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ArticleName | Analytical systems for stainless steel pickling solutions based on mixed acids |
ArticleAuthor | M. Sartor, D. Buchloh, F. Rögener, T. Reichardt. |
ArticleAuthorData | Dr. Eng. M. Sartor, Head of the project; Eng. D. Buchloh, Head of the project; Dr. Eng. F. Rögener, Head of the project group; Eng. T. Reichardt, Head of department of halvanizing and surface processing, Scientific and Research Institute VDEh, Düsseldorf; frank.roegener@bfi.de |
Abstract | On-line measurement systems for stainless steel pickling solutions — consisting of HF and HNO3 — are not available. Nevertheless a fast and reliable measurement is important to control a pickling line and the subsequent regeneration technology to assure proper pickling performance in steel production and to avoid surface failures. Thus, the operator has the choice between different off-line analysing systems which employ different physical data for parameter detection. In this study the performance of conventional lab analysis and two commercially available measurement systems was compared using the same solutions taken from different stainless steel pickling lines in Germany and Spain. As a result, the applied calculation algorithms are sufficient to control pickling processes. |
keywords | Analytical systems, stainless steel, pickling, mixed acids, regeneration, nitric acid, hydrofluoric acid. |
References | 1. Fernando, L. A.: Metall. Trans. B, Vol. 21B (1990) No. 1, p. 5/9. 2. Stephenson, J. B.; Horter, G. L.; Dewing, H. H.: Iron removal and the complexity of stainless steel pickling liquors, [in:] Dutrizac, J. E.; Monhemius, A. J. [ed.:]: Iron control in hydrometallurgy, Ellis Horwood Ltd., Chichester, 1986, p. 571/81. 3. Reddy, R. G.; Wang, S.; Chen, B.: Min. Metall. Proc. 102 (1993) No. 5, p. 102/07. 4. Price, D. M.; Horter, G. L.: Metal Finishing (1994) No. 2, p. 60/65. 5. Koivunen, T.: MPT Intern. 11 (1987) No. 1, p. 65/66. 6. Mayr, D.; Coronado, L.: SEAISI Quart. 32 (2003) No. 2, p. 28/36. 7. Xu, T.; Yang, W.: J. Membr. Sci. 220 (2003), p. 89/95. 8. Baley, D.: Stainless Steel (2003) Nov/Dec, p. 10/11. 9. Rapp, H. J.; Rögener, F.; Sartor, M.; Reichardt, T.: Regeneration of stainless steel pickling solutions by a multistage process consisting of retardation, electrodialysis and membrane electrolysis, Filtech 2009, 13–15 Oct 2009, Wiesbaden, Preprints Vol. II, p. 529/33, 10. Ito, M.; Yoshioka, M.; Isobe, T.; Seino, Y.; Chonan, T.; Yasuhara, H.; Kawabata, Y.; Naka, S.: ISIJ Intern. 37 (1997) No. 4, p. 47/54. 11. Rögener, F.; Buchloh, D.; Schmidt, B.: Überprüfung von Beizsäureanalytik und Wirkungsgrad einer Säureretardationsanlage, BFI-Bericht V 4.48.048, Düsseldorf, 2001. 12. http://www.scanacon.com/SA70.htm, 9 Nov 2009. 13. OS-DE19852242: Verfahren zur Konzent ra tionsbestimmung von Säuren in einem Säuregemisch, 2000. |
Language of full-text | russian |
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