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| Hydrometallurgy of non-ferrous, rare and noble elements: problems and prospects | |
| ArticleName | The features of interaction of nickel oxides with solutions of sulfuric acid during leaching of industrial roasted product of nickel concentrate |
| ArticleAuthor | Kalashnikova M. I., Volkov L. V., Keskinova M. V. |
| ArticleAuthorData | M. I. Kalashnikova, Head of the Hydrometallurgy Laboratory, e-mail: MIKal@nikel.spb.su, The Gipronickel Institute; L. V. Volkov, Professor, St. Peterburg State Polytechnical University; M. V. Keskinova, Junior Researcher, Hydrometallurgy Laboratory, The Gipronickel Institute. |
| Abstract | The results of researches of nickel oxide (II) leaching with water solutions of sulfuric acid from semi-finished product of nickel production — roasted product of oxidizing roasting of sulphide nickel concentrate have been exposed. Nickel dissolving from the roasted product is possible at temperatures above 180 oC. It has been shown that speed of leaching have been raised and temperature has been reduced till 90 oC via implementation of oxidizing material in the pulp and maintenance of oxidizing-reducing potential on definitely level. The mechanism of sharp speed raising, based on possibility of forming of nickel oxides with the higher oxidation level (NiOx) in the roasting product has been proposed. The nickel oxide (II) can be dissolved through the stages of formation and follow dissolving of NiOx. The speed of both stages of this cycle process is more higher than speed of direct reaction. |
| keywords | Nickel concentrate, oxidizing roasting, roasted product, leaching, sulfuric acid, nickel oxide (II), consumption of oxidizing material. |
| References | 1. Ripan R., Chetyanu I. Neorganicheskaya khimiya (Inorganic chemistry). Moscow, 1972. Vol. 2. 1431 pp. 2. Fiziko-khimicheskie svoystva okislov : spravochnik (Physicochemical Properties of Oxides : reference book). Moscow, 1978. 472 pp. 3. Bogatskiy D. P. Zhurnal obshchey khimii. Journal of general chemistry. 1951. Vol. XXI, issue. I. pp. 3–10. 4. Tyurin A. G. Termodinamika khimicheskoy i elektrokhimicheskoy ustoychivosti splavov : dis. … d-ra khim. nauk : 02.00.04. Thermodynamics of chemical and electrochemical resistance of alloys : thesis ... Doctor of Chemical Sciences : 02.00.04. Chelyabinsk, 2008. 484 pp. |
| Language of full-text | russian |
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