. Mineral processing : selected works. Мoscow : Nauka, 1970. 310 p.
28. Bocharov V. A., Ignatkina V. A. Features of the use of composite collectors in the technology of selective flotation of non-ferrous metals pyrite ores. GIAB. 2012. No. 8. pp. 168–171.
29. Khersonskiy M. I., Desyatov A. M., Delger R. Development of effective reagent modes of flotation of copper-molybdenum pyrite-containing ores using compositions of various collectors. Collection of scientific papers of FSUE Institute Gintsvetmet. Мoscow : FSUE Institute Gintsvetmet, 2008. рp. 83–94.
30. Ryaboy V. I. On the surface reactions of flotation reagents with minerals based on their donor-acceptor interaction (JSC Mekhanobr-Orgsintez-Reagent). Available at: http://reaflot.com/files/On%20surface%20reactions%20flotoreagents.pdf (accessed: 03.08.2024).
31. Ejtemaei М., Irannajad М., Gharabaghi М. Effect of the chain length on adsorption of mixed collectors on chalcopyrite. XXVI International Mineral Processing Congress, IMPC 2012. New Delhi, India. 24–28 September 2012. pp. 01315–01323.
32. Vidyadhar A., Rao K. H., Forssberg K. S. E. Role of mixed cationic/anionic collector systems in selective feldspar flotation from quartz. Mineral Processing Technology. 15–17 February 2001. Hyderabad, India. pp. 183–191.
33. Nagaraj D. R., Farinato R. S. Major innovations in the evolution of flotation reagents. Mineral processing and extractive metallurgy: 100 years of innovation. Englewood, CO : SME, 2014. pp. 159–175.
34. Abramov A. A. Collected works : Vol. 7. Flotation. Collecting reagents : a textbook. Moscow : Gornaya kniga, 2012. 656 p.
35. Shafeev R. Sh. Relation of semiconductor properties of minerals with the action of flotation reagents. Flotation properties of semiconductor minerals. Мoscow : Nedra, 1966. pp. 10–24.
36. Chanturiya V. A., Bunin I. Zh., Lunin V. D. et al. The use of powerful electromagnetic pulses in the processes of disintegration and releasing of refractory gold-bearing raw materials. Journal of Mining Science. 2001. No. 4. pp. 95–106.
37. Ryaboy V. I. On the surface reactions of flotation reagents with minerals based on their donor-acceptor interaction. Obogashchenie Rud. 2008. No. 6. pp. 24–30.
38. Ryaboy V. I. Creation and application of more effective reagents based on physico-chemical concepts. Obogashchenie Rud. 2002. No. 1. pp. 19–23.
39. Plaksin I. N., Shafeev R. Sh., Chanturiya V. A. Effect of mineral surface heterogeneity on interaction with flotation reagents. Мoscow : Nauka, 1965. 51 p.
40. Plaksin I. N., Shafeev R. Sh., Chanturiya V. A. Interaction of the energy structure of mineral crystals with their flotation properties. Proceedings of the VIII International Congress on Mineral Processing. Leningrad, 1969. Vol. 2. pp. 235–246.
41. Chanturiya V. A. Scientific foundations of electrochemical technology of mineral processing. Bulletin of the AS USSR. 1985. No. 9. pp. 39–47.
42. Solozhenkin P. M., Solozhenkin O. I. Computer design of sulfhyryl flotation agent and their derivatives. Tsvetnye Metally. 2010. No. 7. pp. 11–14.
43. Solozhenkin P. M., Solozhenkin O. I. Computer modeling of sulfhydric collectors’ and their derivatives’ structure. Obogashchenie Rud. 2010. No. 4. pp. 31–34.
44. Jianhua Chen, Zhenghe Xu, Ye Chen. Electronic Structure and Surfaces of Sulfide Minerals: Density Functional Theory and Applications. Мoscow : Publish. House “Ore & Metals”, 2022. 400 p.
45. Glembockiy O. V., Klimenko N. G. On the relation between the flotation and electrical properties of some sulfide minerals during their oxidation. Trudy CNIGRI. 1969. No. 82. pp. 178–189.
46. Avdokhin V. M., Abramov A. A. Oxidation of sulfide minerals in treatment processes. Мoscow : Nedra, 1989. 231 p.
47. Khramtsova I. N., Gogotina V. V., Baskaev P. M., Kaytmazov N. G., Naftal M. N. Development of technology for processing rich and copper ores to produce high-quality copper and nickel concentrates. Tsvetnye Metally. 2007. No. 7. pp. 32–37.
48. Sataev I. Sh., Baranov V. F. Upon the world practice of copper-porphyry ores dressing (review). Obogashchenie Rud. 2011. No. 4. pp. 45–49.
49. Asonchik K. М., Aksenova G. Ya., Maksimov I. I., Tasina Т. I. Porphyry copper ore different flotation regimes studies. Obogashchenie Rud. 2017. No. 4. pp. 18–21.
50. Kuznetsova I. A., Maksimov I. I. Development of the processing technology for porphyry copper ores of the Tominsky deposit. Obogashchenie Rud. 2021. No. 2. pp. 9–14.
51. Belov A. S., Shenderovich E. M. Design cases for Russia’s largest mining and processing enterprises for copper ores. Obogashchenie Rud. 2021. No. 6. pp. 48–52.
52. Altushkin I. A., Levin V. V., Gordeev A. I., Pikalov V. A. Development of the Tominsk and Mikheevsk copper ore deposits of the Southern Urals. Tsvetnye Metally. 2019. No. 7. pp. 21–28.
53. Bulatovic S. M. Handbook of flotation reagents: chemistry, theory and practice. Vol. 1. Flotation of sulfide ores. Elsevier Science, 2007. 448 р.
54. Guitard E., Bruce T., Bruey F., Nagaraj D. R. et al. Aerophine 3418A Promoter – the Canadian collector – 50 years of improved metallurgy in vario us applications. 47th Annual meeting of the Canadian mineral processors. Ottawa, Canada. 20–22 January 2015. pp. 255–270.
55. Sadykhov K. I., Agaev A. N. Sulfonate additives for motor oils. Baku : Elm, 1982. pp. 6–7.
56. Kuliev A. M. Chemistry and technology of additives to oils and fuels. Leningrad : Khimiya, 1985. pp. 66–71.
57. Abramzon A. A., Golovina N. A., Zaychenko L. P. The effect of surfactants on the edge angle. Colloid Journal. 1978. Vol. 40, No. 2. pp. 311–314.
58. Klassen V. I., Krokhin S. I., Tikhonov S. A. Effect of an apolar reagent surrounding the area of contact of a bubble and a mineral particle on the strength of their adhesion during flotation. Tsvetnye Metally. 1962. No. 4. pp. 9–11.
59. Melik-Gajkazyan V. I. On the mechanism of action of apolar reagents during froth flotation. Obogashchenie Rud. 1970. No. 3. pp. 38–43.
60. Umarova I. K., Makhmarezhabov D. B., Yuldashev Sh. H. Material composition analysis and process flow development for the porphyry copper ores of the Yoshlik-1 deposit. Obogashchenie Rud. 2021. No. 5. pp. 10–14.
61. Uzbekistan is entering the race for the “copper” billions. Available at: https://uz.sputniknews.ru/20210629/uzbekistan-vstupaet-v-gonku-za-mednye-milliardy-19451609.html (accessed: 20.08.2024).
62. Localization and cooperation. How AMMP implements its ambitious projects. Available at: https://podrobno.uz/cat/obchestvo/lokalizatsiya-i-kooperatsiya-kak-agmk-realizuet-svoi-grandioznye-proekty/?ysclid=lqdntzriom953259588 (accessed: 20.08.2024).

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