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SCIENTIFICAL DEVELOPMENTS OF THE SRC HYDROMETALLURGY
ArticleName Processing of gold-antimony concentrates
DOI 10.17580/tsm.2021.03.06
ArticleAuthor Markelov A. V., Falin K. M., Puchkina V. A., Titova A. N.
ArticleAuthorData

SRC Hydrometallurgy, Saint Petersburg, Russia:
A. V. Markelov, Lead Researcher, Ph. D, e-mail: markelov-a@gidrometall.ru
K. M. Falin, Junior Researcher, e-mail: falin-k@gidrometall.ru
V. A. Puchkina, Lab Assistant, e-mail: puchkina-v@gidrometall.ru
A. N. Titova, Lab Assistant, e-mail: nast116@rambler.ru

Abstract

This paper describes the results of a study that looked at processing of goldantimony concentrates with selective extraction of antimony and gold as commodities. The common global practice of processing antimony sulphide concentrates (20–30% Sb) is based on alkaline sulphide leaching followed by precipitation of metallic antimony by electrowinning. However, application of this technique to process sulphide concentrates that, apart from antimony, also contain gold, can be difficult as, together with antimony, up to 10–15% of gold can leach to the solution. It takes a special process during final refining of cathode antimony to recover that gold. This paper describes a process that involves two stages of atmospheric leaching of antimony. The gold that leached to the solution is precipitated with zinc after the first stage of antimony leaching. Together with atmospheric leach tailings, it then goes to the pressure oxidation unit. This process helps oxidize the rest of the sulphides and release refractory gold. The resultant cake is processed following a standard sorption cyanidation technique. The paper looks at the antimony leaching rate and the rate at which gold leaches to the solution during this process. The paper describes the results of selective precipitation of gold from gold-antimony solutions and highlights certain features of this process. A series of tests was conducted to test the techniques of pressure oxidation of atmospheric leach tailings and cyanidation of the residue. The paper also describes a process that was developed for processing of goldantimony concentrates and precipitation of antimony and gold. An antimony recovery exceeding 90–95% can be achieved when using this process. At the same time, the percent of dissolved gold can be reduced from 10–15 tо 1–3%.

keywords Antimony, gold, pressure oxidation, atmospheric leaching, precipitation, process flow chart, refractory gold, cementation
References

1. Jeffrey M. I., Anderson C. G. A fundamental study of the alkaline sulfide leaching of gold. The European Journal of Mineral Processing and Environmental Protection. 2003. Vol. 3, No. 3. pp. 336–343.
2. Anderson C. G. The metallurgy of antimony. Geochemistry. 2012. Vol. 72, No. 4. pp. 3–8.
3. Anderson C. G., Krys L. E. Leaching of Antimony from a Refractory Precious Metals Concentrate. Hydrometallurgy. 1993. Salt Lake City, Utah, 1993. pp. 341–363.
4. Nordwick S., Anderson C. Advances in Antimony Electrowinning at the Sunshine Mine. Hydrometallurgy Fundamentals, Technology and Innovations. Salt Lake City, Utah, 1993.
5. Ubaldini S. et al. Process flow-sheet for gold and antimony recovery from stibnite. Hydrometallurgy. 2000. Vol. 57, No. 3. pp. 187–199.
6. Multani R. S., Feldmann T., Demopoulos G. P. Antimony in the metallurgical industry: A review of its chemistry and environmental stabilization options. Hydrometallurgy. 2016. Vol. 164. pp. 141–153.
7. Solozhenkin P. M. Ferric chloride leaching of antimony sulphides and electrowinning of slurry. Gornyy informatsionno-analiticheskiy byulleten. 2011. pp. 253–260.
8. Wu H. et al. Basic theory and optimization of gold containing antimony concentrate leaching by alkaline sulfide. Physicochemical Problems of Mineral Processing. 2019. Vol. 55, No. 1. pp. 248–257.
9. Yang T. et al. A selective process for extracting antimony from refractory gold ore. Hydrometallurgy. 2017. Vol. 169. pp. 571–575.
10. Yang J., Wu Y. A hydrometallurgical process for the separation and recovery of antimony. Hydrometallurgy. 2014. Vol. 143. pp. 68–74.
11. Anderson C. G. Alkaline sulfide gold leaching kinetics. Minerals Engineering. 2016. Vol. 92. pp. 248–256.
12. Panchenko A. F., Lodeyshchikov V. V., Byvaltsev V. Ya. Comprehensive processing of gold-antimony ores: Process development, adoption and possible optimization. Development of Siberia’s Production Capacity and the Challenge of Accelerating the Technical Progress: Conference proceedings. Krasnoyarsk, 1985. Vol. 1, Iss. 2. pp. 354–358.
13. Naboychenko S. S. et al. Pressure hydrometallurgy of non-ferrous metals. Yekaterinburg : GOU VPO UGTU-UPI, 2008.
14. Gold ore processing: project development and operations. Second edition. Ed. M. D. Adams. Amsterdam : Elsevier, 2016. 1020 p.
15. Marsden J., House I. The chemistry of gold extraction. 2nd ed. SME, 2006. 682 p.
16. Chugaev L. V., Shneerson Ya. M., Lapin A. Yu. Autoclaving and gold extraction. Zoloto i tekhnologii. 2014. No. 4. pp. 90–94.

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