Журналы →  Chernye Metally →  2015 →  №1 →  Назад

Development of metallurgy in Russia and CIS
Название Analysis of dephosphorization process in steel making from metallized raw materials with high phosphorus content
Автор A. I. Hassan, G. I. Kotelnikov, A. E. Semin, G. M. Megahed
Информация об авторе

National University of Science and Technology «MISiS» (Moscow, Russia):

Hassan A. I., Post-Graduate, the Chair «Metallurgy of Steel and Ferroalloys»; e-mail: discover3030@gmail.com
Kotelnikov G. I., Cand. Eng., Ass. Prof., the Chair «Metallurgy of Steel and Ferroalloys»; e-mail: gikotelnikov@yandex.ru
Semin A. E., Dr. Eng., Prof., the Chair «Metallurgy of Steel and Ferroalloys»; e-mail: asemin2007@yandex.ru

 

EZZ Flat Steel (Suez, Egypt):

Megahed G. M., Deputy General Director on Technical Aff airs; e-mail: gmegahed@ezzsteel.com

Реферат

The world products of direct reduced iron are presented not only by metalized pellets (DRI) and hot briquetted iron (HBI) with low phosphorus content, but also by these products with high phosphorus concentrations, depending upon the quality of iron ore and its degree of enrichment. They may contain up to 0.08% of phosphorus and above it. This makes it necessary to analyze the process of dephosphorization during the melting and refining processes of these products as a charge materials in the electric arc furnace steel making. The experiments have been conducted at EZZ Flat Steel Company in Suez, Egypt, with annual production capacity 1.2 mln. t of hot-rolled steel sheet with thickness 1.0–12.0 mm. This analysis showed that, the dephosphorization reactions are sufficiently far from equilibrium, and the continuous feeding of metallized pellets (DRI) and hot briquetted iron (HBI) hinders the dephosphorization process and decreases the distribution of phosphorous between slag and metal. For efficient dephosphorization with using the metallized materials, which have phosphorus content 0.061%, the slag should have 25–30% FeO, 4% MgO, and the slag basicity preferably should be between 2.5 and 3.0, while its temperature — 1625–1635 oC.

Ключевые слова Steel making, electric arc furnaces, metallized raw materials, phosphorus content, dephosphorizing, slag basicity
Библиографический список

1. Skorokhodov V. N., Odesskiy P. D., Rudchenko A. V. Stroitelnaya stal (Building steel). Moscow : Metallurgizdat, 2002. 624 p.
2. Gulyaev A. P. Metallovedenie (Metal science). Moscow : Metallurgiya, 1977. 647 p.
3. Bigeev A. M., Bigeev V. A. Teoriya i tekhnologiya plavki stali (Theory and technology of steel smelting). Moscow : Metallurgizdat – MGTU, 2000. 544 p.
4. Trakhimovich V. I., Shalimov A. G. Ispolzovanie zheleza pryamogo vosstanovleniya pri vyplavke stali (Use of direct-reduced iron in the time of steel smelting). Moscow : Metallurgiya, 1982. 248 p.
5. Gudim Yu. A., Zinurov I. Yu., Kiseev A. D. Proizvodstvo stali v dugovykh pechakh. Konstruktsii, tekhnologiya, materialy (Steel manufacturing in arc furnaces. Design, technology, materials). Novosibirsk : Publishing House of Novosibirsk State Technical University, 2010. 547 p.
6. Manning C. P., Fruehan R. J. The rate of the phosphorous reaction between liquid iron and slag. Metallurgical and materials transaction B. 2013. Vol. 44, No. 2. pp. 37–44.
7. Smailer R. M. Phosphorous control in DRI steelmaking. Proceedings of ILAFA congress. Mexico, 1983. p. 13.
8. Lee M., Trotter D., Mazzei O. The production of low phosphorus and nitrogen steels in an EAF using HBI. Scandinavian Journal of Metallurgy. 2001.Vol. 30. pp. 286–291.
9. Sponge iron, direct reduced iron (DRI), hot briqueted iron (HBI), cold briqueted iron (CBI) for steelmaking in induction furnace. Doc: MTD 30(5066). ICS 73.060.10. Accepted: September 15, 2011. Bureau of Indian standards.
10. Meraikib M. Contribution to phosphorus behavior in steelmaking with sponge iron. Steel research. 1988. No. 10. pp. 449–453.
11. Frohber M., Kappor M., Pantke H. D., Queens C. Archiv für das Eisenhüttenwesen. 1975. Bd. 46, No. 11. ss. 695–700.
12. Grigoryan V. A., Stomakhin A. Ya., Utochkin Yu. I. et al. Fiziko-khimicheskie raschety elektrostaleplavilnykh protsessov (Physical-chemical calculations of electric-steel smelting processes). Moscow : MISiS, 2007. 318 p.
13. Kozheurov V. A. Termodinamika metallurgicheskikh shlakov (Thermodynamics of metallurgical slags). Sverdlovsk : Metallurgiya, 1955. 163 p.

Language of full-text русский
Полный текст статьи Получить
Назад