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COMPOSITES AND MULTIPURPOSE COATINGS
ArticleName Understanding the effect of metastable phases on the production of high-density ZrO2 – Y2O3 ceramics
DOI 10.17580/tsm.2019.10.08
ArticleAuthor Mayzik M. A., Kharitonov D. V., Lemeshev D. O., Zhukov D. Yu.
ArticleAuthorData

Obninsk Research and Production Enterprise Technologiya named after A. G. Romashin JSC, Obninsk, Russia:

M. A. Mayzik, Process Engineer, e-mail: mar-majzik@yandex.ru
D. V. Kharitonov, Deputy Director of the Research and Production Complex Responsible for Production, Doctor of Engineering Sciences

 

D. Mendeleev University of Chemical Technology of Russia, Moscow, Russia:
D. O. Lemeshev, Dean at the Faculty of Inorganic Matter and High-Temperature Materials Engineering, Candidate of Engineering Sciences, Associate Professor
D. Yu. Zhukov, Advisor to Rector, Candidate of Engineering Sciences, Associate Professor

Abstract

Development of modern engineering materials is a task of long-term relevance. Technological advancements lead to new developments in materials engineering. This paper examines modern high-density materials on the basis of zirconium dioxide with varying concentrations of yttrium oxide, which is a stabilizing agent that influences the phase composition of material and the end properties of products. It was verified that the developed ceramic materials can withstand drastic changes in temperature varying from +20 to +700 °С avoiding fracture and at the same time retain stable phase composition during operation. The studied materials find application as a ceramic carrier base in oxygen partial-pressure sensors designed for different gas media. The ceramic base was produced by casting of ceramic tapes over the moving maylar substrate. This technique enables to produce tapes with thicknesses from 150 to 400 μm. This research looked at specimens with the thicknesses of 250–270 μm. The paper describes the results of a laboratory study that analysed the ability of ceramic carrier base to withstand fracture when being heat up to 650–700 °С and then shock cooled to room temperature. The results of X-ray diffraction and structural analyses before and after the tests are also described. Apparent volume weight and open porosity of the specimens have been determined. A laboratory testing technique has been developed that simulates the actual environment in which oxygen partial-pressure sensors operate and can validate the instruments’ operability. The authors established the nature of cracking that occurs in the material under repeated temperature cycling (from +25 to +700 °С). They also found a relationship between metastable phases and the production of ceramic tapes with stable properties (such as average density, open porosity, relative density, phase composition).

This research was funded by D. Mendeleev University of Chemical Technology of Russia. Project No. 041-2018.

keywords Zirconium dioxide, polymorphic transformation, metastable phases, thermostability, ceramic tapes, carrier base, oxygen partial-pressure sensor
References

1. Tao Liu, Xiaofang Zhang, Lei Yuan, Jingkun Yu. A review of high-temperature electrochemical sensors based on stabilized zirconia. Solid State Ionics. 2015. No. 283. pp. 91–102.
2. Persson A., Khaji Z., Klintberg L. Dynamic behaviour and conditioning time of a zirconia flow sensor for high-temperature applications. Sensors and Actuators A: Physical. 2016. Vol. 251. pp. 59–65.
3. Studenikin G. V., Mokhon T. V., Lukashenko G. V. The effect of zirconium nanopowder on the sintering temperature. Ogneupory i tekhnicheskaya keramika. 2010. No. 7. pp. 21–28.
4. Amiel S., Copin E., Sentenac T., Lours P., Le Maoult Y. On the thermal sensitivity and resolution of a YSZ:Er3+/YSZ:Eu3+ fluorescent thermal history sensor. Sensors and Actuators A: Physical. 2018. Vol. 272. pp. 42–52.
5. Korableva E. A., Yakushkina V. S., Nekrasov E. V., Savanina N. N., Rusin M. Yu., Vikulin V. V. Electrochemical element and method of its manufacturing. Patent RF, No. 2379670. Published: 20.01.2010.
6. Korableva E. A., Mayzik M. A., Savanina N. N. Formation of tape structures in solid electrolytes. Novye ogneupory. 2014. No. 14. pp. 47–50.
7. HaoLiu, Shuwen Jiang, Xiaohui Zhao, Hongchuan Jiang, Wanli Zhang. YSZ/Al2O3 multilayered film as insulating layer for high temperature thin film strain gauge prepared on Ni-based superalloy. Sensors and Actuators A: Physical. 2018. Vol. 279. pp. 272–277.
8. Jens Eichler, Ulrich Eisele, Jurgen Rodel. Mechanical Properties of Monoclinic Zirconia. Journal of the American Ceramic Society. 2004. Vol. 87, No 7. pp. 1401–1403.
9. Schelling P. K., Phillpot S. R., Wolf D. Mechanism of the Cubic-to-Tetragonal Phase Transition in Zirconia and Yttria-Stabilized Zirconia by Molecular-Dynamics Simulation. Journal of the American Ceramic Society. 2001. Vol. 84, No 7. pp. 1609–1619.
10. Grosso R. L., Muccillo E. N. S., Castro R. H. R. Phase stability in scandiazirconia nanocrystals. Journal of the American Ceramic Society. 2017. Vol. 100, No 5. pp. 2199–2208.
11. Glymond D., Vick M. J., Giuliani F., Vandeperre L. J. High-temperature fracture toughness of mullite with monoclinic zirconia. Journal of the American Ceramic Society. 2017. Vol. 100, No 4. pp. 1570–1577.
12. Gibson I. R. Qualitative X-ray Diffraction Analysis of Metastable Tetragonal (t*) Zirconia. Journal of the American Ceramic Society. 2001. Vol. 84, No 3. pp. 615–618.

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