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75 years of Chelyabinsk Zinc Plant | |
ArticleName | Chemical and Electrochemical Purification of Alumina Production Solutions |
ArticleAuthor | Yatsenko S. P., Rubinshtein G. M., Pyagai I. N. |
ArticleAuthorData | S. P. Yatsenko, head of department, e-mail: yatsenko@ihim.uran.ru; G. M. Rubinshtein, senior scientist; I. N. Pyagai, senior scientist, Institute of Chemistry of Solids, Ural Division of the Russian Academy of Sciences |
Abstract | The methods for removal of Zn, Fe, Si, S and organic substances from alkali-aluminate solutions at processing by the compounds of Mg, Ca, NaS and electrolysis are discussed and the experimental results are presented. The conditions of the most effective removal of impurities from Bayer solutions, providing the manufacturing of high quality alumina, are determined. |
keywords | Solutions of aluminiuim oxide production, removing of impurities, processing by magnesium and calcium compounds, electrolysis of solutions |
References | 1. Yatsenko S. P., Shirokova A. G., Koryakova O. V. et al // Proc. IX regional NPK “Aluminum of Ural Mountains — 2004”. — Krasnoturyinsk. BAS. 2005. P. 118–127. 2. Krasnykh A. I. // Collected works “Aluminum of Siberia”. Scientific and Technological Center “Light metals. III. Alumina production”. 2004. P. 228–231. 3. Pulpeiro J. G., Fleming L., Hiscox B. et al. // Light Metals. 1999. P. 89–95. 4. Yatsenko S. P., Pasechnik L. А., Rubinshtein G. M. et al // Abstracts of Х Anniversary NPK “Aluminum of Ural Mountains — 2005”, Krasnoturyinsk. BAS. 2005. P. 41–42. 5. Williams F. S., Perotta A. J. // Light Metals. 1998. P. 81–87. 6. Soucy G., Larocgue J. E., Fortes G. // Ibid. 2004. P. 109–119. 7. Pat. 179404. Process for decomposition of organic materials in aluminate liquor of alum earth-production according to the Bayer method, and for separating solid decomposition products / Feher I., Siegfried Z., Siebert R. ; appl. Magyar aluminum, Mansfeld kombinat w pieck veb ; publ. 28.10.1982. 8. Pat. 5888461 US. Process for purifying sodium aluminate solutions containing sodium oxalate / Soirat A. ; appl. Pechiney aluminum ; publ. 30.03.1999. 9. Pat. 5902560 US. Method for inhibiting precipitation of sodium oxalate in a Bayer process liquor / Farquharson G. J. ; appl. Nalco chemical Co ; publ. 11.05.1999. 10. Pat. 4275043 US. Removal of oxalate from Bayer process liquor / Gnyra B. ; appl. Alcan res & dev ; publ. 23.06.1981. 11. Pat. 4275042 US. Removal of oxalate from Bayer process liquor / Lever G. ; appl. Alcan res & dev ; publ. 23.06.1981. 12. Pat. 5284634 US. Purification of Bayer process liquors using cationic polymeric quaternary ammonium salts / Strominger M. G., Malito J. T. ; appl. Nalco chemical Co. ; publ. 8.02.1994. 13. Pat. 5427750 US. Polymers for removing humates from Bayer process liquors / Sommese A. G., Mahoney R. P. ; appl. Nalco chemical Co. ; publ. 27.06.1995. 14. Pat. 5837215 US. Method of removing insoluble materials from Bayer process with fatly acid and fatly acid free polymer flocculants / Tippett J. M. ; Farquarson G. J., Selvarajan R. et al. ; appl. Nalco chemical Co. ; publ. 17.11.1998. 15. Hansen R. M. // J. Metals. 1969. Vol. 21, No. 9. P. 32–34. 16. Perestoronina M. A., Zusman M. V. // Abstracts of VIII NPK “Aluminum of Ural Mountains-2003”. Krasnoturyinsk. BAS. 2003. P. 59. 17. Zusman M. V., Perestoronina M. A., Marynyuk A. R. // Ibid. P. 57–58. 18. Guseinov E. R. // J. Appl. Chem. (Russian). 2008. V. 81, No. 8. P. 1307–1310. 19. Inventor’s certificate 1123252 USSR. Method of purification of aluminate solutions from impurities / A. I. Zazubin, G. A. Romanov, G. M. Rubinshtein ; publ. 1984. 20. Pat. 4836990 US. Removal of organics from Bayer process streams / Swinkels D. A., Chouzadjian K. ; appl. Broken hill pty Co. Ltd ; publ. 6.06.1989. 21. Pat. 2264481 Russian Federations. Method of gallium recovery from alkali-aluminate solutions of alumina production / Yatsenko S. P., Rubinshtein G. M., Diev V. N., etc. ; publ. 20.11.2005. |
Language of full-text | english |
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